Reduced fouling process for the production of methyl methacrylate

Patent metadata

Field	Value
Publication number	US-10294190-B2
Application number	US-201515521421-A
Country	US
Kind code	B2
Filing date	Oct 13, 2015
Priority date	Oct 27, 2014
Publication date	May 21, 2019
Grant date	May 21, 2019

Abstract

Fouling of an MMA process is reduced by strategically removing an aqueous slip stream.

First claim

What is claimed is:

1. A process for producing methyl methacrylate (MMA) comprising: (a) contacting methacrylamide (MAM) with methanol in an aqueous reaction medium in an esterification reaction zone in the presence of an acidic raw material selected from the group consisting of sulfuric acid, oleum, and mixtures thereof, to produce a first stream comprising MMA, water, methanol, acidic raw material and methacrylic acid (MAA); (b) phase separating the first stream in a first phase separating apparatus into a first aqueous phase comprising the acidic raw material, and a first organic liquid product phase comprising: MMA, methanol and MAA; (c) taking a first organic stream from the first organic liquid product phase, and neutralizing the MAA of the first organic stream with ammonia to produce a neutralized stream comprising MMA, methanol and ammonium methacrylate; (d) optionally adding water to the neutralized stream; (e) phase separating the neutralized stream in a second phase separating apparatus into an organic layer comprising MMA and an aqueous layer comprising methanol and ammonium methacrylate, the layers having a common interface; (f) removing a polymer-removing stream from the phase separating apparatus at or below the height of the interface; and (g) removing from the second phase separating apparatus a second aqueous stream comprising a portion of the aqueous layer and from 1 to 500 ppm of a soluble polymer and wherein the second aqueous stream is recycled to the esterification reaction zone wherein the polymer-removing stream has a relative size compared to the second aqueous stream, and the relative size is from 0.1 to 7% of the size of the second aqueous stream.

2. The process of claim 1 wherein water is added to the neutralized stream.

3. The process of claim 1 wherein the relative size of the polymer-removing stream is from 0.5 to 4%, of the size of the second aqueous stream.

4. The process of claim 1 wherein the relative size of the polymer-removing stream is from 1 to 2%, of the size of the second aqueous stream.

5. The process of claim 1 wherein the concentration of soluble polymer in the second aqueous stream is less than 400, less than 250 ppm, or less than 100 ppm, based on the weight of the second aqueous stream.

6. The process of claim 1 wherein the concentration of soluble polymer in the second aqueous stream is from 2 to 400 ppm, from 5 to 250 ppm, or from 10 to 100 ppm, based on the weight of the second aqueous stream.

Assignees

• Rohm & Haas

Inventors

• Hoy Iv Stacy W
• Mendoza Joy L
• Ye Mingyu
• Maillot Philippe P

Classifications

• C07C67/20 Primary

  from amides or lactams · CPC title

• B01J19/1875

  internally, i.e. the mixture circulating inside the vessel such that the upwards stream is separated physically from the downwards stream(s) · CPC title

• B01J2219/0004

  Processes in series · CPC title

• C07C69/54

  Acrylic acid esters; Methacrylic acid esters · CPC title

• B01D3/4294

  Feed stream · CPC title