Copper and/or copper oxide dispersion, and electroconductive film formed using dispersion

Patent metadata

Field	Value
Publication number	US-10424648-B2
Application number	US-201414906422-A
Country	US
Kind code	B2
Filing date	Jul 22, 2014
Priority date	Jul 23, 2013
Publication date	Sep 24, 2019
Grant date	Sep 24, 2019

Abstract

To provide a copper and/or copper oxide dispersion capable of forming an electroconductive film exhibiting excellent stability with respect to temporal change and having a fine pattern form, an electroconductive film laminate obtained by laminating the electroconductive film produced using the copper and/or copper oxide dispersion, and an electroconductive film transistor. The copper and/or copper oxide dispersion contains 0.50-60 mass % of copper and/or copper oxide microparticies and the following components (1)-(4): (1) a surface energy modifier; (2) an organic compound having a phosphate group; (3) 0.050-10 mass % of a solvent having a vapor pressure of 0.010 Pa to less than 20 Pa at 20° C.; and (4) a solvent having a vapor pressure of 20 Pa to 150 hPa at 20° C. The electroconductive laminate is obtained by laminating an electroconductive film containing copper on a substrate.

First claim

What is claimed is:

1. A dispersion of copper and/or copper oxide, wherein the dispersion contains copper and/or copper oxide microparticles in an amount of between 0.50 mass % and 60 mass %, inclusive relative to the total mass of the dispersion, as well as the following (1) to (4):
(1) a fluorine-containing surfactant that modifies a surface free energy of the dispersion, in an amount of between 0.10 mass % and 2.0 mass %, inclusive relative to the total mass of the dispersion,
(2) an organic dispersing agent having a phosphate group and a number average molecular weight (Mn) of 300 to 30000, in an amount of between 0.10 mass % and 20 mass %, inclusive relative to the total mass of the dispersion,
(3) a dispersing medium having a vapor pressure of 0.010 Pa or higher and lower than 20 Pa at 20° C., in an amount of between 0.050 mass % and 10 mass %, inclusive relative to the total mass of the dispersion, and
(4) a dispersing medium having a vapor pressure of between 20 Pa and 150 hPa, inclusive relative to the total mass of the dispersion, at 20° C.,
wherein the dispersion has a surface free energy of no greater than 40 mN/m at 25° C.

2. The dispersion according to claim 1 , wherein the (3) dispersing medium having a vapor pressure of 0.010 Pa or higher and lower than 20 Pa at 20° C. is a polyhydric alcohol having 10 or less carbon atoms.

3. The dispersion according to claim 1 , wherein the (4) dispersing medium having a vapor pressure of between 20 Pa and 150 hPa, inclusive, at 20° C. is a monoalcohol having 10 or less carbon atoms.

4. The dispersion according to claim 1 , wherein the copper and/or copper oxide is cuprous oxide or cupric oxide.

5. The dispersion according to claim 4 , wherein the copper and/or copper oxide is cuprous oxide.

6. A method of producing a copper electrode or an electroconductive film comprising printing the dispersion of copper and/or copper oxide according to claim 1 on a substrate.

7. A method of producing a copper electrode or an electroconductive film comprising:
printing the dispersion of copper and/or copper oxide according to claim 1 on a substrate; and
reducing the dispersion to provide electroconductivity.

8. A dispersion of copper and/or copper oxide, containing copper and/or copper oxide microparticles in an amount of between 0.50 mass % and 60.0 mass %, inclusive relative to the total mass of the dispersion, and the following (1) to (4):
(1) a fluorine-containing surfactant that modifies a surface free energy of the dispersion in an amount of between 0.10 mass % and 2.0 mass %, inclusive relative to the total mass of the dispersion,
(2) an organic dispersing agent having a phosphate group and a number average molecular weight (Mn) of 300 to 30000, in an amount of between 0.10 mass % and 20 mass %, inclusive relative to the total mass of the dispersion,
(3) a polyhydric alcohol having 10 or less carbon atoms in an amount of between 0.050 mass % and 10 mass %, inclusive relative to the total mass of the dispersion, and
(4) a monoalcohol having 10 or less carbon atoms,
wherein the dispersion has a surface free energy of no greater than 40 mN/m at 25° C.

Assignees

• Asahi Chemical Ind

Inventors

• Ogawa Shimpei
• Ohno Eiichi
• Tsuruta Masanori

Classifications

• C09D11/52 Primary

  Electrically conductive inks · CPC title

• H05K1/092

  Dispersed materials, e.g. conductive pastes or inks · CPC title

• C09D11/037

  characterised by the pigment · CPC title

• C01P2004/03

  obtained by SEM · CPC title

• C01P2006/40

  Electric properties · CPC title