Processes for the removal of rubber from non-hevea plants

Patent metadata

Field	Value
Publication number	US-9315589-B2
Application number	US-201314383379-A
Country	US
Kind code	B2
Filing date	Mar 6, 2013
Priority date	Mar 6, 2012
Publication date	Apr 19, 2016
Grant date	Apr 19, 2016

Abstract

Provided herein are organic solvent-based processes for the removal of rubber from non- Hevea plants such as guayule shrubs. By the use of the processes, solid purified rubber can be obtained that contains 0.05-0.5 weight % dirt, 0.2-1.5 weight % ash, and 0.1-4 weight % resin (when it has been dried so as to contain 0.8 weight % volatile matter).

First claim

What is claimed is:

1. A method of increasing the rubber recovery from non- Hevea plants comprising:
A. utilizing briquettes comprising (i) compressed chopped plant matter having an average size of 1.5″ or less, comprising bagasse, rubber, resin, residual water and (ii) no more than 5 weight % leaves from a non- Hevea plant, wherein the briquettes have a density that is 40-325% higher than the density of the non-compressed plant matter;
B. subjecting the briquettes to an organic solvent extraction process whereby the briquettes are mixed with at least one polar organic solvent and at least one non-polar organic solvent to form a slurry that contains plant matter, organic solvents and 0.5-10 weight % water; and
C. processing the slurry to remove bagasse and resin and recover at least 95-99% by weight of the rubber contained within the briquettes.

2. The method of claim 1 , wherein the chopped plant matter is from guayule shrubs and (B) and (C) comprise:
a. preparing a slurry from (i) the briquettes wherein the briquettes contain plant matter from a non- Hevea plant comprising bagasse, rubber and resin, (ii) the least one non-polar organic solvent and (iii) the least one polar organic solvent, wherein the slurry contains 10-50% by weight plant matter from the briquettes, 50-90% by weight of (ii) and (iii) combined, and 0.5-10 weight % water from the plant matter;
b. removing a majority of the bagasse from the slurry to produce a miscella and a first bagasse portion;
c. optionally adding additional polar organic solvent, non-polar organic solvent or a combination thereof to the miscella to form a reduced viscosity miscella where any polar organic solvent and non-polar organic solvent may be the same or different than those utilized in (a) and where the amount of any additional polar organic solvent that is added is less than the amount that causes the rubber contained with the reduced viscosity miscella to coagulate;
d. removing 80-95 weight % of bagasse from the miscella resulting from (b) or (c) (based on the total weight of bagasse present in the miscella) to form a purified miscella and a second bagasse fraction wherein the majority of the bagasse that is removed has a particle size of less than 105 microns;
e. optionally treating the purified miscella to remove additional bagasse thereby producing a clarified rubber solution that contains 0.01-1% by weight of bagasse (based on the total weight of bagasse present in the slurry) wherein 90-99% of the additional bagasse that is removed has a particle size greater than 45 microns;
f. increasing the relative amount of polar organic solvent as compared to non-polar organic solvent within the clarified rubber solution so as to coagulate the rubber; and
g. producing solid purified rubber from the coagulated rubber where when said solid purified rubber contains 0.8 weight % volatile matter it also contains 0.05-0.5 weight % dirt, 0.2-1.5 weight % ash and 0.1-4 weight % resin;
wherein at least (a)-(e) are conducted at a temperature or temperatures of 10-80° C. and a pressure of 35 to 1000 kPa.

3. The method of claim 2 , wherein the briquettes contain at least one antioxidant.

4. The method of claim 2 , wherein at least one of steps (b) and (d) comprises the use of a centrifuge.

5. The method of claim 2 , wherein removing of the majority of bagasse in (b) comprises use of a screw press.

6. The method of claim 2 , wherein the non-polar organic solvent and additional non-polar organic solvent comprises hexane or cyclohexane and the polar organic solvent and any additional polar organic solvent comprises acetone.

7. The method of claim 2 , wherein the (ii) at least one non-polar organic solvent of (a); and the (iii) at least one polar organic solvent of (a) are present in relative weight amounts of 50-90% and 10-50%, respectively.

8. An organic solvent-based process for the removal of rubber from non- Hevea plants comprising:
a. utilizing a slurry containing (i) non- Hevea plant matter, the plant matter comprising bagasse, rubber and resin; (ii) at least one non-polar organic solvent; and
(iii) at least one polar organic solvent, wherein the slurry contains 10-50% by weight plant matter, 50-90% by weight of (ii) and (iii) combined, and 0.5-10 weight % water from the plant matter;
b. removing a majority of the bagasse from the slurry to produce a miscella and a first bagasse portion;
c. optionally adding additional polar organic solvent, non-polar organic solvent or a combination thereof to the miscella to form a reduced viscosity miscella where any polar organic solvent and non-polar organic solvent may be the same or different than those utilized in (a) and where the amount of any additional polar organic solvent that is added is less than the amount that causes the rubber contained with the reduced viscosity miscella to coagulate;
d. removing 80-95 weight % of bagasse from the miscella resulting from (b) or (c) (based on the total weight of bagasse present in the miscella) to form a purified miscella and a second bagasse fraction wherein the majority of the bagasse that is removed has a particle size of less than 105 microns;
e. optionally treating the purified miscella to remove additional bagasse thereby producing a clarified rubber solution that contains 0.01-1% by weight of bagasse additional bagasse that is removed has a particle size greater than 45 microns;
f. increasing the relative amount of polar organic solvent as compared to non-polar organic solvent within the clarified rubber solution so as to coagulate the rubber; and
g. producing solid purified rubber from the coagulated rubber where when said solid purified rubber contains 0.8 weight % volatile matter it also contains 0.05-0.5 weight % dirt, 0.2-1.5 weight % ash and 0.1-4 weight % resin;
wherein at least (a)-(e) are conducted at a temperature or temperatures of 10-80° C. and a pressure of 35 to 1000 kPa.

9. The process of claim 8 , wherein the (i) non- Hevea plant matter comprises guayule plant matter.

10. The process of claim 8 , wherein the majority of bagasse removed from the slurry in (b) is 60-95 weight % of the bagasse contained within the slurry.

11. The process of claim 8 , wherein removing of the majority of bagasse in (b) comprises use of a screw press.

12. The process of claim 8 , wherein removing of the majority of bagasse in (b) comprises use of a counter-current extractor and the majority is 70-95 weight %.

13. The process of claim 8 , wherein the plant matter in the slurry has been in contact with the solvents (ii) and (iii) for 0.3 to 3 hours prior to (b).

14. The process of claim 8 , wherein the removing in (d) comprises use of a centrifuge.

15. The process of claim 14 , wherein the centrifuge is a disk centrifuge operated a speed sufficient to generate a g force of 4,000-12,000.

16. The process of claim 8 , wherein at least a portion of at least one of the first bagasse portion and the second bagasse portion is recycled into the slurry, allowing for transfer of additional rubber or resin that is associated with the bagasse portion(s) into the miscella that is produced in (b).

17. The process of claim 8 , wherein the plant matter comprises chopped guayule shrub including bark and woody tissue with no more than 5 weight % of the plant material comprising leaves.

18. The process of claim 8 , wherein at least (a)-(e) are conducted at a temperature or temperatures of 10-50° C.

19. The process of claim 8 , wherein the non-polar organic solvent and any additional non-polar organic solvent comprises

Assignees

• Bridgestone Corp

Inventors

• Huang Yingyi
• Smale Mark
• White Robert
• Mouri Hiroshi
• Cole William

Classifications

• C08C2/06 Primary

  Winning of rubber from solutions · CPC title

• C08C3/02 Primary

  Purification · CPC title

• C08C1/14

  Coagulation · CPC title

• C08G83/00

  Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00 · CPC title

• C08C4/00

  Treatment of rubber before vulcanisation, not provided for in groups C08C1/00 - C08C3/02 · CPC title