Carbon fiber precursor fiber bundle, production method and production device therefor, and carbon fiber and production method therefor

Patent metadata

Field	Value
Publication number	US-10308472-B2
Application number	US-201113082232-A
Country	US
Kind code	B2
Filing date	Apr 7, 2011
Priority date	Feb 13, 2004
Publication date	Jun 4, 2019
Grant date	Jun 4, 2019

Abstract

A carbon fiber precursor fiber bundle which permits easy bundling of a plurality of small tows into one bundle, is provided with a dividing capability to divide into the original small tows spontaneously at the time of firing, and is suitable for obtaining a carbon fiber that is excellent in productivity and quality. A carbon fiber precursor fiber bundle that has a degree of intermingle of 1 m −1 or less between small tows, consists of substantially straight fibers without imparted crimp, a tow of which straight fibers has a moisture content of less than 10% by mass when housed in a container, and has a widthwise dividing capability to maintain a form of a single aggregate of tows when housed in a container, taken out from the container and guided into a firing step, and to divide into a plurality of small tows in the firing step by the tension generated in the firing step.

First claim

The invention claimed is:

1. A carbon fiber precursor fiber bundle, said carbon fiber precursor fiber bundle:
having 1 m −1 or less of a degree of intermingle between a plurality of small tows based on the hook drop method with a 10 g weight; and
consisting of substantially straight fibers without imparted crimp, a tow of which straight fibers has a moisture content of 2.0% by mass or more and 5% by mass or less when housed in a container;
wherein:
the carbon fiber precursor fiber bundle has a widthwise dividing capability to maintain a form of a single aggregate of tows when housed in a container, such that when taken out from the container and guided into a firing step, the carbon fiber precursor fiber bundle spontaneously divides widthwise in the firing step into the plurality of small tows only by a tension generated in the firing step,
the aggregate of tows is formed by intermingling monofilaments between a widthwise end of a small tow and a widthwise end of an adjacent small tow by air flow,
a number of the monofilaments in each of the plurality of small tows is from 50,000 to 150,000, and
the straight fibers consist of acrylonitrile-based polymers.

2. The carbon fiber precursor fiber bundle according to claim 1 , wherein
a fineness of the monofilaments is in a range of from 0.7 dtex to 1.3 dtex, and
a total number of monofilaments in the aggregate of tows is 100,000 or more and 600,000 or less.

3. The carbon fiber precursor fiber bundle according to claim 1 , wherein a number of monofilaments undergoing adhesion between the monofilaments is 5 per 50,000 of monofilaments or less and a size of a crystal region in a direction perpendicular to the fiber axis is 1.1×10 −8 m or more.

4. The carbon fiber precursor fiber bundle according to claim 1 , wherein a strength of the monofilament is 5.0 cN/dtex or more, and a fineness unevenness (CV value) of the monofilament is 10% or less.

5. The carbon fiber precursor fiber bundle according to claim 1 , wherein an oiling agent adhesion unevenness (CV value) along a lengthwise direction is 10% or less.

6. A carbon fiber bundle obtained by firing the carbon fiber precursor fiber bundle according to claim 1 .

7. The carbon fiber precursor fiber bundle according to claim 1 , wherein the carbon fiber precursor fiber bundle is made of three or more small tows.

8. The carbon fiber precursor fiber bundle according to claim 1 , wherein said widthwise dividing capacity is capable of dividing the carbon fiber precursor fiber bundle into a plurality of small tows by the tension generated in a flame retarding step of the firing step.

9. The carbon fiber precursor fiber bundle according to claim 1 , wherein the small tows of the plurality of small tows are not intermingled.

10. The carbon fiber precursor fiber bundle according to claim 1 , wherein the small tows of the plurality of small tows are in contact with one another only at the widthwise ends thereof.

11. The carbon fiber precursor fiber bundle according to claim 1 , wherein the widthwise ends of the small tows do not overlap.

12. The carbon fiber precursor fiber bundle according to claim 1 , wherein the fibers of the carbon fiber precursor fiber bundle are non-oxidized fibers.

13. The carbon fiber precursor fiber bundle according to claim 1 , wherein the tow of straight fibers has a moisture content of more than 1.0% by mass and 5% by mass or less when housed in a container.

Assignees

• Ikeda Katsuhiko
• Shimozawa Nobuyuki
• Mitsubishi Chem Corp

Inventors

• Ikeda Katsuhiko
• Shimozawa Nobuyuki

Classifications

• D01D7/00

  Collecting the newly-spun products ({D01D5/0076 takes precedence;} collecting newly-spun products with the imparting of twist D01H) · CPC title

• D01F9/14 Primary

  by decomposition of organic filaments · CPC title

• D02J1/228

  Stretching in two or more steps, with or without intermediate steps · CPC title

• D01D5/16

  using rollers, or like mechanical devices, e.g. snubbing pins · CPC title

• Y10T428/2918

  including free carbon or carbide or therewith [not as steel] · CPC title