Process for the removal of rubber from TKS plant matter

Patent metadata

Field	Value
Publication number	US-10287367-B2
Application number	US-201715430938-A
Country	US
Kind code	B2
Filing date	Feb 13, 2017
Priority date	Sep 11, 2013
Publication date	May 14, 2019
Grant date	May 14, 2019

Abstract

Provided herein are organic solvent-based processes for the removal of rubber from non- Hevea plants such as TKS. By the use of the processes, solid purified rubber can be obtained that contains 0.05-0.5 weight % dirt, 0.2-1.5 weight % ash, and 0.1-4 weight % resin (when it has been dried so as to contain 0.8 weight % volatile matter).

First claim

What is claimed is:

1. A process for increasing the rubber recovery from TKS plant matter comprising:
A. utilizing briquettes comprising (i) compressed chopped TKS plant matter having an average size of 1.5″ or less, comprising bagasse, rubber, resin, residual water and (ii) no more than 5 weight % leaves, stems, crowns, and flowers, wherein the briquettes have a density that is 40-325% higher than the density of the non-compressed TKS plant matter;
B. subjecting the briquettes to an organic solvent extraction process whereby the briquettes are mixed with a co-solvent of at least one polar organic solvent and at least one non-polar organic solvent to form a slurry that contains TKS plant matter, organic solvents and 0.5-10 weight % water; and
C. processing the slurry to remove bagasse and resin and recover at least 95-99% by weight of the rubber contained within the briquettes,
wherein (B) and (C) comprise:
a. preparing a slurry from (i) the briquettes wherein the briquettes contain TKS plant matter comprising bagasse, rubber and resin, (ii) the at least one non-polar organic solvent and (iii) the at least one polar organic solvent, wherein the slurry contains 10-50% by weight TKS plant matter from the briquettes, 50-90% by weight of (ii) and (iii) combined, and 0.5-10 weight % water from the TKS plant matter;
b. removing a majority of the bagasse from the slurry to produce a miscella and a first bagasse portion;
c. optionally adding additional polar organic solvent, non-polar organic solvent or a combination thereof to the miscella to form a reduced viscosity miscella where any polar organic solvent and non-polar organic solvent may be the same or different than those utilized in (a) and where the amount of any additional polar organic solvent that is added is less than the amount that causes the rubber contained with the reduced viscosity miscella to coagulate;
d. removing 80-95 weight % of bagasse from the miscella resulting from (b) or (c) (based on the total weight of bagasse present in the miscella) to form a purified miscella and a second bagasse fraction wherein the majority of the bagasse that is removed has a particle size of less than 105 microns;
e. optionally treating the purified miscella to remove additional bagasse thereby producing a clarified rubber solution that contains 0.01-1% by weight of bagasse (based on the total weight of bagasse present in the slurry) wherein 90-99% of the additional bagasse that is removed has a particle size greater than 45 microns;
f. increasing the relative amount of polar organic solvent as compared to non-polar organic solvent within the clarified rubber solution from (e) or within the purified miscella from (d) so as to coagulate the rubber; and
g. producing solid purified rubber from the coagulated rubber wherein when said solid purified rubber contains 0.8 weight % volatile matter it also contains 0.05-0.5 weight % dirt, 0.2-1.5 weight % ash and 0.1-4 weight % resin;

wherein at least (a)-(e) are conducted at a temperature or temperatures of 10-80° C. and a pressure of 35 to 1000 kPa.

2. The process of claim 1 , wherein the briquettes contain at least one antioxidant.

3. The process of claim 1 , wherein at least one of steps (b) and (d) comprises the use of a centrifuge.

4. The process of claim 1 , wherein the briquettes contain at least one antioxidant.

5. The process of claim 1 , wherein the majority of bagasse removed from the slurry in (b) is 60-95 weight % of the bagasse contained within the slurry.

6. The process of claim 1 , wherein removing of the majority of bagasse in (b) comprises use of a screw press.

7. The process of claim 1 , wherein removing of the majority of bagasse in (b) comprises use of a counter-current extractor.

8. The process of claim 1 , wherein the TKS plant matter in the slurry has been in contact with the solvents (ii) and (iii) for 0.3 to 3 hours prior to (b).

9. The process of claim 1 , wherein the removing of 80-95 weight % of bagasse removed in (d) comprises use of a centrifuge.

10. The process of claim 1 , wherein at least a portion of at least one of the first bagasse portion and the second bagasse portion is recycled into the slurry so as to allow for transfer of additional rubber or resin that is associated with the bagasse portion(s) into the miscella that is produced in (b).

11. The process of claim 1 , wherein the compressed chopped plant matter comprises TKS roots with no more than 5 weight % of the plant material comprising leaves, crowns, stems, and flowers.

12. The process of claim 1 , wherein at least (a)-(e) are conducted at a temperature or temperatures of 10-50° C.

13. A process of claim 1 , wherein the compressed chopped TKS plant matter comprises at least 90% by weight roots from Taraxacum kok - saghyz, Scorzonera tau - saghyz, Scorzonera uzbekistanica , and combinations thereof.

14. The process of claim 1 , wherein the (ii) at least one non-polar organic solvent; and the (iii) at least one polar organic solvent are present in relative weight amounts of 50-90% and 10-50%, respectively.

15. The process of claim 1 , wherein the non-polar organic solvent and any additional non-polar organic solvent comprises hexane or cyclohexane and the polar organic solvent and any additional polar organic solvent comprises acetone.

16. The process of claim 1 , wherein the briquettes have been aged for 21-200 days after formation.

17. A process for increasing the rubber recovery from TKS plant matter comprising:
A. utilizing briquettes comprising (i) compressed chopped TKS plant matter comprising at least 90% by weight roots from Taraxacum kok - saghyz , the chopped TKS plant matter having an average size of 1.5″ or less, comprising bagasse, rubber, resin, residual water and (ii) no more than 5 weight % leaves, stems, crowns, and flowers, wherein the briquettes have a density that is 40-325% higher than the density of the non-compressed TKS plant matter;
B. subjecting the briquettes to an organic solvent extraction process whereby the briquettes are mixed with a co-solvent of at least one polar organic solvent and at least one non-polar organic solvent to form a slurry that contains TKS plant matter, organic solvents and 0.5-10 weight % water; and
C. processing the slurry to remove bagasse and resin and recover at least 95-99% by weight of the rubber contained within the briquettes,
wherein (B) and (C) comprise:
a. preparing a slurry from (i) the briquettes wherein the briquettes contain TKS plant matter comprising bagasse, rubber and resin, (ii) the at least one non-polar organic solvent and (iii) the at least one polar organic solvent, wherein the slurry contains 10-50% by weight TKS plant matter from the briquettes, 50-90% by weight of (ii) and (iii) combined, and 0.5-10 weight % water from the TKS plant matter;
b. removing a majority of the bagasse from the slurry to produce a miscella and a first bagasse portion;
c. optionally adding additional polar organic solvent, non-polar organic solvent or a combination thereof to the miscella to form a reduced viscosity miscella where any polar organic solvent and non-polar organic solvent may be the same or different than those utilized in (a) and where the amount of any additional polar organic solvent that is added is less than the amount that causes the rubber contained with the reduced viscosity miscella to coagulate;
d. removing 80-95 weight % of bagasse from the miscella resulting from (b) or (c) (based on the total weight of bagasse present in the miscella) to form a purified miscella and a second bagasse fraction wherein t

Assignees

• Bridgestone Corp

Inventors

• Huang Yingyi
• Mouri Hiroshi
• Beaulieu Michael R

Classifications

• C08L21/00

  Compositions of unspecified rubbers · CPC title

• C08C3/02

  Purification · CPC title

• C08C2/06

  Winning of rubber from solutions · CPC title

• C08L7/02

  Latex · CPC title

• C08L7/00

  Compositions of natural rubber · CPC title