In-fiber particle generation

Patent metadata

Field	Value
Publication number	US-9512036-B2
Application number	US-201313803213-A
Country	US
Kind code	B2
Filing date	Mar 14, 2013
Priority date	Oct 26, 2010
Publication date	Dec 6, 2016
Grant date	Dec 6, 2016

Abstract

A fiber is provided, including a cladding material that is disposed along a longitudinal-axis fiber length. A plurality of spherical particles are disposed as a sequence along a longitudinal line parallel to the longitudinal fiber axis in at least a portion of the fiber length, and include a spherical particle material that is interior to the fiber cladding material and different than the fiber cladding material. To produce particles, a drawn fiber, having a longitudinal-axis fiber length and including at least one fiber core that has a longitudinal core axis parallel to the longitudinal fiber axis and that is internally disposed to at least one outer fiber cladding layer along the fiber length, is heated for a time that is sufficient to cause a fiber core to break-up into droplets sequentially disposed along the fiber core axis. Fiber cooling solidifies droplets into spherical particles interior to fiber cladding.

First claim

We claim:

1. A method for producing particles comprising:
providing a drawn fiber having a longitudinal-axis fiber length and including at least one fiber core having a longitudinal core axis parallel to the longitudinal fiber axis and internally disposed to at least one outer fiber cladding layer along the fiber length;
heating the fiber at a heating temperature, T, for a heating time, t, that is sufficient to cause at least one fiber core break up into droplets that are sequentially disposed along the fiber core axis; and
cooling the heated fiber to solidify the droplets into spherical particles that are disposed along the fiber core axis over the fiber length, interior to the fiber cladding layer, as a longitudinal sequence of spherical particles that is parallel to the longitudinal fiber axis.

2. The method of claim 1 wherein heating the fiber comprises applying the heating temperature, T, locally to sections of the fiber in sequence along the fiber length.

3. The method of claim 2 wherein heating the fiber further comprises applying tension to opposite ends of the fiber during the heating to taper fiber diameter during the heating.

4. The method of claim 1 wherein heating the fiber comprises applying the heating temperature, T, globally along the fiber length.

5. The method of claim 1 wherein heating the fiber comprises applying the heating temperature, T, as a temperature gradient along at least a portion of the fiber length.

6. The method of claim 1 wherein the heating time, t, is greater than a duration for which a fiber core viscosity is sufficiently reduced to cause instability in fiber core material due to perturbations at an interface between the fiber core material and the at least one cladding material.

7. The method of claim 1 wherein the heating time, t, is at least as long as τ fastest , which is a minimum capillary instability growth time required for the fiber core to break up into droplets during the heating duration, and which is characteristic of the fiber based on fiber cladding material, fiber core material, fiber core diameter, and the heating temperature, T.

8. The method of claim 1 wherein providing a fiber comprises:
assembling a fiber preform including at least one fiber core material encircled by at least one layer of fiber cladding material;
consolidating the fiber preform; and
drawing the consolidated preform into a fiber.

9. The method of claim 8 wherein heating the fiber comprises exposing the fiber to a heating temperature, T, that is greater than a temperature at which the preform was drawn into a fiber.

10. The method of claim 1 further comprising, after cooling the heated fiber to solidify the droplets into spherical particles, removing fiber cladding material to release the spherical particles from the fiber.

11. The method of claim 10 further comprising passivating the spherical particles to prevent agglomeration of released particles.

12. The method of claim 1 wherein providing a fiber comprises:
assembling a fiber preform including a plurality of drawn fibers each including at least one fiber core surrounded by at least one layer of fiber cladding;
consolidating the fiber preform; and
drawing the consolidated preform into a fiber including a plurality of fiber cores.

13. The method of claim 1 wherein providing a fiber comprises providing a drawn fiber including at least one core material layer cylindrically disposed around a fiber core cylinder, together internally disposed to the outer fiber cladding layer along a longitudinal-axis fiber length, whereby cooling the heated fiber to solidify the droplets into spherical particles comprises forming particles including a spherical core surrounded by at least one spherical shell.

14. The method of claim 1 wherein providing a fiber comprises providing a drawn fiber including at least two core material layers cylindrically disposed around a fiber core cylinder, together internally disposed to the outer fiber cladding layer along a longitudinal-axis fiber length, whereby cooling the heated fiber to solidify the droplets into spherical particles comprises forming particles including a spherical core surrounded by a plurality of nested spherical shells.

15. The method of claim 1 wherein providing a fiber comprises providing a drawn fiber including at least one fiber core cylinder including a plurality of distinct materials arranged among azimuthal segments of the cylinder, each segment subtending a polar angle, whereby cooling the heated fiber to solidify the droplets into spherical particles comprises forming particles including a plurality of azimuthal segments, each segment subtending a polar angle.

16. The method of claim 15 wherein the spherical particle azimuthal segments are 180° segments, forming a broken-symmetry Janus particle.

17. A method of fabricating particles, comprising:
providing a multi-material preform having at least one fiber core comprising a first material and an outer first cladding layer, comprising a second material different from the first material, outside the fiber core;
thermal fiber drawing the multi-material preform to increase a length of said multi-material preform to form an extended multi-material fiber having an extended core, and
thermally treating the extended multi-material fiber under conditions that cause a break-up of the extended core to form a plurality of core particles embedded in the outer first cladding layer.

18. The method of claim 17 , wherein the thermal fiber drawing comprises a first thermal fiber drawing step and at least a second thermal fiber drawing step, comprising:
after the first thermal fiber drawing step, arranging a plurality of multi-material fibers within a second outer cladding layer; and
performing a second thermal fiber drawing step on the arranged plurality of multi-material fibers.

19. The method of claim 17 , wherein a maximum temperature during the thermal fiber drawing is less than a maximum temperature during the thermally treating.

20. The method of claim 17 , wherein said first material comprises a chalcogenide glass and said second material comprises a thermoplastic polymer.

21. The method of claim 20 , further comprising dissolving the thermoplastic polymer after thermally treating the fiber.

22. The method of claim 17 , wherein the at least one core comprises two half cylinders each comprising a different material aligned with respect to one another to provide a cylindrical core.

23. The method of claim 22 , wherein the two half cylinders comprise a first glass and a second glass, and wherein the plurality of core particles comprise spherical particles including a first hemisphere comprising the first glass and a second hemisphere comprising the second glass.

24. The method of claim 17 , wherein the at least one fiber core comprises a plurality of fiber cores, and wherein thermally treating the fiber produces a three-dimensional distribution of fiber core particles embedded in the outer first cladding layer.

25. The method of claim 24 , wherein the three dimensional distribution of fiber core particles includes periodicity providing a standard deviation of center-to-center particle spacing less than 15% of average center-to-center particle spacing in at least a first and a second dimension transverse to a longitudinal-axis of the extended multi-material fiber.

Assignees

• Massachusetts Inst Technology
• Univ Central Florida Res Found Inc

Inventors

• Abouraddy Ayman F
• Banaei Esmaeil H
• Deng Daosheng S
• Fink Yoel
• Johnson Steven G
• Kaufman Joshua J
• Liang Xiangdong
• Shabahang Soroush
• Tao Guangming

Classifications

• B29C48/16

  Articles comprising two or more components, e.g. co-extruded layers · CPC title

• B29C48/0022

  combined with cutting · CPC title

• C03C25/26 Primary

  Macromolecular compounds or prepolymers · CPC title

• B29C48/156

  Coating two or more articles simultaneously · CPC title

• B29C2948/92704

  Temperature · CPC title