Installation and process for the preparation of hydrogen cyanide

Patent metadata

Field	Value
Publication number	US-9944533-B2
Application number	US-201414905435-A
Country	US
Kind code	B2
Filing date	Jul 18, 2014
Priority date	Jul 19, 2013
Publication date	Apr 17, 2018
Grant date	Apr 17, 2018

Abstract

Present invention relates to a process and an installation ( 100 ) for the preparation of hydrogen cyanide by the Andrussow process, and more precisely for improving the conditions of mixing the reactant gases before feeding the Andrussow type reactor ( 60 ), in order to improve safety, to avoid any risk of explosion and to produce HCN in safe and efficient manner. The installation is configured in such a manner that oxygen is pre-mixed with air with a ratio comprised between 20.95% and 32.5% by volume, preferably between 25% and 30.5% by volume; methane containing gas and ammonia are simultaneously added in the pre-mixture of oxygen-enriched air in such a manner that the volumic ratio of methane to ammonia is comprised between 1.35 and 1.02 depending on the content of oxygen into air; said obtained reactant gases mixture having a temperature comprised between 80° C. and 120° C., preferably between 95° C. and 115° C. for feeding the Andrussow type reactor ( 60 ).

First claim

The invention claimed is:

1. A process for preparing hydrogen cyanide HCN by reacting, over a catalyst placed inside an Andrussow type reactor ( 60 ), a reactant gases mixture containing a methane-containing gas, ammonia and oxygen-enriched air, the process comprising before feeding the Andrussow type reactor with the reactant gases mixture, a pre-mixing step of oxygen with air followed by a simultaneous addition of methane-containing gas and ammonia into the obtained pre-mixture of oxygen-enriched air, said process comprising the steps of pre-mixing oxygen with air with a ratio comprised between 20.95% and 32.5% by volume, wherein the content of oxygen in air is progressively increased until reaching the maximum value of 32.5% by volume; simultaneously adding methane containing gas and ammonia in the pre-mixture of oxygen-enriched air in such a manner that the volumic ratio of methane to ammonia is comprised between 1.35 and 1.02 depending on the content of oxygen into air; said obtained reactant gases mixture having a temperature comprised between 80° C. and 120° C., for feeding the Andrussow type reactor ( 60 ).

2. The process according to claim 1 , wherein the volumic ratio of oxygen-enriched air to ammonia is in the range between 7 to 3.5.

3. The process according to claim 1 , wherein before pre-mixing, each gas is independently preheated, ammonia and methane-containing gas being independently preheated at a temperature between 60° C. and 100° C. ; oxygen and air being independently preheated to a temperature between 100° C. and 165° C., so that the resultant reactant gas mixture, feeding the Andrussow type reactor, is at said temperature between 80° C. and 120° C.

4. The process according to claim 1 , wherein the flow rate of the reactant gases mixture is controlled before feeding the Andrussow type reactor ( 60 ) so that it is higher than a predetermined threshold value, which depends on a flame velocity.

5. The process according to claim 1 , wherein the methane-containing gas comprises methane of purity above 94% by volume.

6. The process according to claim 1 , wherein before the preheating step and the premixing step of air with oxygen, and if the temperature of air is less than 70° C., air is washed with water, whose temperature is comprised between 15° C. and 30° C.

7. The process according to claim 1 , wherein before the preheating step and the premixing step of air with oxygen, steam is injected into air stream.

8. The process according to claim 1 , wherein each gas stream and the mixture of resultant reactant gases is filtered before feeding of Andrussow type reactor ( 60 ).

Assignees

• Arkema France

Inventors

• Bernardin Yves
• Marcarian Xavier
• Billon Romain

Classifications

• C07C67/20

  from amides or lactams · CPC title

• C07C51/06

  from carboxylic acid amides · CPC title

• Y02P20/129

  Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines · CPC title

• C07C231/12

  by reactions not involving the formation of carboxamide groups · CPC title

• C07C231/06

  from nitriles by transformation of cyano groups into carboxamide groups · CPC title