Catalyst for hydrogen peroxide decomposition, process for producing the same, and method for decomposing hydrogen peroxide using the catalyst

Patent metadata

Field	Value
Publication number	US-10441943-B2
Application number	US-201515534601-A
Country	US
Kind code	B2
Filing date	Dec 10, 2015
Priority date	Dec 11, 2014
Publication date	Oct 15, 2019
Grant date	Oct 15, 2019

Abstract

The present invention provides a catalyst for hydrogen peroxide decomposition with which hydrogen peroxide present in acid-containing water to be treated can be efficiently decomposed at low cost and which is less apt to dissolve away in the water being treated, can be stably used over a long period, and renders acid recovery and recycling possible. The present invention has solved the problems with a catalyst for hydrogen peroxide decomposition which is for use in decomposing hydrogen peroxide present in acid-containing water to be treated, the catalyst including a base and, a catalyst layer that is amorphous, includes a platinum-group metal having catalytic function and a Group-6 element metal having catalytic function and is formed over the base.

First claim

The invention claimed is:

1. A catalyst for hydrogen peroxide decomposition for use in decomposing hydrogen peroxide present in acid-containing water to be treated containing sulfuric acid in a concentration of 5% mass or more, comprising:
a base;
a catalyst layer that is amorphous, comprises a platinum-group metal having catalytic function and a Group-6 element metal having catalytic function and is formed over the base; and
a corrosion-resisting interlayer consisting of platinum or gold that coats the base and is between the base and catalyst layer, the interlayer having a thickness of 0.1 to 10 μm.

2. The catalyst for hydrogen peroxide decomposition according to claim 1 , wherein a mass content ratio of the platinum-group metal to the Group-6 element metal is 99:1 to 70:30.

3. The catalyst for hydrogen peroxide decomposition according to claim 1 , wherein the platinum-group metal is at least one metal selected from the group consisting of Pt, Pd, Ru, Ir, and Rh.

4. The catalyst for hydrogen peroxide decomposition according to claim 1 , wherein the Group-6 element metal is at least one metal selected from the group consisting of Mo and W.

5. The catalyst for hydrogen peroxide decomposition according to claim 1 , wherein the amorphous catalyst layer is configured of metals comprising any one combination selected from among: Pd and Mo; Ru and Mo; Pt and W; and Ir and W.

6. The catalyst for hydrogen peroxide decomposition according to claim 1 , wherein the base comprises at least one metal selected from the group consisting of Ta, Nb, Zr, and Ti.

7. The catalyst for hydrogen peroxide decomposition according to claim 1 , wherein the base has a shape which is any one of a plate shape, a net shape, a punching metal, and an expanded metal.

8. A method for decomposing hydrogen peroxide contained in water, comprising:
treating the water with the catalyst according to claim 1 , wherein the hydrogen peroxide is decomposed.

9. The method for decomposing hydrogen peroxide according to claim 8 , wherein the water to be treated has the hydrogen peroxide concentration of 0.1-10% by mass.

10. The method for decomposing hydrogen peroxide according to claim 8 , wherein the water to be treated contains an acid in a concentration of 5-75% by mass.

11. The method for decomposing hydrogen peroxide according to claim 10 , wherein the acid is sulfuric acid.

12. A process for producing a catalyst for hydrogen peroxide decomposition, comprising:
a step of forming a corrosion-resisting interlayer consisting of platinum or gold and having a thickness of 0.1 to 10 μm by forming a coating film on the base by plating; and
a step of forming a catalyst layer that is amorphous and comprises a platinum-group metal having catalytic function and a Group-6 element metal having catalytic function over the interlayer and the base by forming a coating film by plating.

Assignees

• Tanaka Precious Metal Ind

Inventors

• Sato Hiroyasu
• Watanabe Jun
• Sawada Matsunori

Classifications

• C25D3/567

  containing more than 50% by weight of platinum group metals · CPC title

• C25D3/50

  of platinum group metals · CPC title

• C02F2101/10

  Inorganic compounds · CPC title

• C02F2103/346

  from semiconductor processing, e.g. waste water from polishing of wafers · CPC title

• C25D3/48

  of gold · CPC title