Polarizing plate and image display device including the same

Patent metadata

Field	Value
Publication number	US-10353125-B2
Application number	US-201414388153-A
Country	US
Kind code	B2
Filing date	Jun 18, 2014
Priority date	Jun 18, 2013
Publication date	Jul 16, 2019
Grant date	Jul 16, 2019

Abstract

The present disclosure relates to a polarizing plate including an adhesive layer, a primer layer and a polyethylene terephthalate film which are sequentially formed on at least one side of a polarizer, wherein the adhesive layer in the present disclosure is formed by an active energy ray-curable adhesive including a first epoxy compound of which a homopolymer has a glass transition temperature of 120° C. or higher, a second epoxy compound of which a homopolymer has a glass transition temperature of 60° C. or lower, and a cationic photopolymerization initiator, and wherein the primer layer is formed by a primer composition including one or more binder resins selected from the group consisting of polyester and polyvinyl alcohol-based resins, and one or more cross-linking agents selected from the group consisting of acrylic cross-linking agents, epoxy-based cross-linking agents and polyvinyl alcohol-based cross-linking agents.

First claim

The invention claimed is:

1. A polarizing plate comprising an adhesive layer, a primer layer, and a polyethylene terephthalate film which are sequentially formed on at least one side of a polarizer,
wherein the adhesive layer is formed by an active energy ray-curable adhesive comprising a first epoxy compound of which a homopolymer has a glass transition temperature of 120° C. to 200° C., a second epoxy compound of which a homopolymer has a glass transition temperature of 0° C. to 60° C., and a cationic photopolymerization initiator,
wherein the primer layer is formed by a primer composition comprising one or more binder resins selected from the group consisting of polyester and polyvinyl alcohol resins, and one or more cross-linking agents selected from the group consisting of acrylic cross-linking agents, epoxy-based cross-linking agents, and polyvinyl alcohol-based cross-linking agents,
wherein the polyethylene terephthalate film further comprises a low refractive index layer with a refractive index of 1.4 to 1.5 formed on one side thereof directly contacting the primer layer, or both sides thereof,
wherein the polyethylene terephthalate film having the low refractive index layer has a total refractive index of 1.48 to 1.55,
wherein the polyethylene terephthalate film has a water vapor transmission rate of 100 g/m 2 *day or less and a moisture content of 1% by weight or less, and
wherein a surface of the primer layer has a water contact angle of 40° to 100°.

2. The polarizing plate of claim 1 , wherein the active energy ray-curable adhesive comprises 100 parts by weight of the first epoxy compound, 30 parts by weight to 100 parts by weight of the second epoxy compound, and 0.5 parts by weight to 20 parts by weight of the cationic photopolymerization initiator.

3. The polarizing plate of claim 1 , wherein the first epoxy compound comprises one or more selected from the group consisting of an alicyclic epoxy compound and an aromatic epoxy compound.

4. The polarizing plate of claim 3 , wherein the first epoxy compound comprises one or more selected from the group consisting of 3,4-epoxycyclohexylmethyl-3,4′-epoxycyclohexanecarboxylate, vinyl cyclohexane dioxide, dicyclopentadiene dioxide, bis(epoxycyclopentyl) ether, bisphenol A-based epoxy compounds, and bisphenol F-based epoxy compounds.

5. The polarizing plate of claim 1 , wherein the second epoxy compound comprises one or more selected from the group consisting of alicyclic epoxy compounds and aromatic epoxy compounds.

6. The polarizing plate of claim 5 , wherein the second epoxy compound comprises one or more of glycidyl ether groups.

7. The polarizing plate of claim 6 , wherein the second epoxy compound comprises one or more selected from the group consisting of 1,4-cyclohexanedimethanoldiglycidyl ether, 1,4-butanedioldiglycidyl ether, 1,6-hexanedioldiglycidyl ether, neopentyldiglycidyl ether, resorcinol diglycidyl ether, diethylene glycol diglycidyl ether, ethylene glycol diglycidyl ether, trimethylolpropane triglycidyl ether, n-butyl glycidyl ether, 2-ethylhexyl glycidyl ether, phenyl glycidyl ether, and o-cresyl glycidyl ether.

8. The polarizing plate of claim 1 , wherein the active energy ray-curable adhesive comprises the first epoxy compound and the second epoxy compound at a weight ratio of 1:1 to 3:1.

9. The polarizing plate of claim 2 , wherein the active energy ray-curable adhesive further comprises 100 parts by weight to 400 parts by weight of an oxetane compound having at least one oxetanyl group within molecules thereof.

10. The polarizing plate of claim 1 , wherein the active energy ray-curable adhesive further comprises a vinyl-based compound, and the vinyl-based compound is contained in an amount of 0.1 parts by weight to 10 parts by weight with respect to 100 parts by weight of the total adhesive.

11. The polarizing plate of claim 10 , wherein the vinyl-based compound comprises at least one selected from the group consisting of hydroxy C 1-6 alkylvinylether and vinyl acetate.

12. The polarizing plate of claim 1 , wherein the active energy ray-curable adhesive further comprises a silane coupling agent, and the silane coupling agent is contained in an amount range of 0.1 parts by weight to 5 parts by weight with respect to 100 parts by weight of the total adhesive.

13. The polarizing plate of claim 12 , wherein the silane coupling agent comprises one or more cationic polymerizable functional groups selected from the groups consisting of an epoxy group, a vinyl group, a radical group, and combinations thereof.

14. The polarizing plate of claim 1 , wherein the active energy ray-curable adhesive further comprises radical polymerizable monomers, and the radical polymerizable monomers are contained in an amount greater than 0 parts by weight to 40 parts by weight with respect to 100 parts by weight of the total adhesive.

15. The polarizing plate of claim 14 , wherein the active energy ray-curable adhesive further comprises a photoradical polymerization initiator, and the photoradical polymerization initiator is contained in an amount of 0.5 parts by weight to 20 parts by weight with respect to 100 parts by weight of the total adhesive.

16. The polarizing plate of claim 1 , wherein the active energy ray-curable adhesive has a glass transition temperature of 80° C. to 120° C.

17. The polarizing plate of claim 1 , wherein the active energy ray-curable adhesive has a viscosity of 15 cP to 50 cP at 25° C.

18. The polarizing plate of claim 1 , wherein the polyethylene terephthalate film is disposed on one side of the polarizer, and a transparent polymer film selected from the group consisting of a triacetyl cellulose film, a cycloolefin polymer film, a polyester-based film, a polycarbonate film, and an acrylic film is disposed on the other side of the polarizer.

19. The polarizing plate of claim 18 , wherein the transparent polymer film adhered to the other side of the polarizer is a uniaxially or biaxially oriented film having a phase difference.

20. An image display device comprising the polarizing plate of claim 1 .

21. The image display device of claim 20 , wherein the image display device is a liquid crystal display (LCD) or an organic electroluminescence display.

Assignees

• Lg Chemical Ltd

Inventors

• Nam Sung-Hyun
• Seo Eun-Mi
• Nam Seung-Hee
• Lee Dae-Woong
• Rah Kyun-Il

Classifications

• C08G59/22

  Di-epoxy compounds · CPC title

• Y10T428/1073

  Cross-Sectional Technologies · mapped topic

• C09J163/10

  Epoxy resins modified by unsaturated compounds · CPC title

• C08G59/20

  characterised by the epoxy compounds used · CPC title

• G02F2202/28

  Adhesive materials or arrangements · CPC title