Reduced fouling process for the production of methyl methacrylate

Patent metadata

Field	Value
Publication number	US-9932291-B2
Application number	US-201515521440-A
Country	US
Kind code	B2
Filing date	Oct 13, 2015
Priority date	Oct 27, 2014
Publication date	Apr 3, 2018
Grant date	Apr 3, 2018

Abstract

Fouling of an MMA process is reduced by acidifying a stream comprising recycled components.

First claim

What is claimed is:

1. A process for producing methyl methacrylate (MMA) comprising: (a) contacting methacrylamide with methanol in an aqueous reaction medium in an esterification reaction zone in the presence of an acidic raw material comprising sulfuric acid to produce a first stream comprising MMA, water, methanol, the acidic raw material and methacrylic acid (MAA); (b) phase separating the first stream into a first aqueous stream comprising the acidic raw material, and a first organic liquid product stream comprising MMA, methanol and MAA; (c) neutralizing the MAA of the first organic liquid product stream with ammonia to produce a neutralized stream comprising MMA, methanol and ammonium methacrylate; (d) optionally adding water to the neutralized stream; (e) separating the neutralized stream into a second organic stream comprising MMA, and a second aqueous stream comprising methanol and ammonium methacrylate; (f) contacting the second aqueous stream with an acidifying agent to form an acidified aqueous stream; and (g) sending at least a portion of the acidified aqueous stream to the reaction zone, wherein the amount of acidifying agent admixed with the second aqueous stream is an amount sufficient to acidify the second aqueous stream to a pH of less than 1.75 before it reaches the reaction zone.

2. The process of claim 1 wherein the separating of step (e) comprises at least one of distillation and phase separation.

3. The process of claim 1 wherein the separating of step (e) comprises phase separation.

4. The process of claim 1 wherein the acidifying agent comprises fresh acid or acid taken from another process stream.

5. The process of claim 4 wherein the acidifying agent comprises acid from another process stream.

6. The process of claim 4 wherein the acidifying agent comprises fresh acid.

7. The process of claim 1 wherein the contacting the second aqueous stream with an acidifying agent to form an acidified aqueous stream comprises admixing the acidifying agent with the second aqueous stream via a static mixer.

8. The process of claim 3 wherein the phase separation is conducted in a decanter, the acidic raw material comprises sulfuric acid, the acidifying agent comprises sulfuric acid, and the amount of acidifying agent is an amount sufficient to acidify the second aqueous stream to a pH of less than 1.75 before it reaches the reaction zone.

9. The process of claim 8 wherein the amount of acidifying agent is an amount sufficient to acidify the second aqueous stream to a pH of less than or equal to 1.5 before it reaches the reaction zone.

Assignees

• Rohm & Haas

Inventors

• Mendoza Joy L
• Maillot Philippe P
• Ye Mingyu
• Hoy Iv Stacy W

Classifications

• C07C67/20 Primary

  from amides or lactams · CPC title

• C07C69/54

  Acrylic acid esters; Methacrylic acid esters · CPC title

• C07C67/58

  by liquid-liquid treatment · CPC title

• C07C67/48 Primary

  Separation; Purification; Stabilisation; Use of additives · CPC title

• C07C67/54

  by distillation · CPC title