Dynamic in-fiber particle production with precise dimensional control

Patent metadata

Field	Value
Publication number	US-10406723-B2
Application number	US-201414210359-A
Country	US
Kind code	B2
Filing date	Mar 13, 2014
Priority date	Mar 13, 2013
Publication date	Sep 10, 2019
Grant date	Sep 10, 2019

Abstract

A fiber is provided that has been thermally drawn from a fiber preform, having a longitudinal-axis length and including at least one core that has a longitudinal core axis parallel to the longitudinal axis and internally disposed to at least one outer fiber cladding material layer along the fiber length. The fiber is fed through a localized heating site having a heating site temperature, T, that is above a melting temperature of the fiber core, with a feed speed, υ f , that melts a portion of the fiber core at the heating site, causing molten droplets to pinch off of fiber core material, one droplet at a time, with a time period of molten droplet formation set by the fiber feed speed, υ f . The fiber is fed through the localized heating site to move the molten droplets out of the heating site and solidify the molten droplets into solid in-fiber particles.

First claim

We claim:

1. A method for producing particles comprising:
providing a fiber that has been thermally drawn from a fiber preform, the fiber having a longitudinal-axis fiber length and including at least one continuous, solid fiber core having a longitudinal core axis parallel to the longitudinal fiber axis and internally disposed to at least one outer fiber cladding layer of cladding material along the fiber length;
feeding the fiber through a localized heating site having a heating site temperature, T, at which a local viscosity of the fiber cladding material is greater than a local viscosity of the fiber core and at which an interfacial tension exists between the fiber cladding material and the fiber core, and which is above a melting temperature of the fiber core, the fiber being fed through the heating site at a fiber feed speed, υ f , that melts a tip portion of the fiber core upon arrival of the tip portion at the localized heating site, causing a molten droplet to pinch off of fiber core material from the fiber core tip portion, producing a longitudinal sequence of molten droplets one droplet at a time, as the fiber is fed through the heating site, with a time period of molten droplet formation set by the fiber feed speed, υ f , wherein the fiber feed speed, υ f , produces solid particles having a diameter, d, as a function of fiber core diameter, D, as:

d
≈

D
·

3
4

⁢

v
f

⁢

μ
p
clad

γ
p

3

,

where μ p clad is local viscosity of the fiber cladding material at the heating site temperature, T, and γ p is interfacial tension between the fiber core material and the cladding material at the heating site temperature, T; and
continually feeding the fiber through the localized heating site to move each molten droplet out of the localized heating site as each molten droplet is formed, to solidify each molten droplet, producing a longitudinal sequence of solid particles in the fiber, parallel to the longitudinal fiber axis, each particle being separated from other particles in the sequence by the fiber cladding material.

2. The method of claim 1 wherein feeding the fiber through a localized heating site comprises feeding the fiber through a localized flame.

3. The method of claim 1 wherein feeding the fiber through a localized heating site comprises feeding the fiber in proximity to a heating element at a distance that melts the fiber core.

4. The method of claim 1 wherein the fiber feed speed, υ f , is between 1 μm/second and 1 mm/second.

5. The method of claim 1 wherein providing a fiber comprises providing a fiber having a core comprising a crystalline material, whereby each solid particle in the fiber comprises a crystalline particle.

6. The method of claim 1 wherein providing a fiber comprises providing a fiber having a core comprising a semiconducting material, whereby each solid particle in the fiber comprises a semiconducting particle.

7. The method of claim 1 wherein providing a fiber comprises providing a fiber having a core comprising a metal, whereby each solid particle in the fiber comprises a metal.

8. The method of claim 1 wherein providing a fiber comprises providing a fiber having a core comprising a polymer material, whereby each solid particle in the fiber comprises a polymer particle.

9. The method of claim 1 wherein providing a fiber comprises providing a fiber having a core comprising a semiconducting glass, whereby each solid particle in the fiber comprises a semiconducting glass particle.

10. The method of claim 1 wherein providing a fiber comprises providing a fiber having a silica cladding layer.

11. The method of claim 1 wherein providing a fiber comprises providing a fiber having a polymer cladding layer.

12. The method of claim 1 wherein providing a fiber comprises providing a fiber having a core comprising a material selected from the group consisting of silicon and germanium.

13. The method of claim 1 wherein providing a fiber comprises providing a fiber having a core comprising a material selected from the group consisting of tin, copper, silver, and antimony.

14. The method of claim 1 wherein providing a fiber comprises providing a fiber including at least two fiber cores, each fiber core comprising a different core material and each core having a longitudinal axis parallel to the longitudinal fiber axis and internally disposed to at least one outer fiber cladding layer of cladding material along the fiber length, the two fiber cores being separated by an amount of fiber cladding whereby feeding the fiber through the localized heating site causes molten droplets to pinch off of each fiber core material simultaneously and form a plurality of separated longitudinal sequences of particles in the fiber, each sequence of particles separated from other sequences by the fiber cladding.

15. The method of claim 1 wherein providing a fiber comprises providing a fiber including at least two fiber cores, each fiber core comprising a different core material and each core having a longitudinal axis parallel to the longitudinal fiber axis and internally disposed to at least one outer fiber cladding layer of cladding material along the fiber length, the two fiber cores being separated by an amount of fiber cladding whereby feeding the fiber through the localized heating site causes molten droplets to pinch off of each fiber core material simultaneously and form multi-spherical molten droplets that solidify into multi-spherical particles in the fiber.

16. The method of claim 1 wherein providing a fiber including at least two fiber cores comprises providing a first semiconducting core that is electronically doped p-type and providing a second semiconducting core that is electronically doped n-type, whereby forming multi-spherical molten droplets that solidify into multi-spherical particles comprises forming multi-spherical p-n junction particles.

17. The method of claim 1 wherein feeding the fiber through a localized heating site at a heating site temperature, T, comprises feeding the fiber through a localized temperature of at least 1600° C.

18. The method of claim 1 further comprising removing the fiber cladding material to release the solid particles from the fiber.

19. The method of claim 18 further comprising passivating released solid particles to prevent agglomeration of released particles.

Assignees

• Massachusetts Inst Technology
• Univ Of Central Florida Research Foundation

Inventors

• Fink Yoel
• Abouraddy Ayman F
• Grena Benjamin Jean-Baptiste
• Gumennik Alexander
• Joannopoulos John D
• Lestoquoy Guillaume R
• Wei Lei

Classifications

• Y10T428/296

  Rubber, cellulosic or silicic material in coating · CPC title

• Y10T428/2991

  Coated · CPC title

• Y10T428/2927

  including structurally defined particulate matter · CPC title

• B29K2995/0005

  Conductive · CPC title

• D01F9/08

  of inorganic material (working or processing of metal wire B21F; from softened glass, minerals or slags C03B37/00) · CPC title