Polymer-carbon composites for temperature-dependent electrical switching applications

Patent metadata

Field	Value
Publication number	US-10276286-B2
Application number	US-201615065579-A
Country	US
Kind code	B2
Filing date	Mar 9, 2016
Priority date	Mar 9, 2016
Publication date	Apr 30, 2019
Grant date	Apr 30, 2019

Abstract

Disclosed here is a method for sensing temperature-dependent electrical switching response, comprising: exposing a polymer-carbon composite to a temperature change, wherein the polymer-carbon composite comprises (a) a semi-conductive or conductive carbon network intercalated with (b) a polymer matrix, wherein the carbon network comprises at least one covalently bonded carbon material, and wherein the polymer matrix comprises at least one polymer having a net electron withdrawing character and adapted to apply a gating effect on the conductive carbon; and detecting a change in electrical conductivity of the polymer-carbon composite of at least three orders of magnitude. Also disclosed is a smart switching device comprising the polymer-carbon composite and a switch triggerable by an increase or decrease in electrical conductivity of the polymer-carbon composite of at least three orders or magnitude.

First claim

What is claimed is:

1. A method for sensing temperature-dependent electrical switching response, comprising: exposing a polymer-carbon composite to a temperature change, wherein the polymer-carbon composite comprises (a) a semi-conductive or conductive carbon network intercalated with (b) a polymer matrix, wherein the carbon network comprises at least one covalently bonded carbon material, and wherein the polymer matrix comprises at least one polymer having a net electron withdrawing character and adapted to apply a gating effect on the carbon network; and detecting a change in electrical conductivity of the polymer-carbon composite of at least three orders of magnitude.

2. The method of claim 1 , wherein the carbon network comprises carbon nanotube bundles covalently crosslinked by carbon nanoparticles.

3. The method of claim 1 , wherein the carbon network comprises graphene sheets covalently crosslinked by carbon bonds.

4. The method of claim 1 , wherein the polymer matrix comprises at least one polymer selected from the group consisting of polysiloxanes, polyurethanes, epoxy resins, fluoropolymers, polyolefins, and acrylate polymers.

5. The method of claim 1 , wherein the polymer matrix comprises polysiloxane.

6. The method of claim 1 , wherein the polymer-carbon composite is a monolith having at least one dimension of 1 cm or more.

7. The method of claim 1 , wherein the polymer-carbon composite is insulating at a first temperature below Tg of the polymer and is semiconducting or conducting at a second temperature above Tg of the polymer, and wherein the difference between the first temperature and the second temperature is 50° C. or less.

8. The method of claim 1 , wherein the detected change in electrical conductivity of the polymer-carbon composite is substantially free of hysteresis over at least 10 cycles.

9. The method of claim 1 , wherein the detected change in electrical conductivity of the polymer-carbon composite is at least four orders of magnitude.

10. The method of claim 1 , further comprising sending a warning signal or an actuation signal when the electrical conductivity exceeds or drops below a predetermined threshold.

11. A smart switching device comprising a polymer-carbon composite comprising (a) a semi-conductive or conductive carbon network intercalated with (b) a polymer matrix, wherein the carbon network comprises at least one covalently-bonded carbon material, and wherein the polymer matrix comprises at least one polymer having a net electron withdrawing character and adapted to apply a gating effect on the carbon network, and a switch triggerable by an increase or decrease in electrical conductivity of the polymer-carbon composite of at least three orders or magnitude.

12. The smart switching device of claim 11 , wherein the carbon network comprises carbon nanotube bundles covalently crosslinked by carbon nanoparticles.

13. The smart switching device of claim 11 , wherein the carbon network comprises graphene sheets covalently crosslinked by carbon bonds.

14. The smart switching device of claim 11 , wherein the polymer matrix comprises at least one polymer selected from the group consisting of polysiloxanes, polyurethanes, epoxy resins, fluoropolymers, polyolefins, and acrylate polymers.

15. The smart switching device of claim 11 , wherein the polymer matrix comprises polysiloxane.

16. The smart switching device of claim 11 , wherein the polymer-carbon composite is a monolith having at least one dimension of 1 cm or more.

17. The smart switching device of claim 11 , wherein the polymer-carbon composite is insulating at a first temperature below Tg of the polymer and is semiconducting or conducting at a second temperature above Tg of the polymer, and wherein the difference between the first temperature and the second temperature is 50° C. or less.

18. The smart switching device of claim 11 , wherein the switch is triggerable by an increase or decrease in electrical conductivity of the polymer-carbon composite of at least four orders or magnitude.

19. A warning system comprising the smart switching device of claim 11 connected to a warning device configured to produce a warning signal when the electrical conductivity exceeds or drops below a predetermined threshold.

20. An actuation system comprising the smart switching device of claim 11 connected to an actuation device configured to produce an actuation signal when the electrical conductivity exceeds or drops below a predetermined threshold.

Assignees

• L Livermore Nat Security Llc

Inventors

• Lewicki James
• Worsley Marcus A

Classifications

• C08J2383/04

  Polysiloxanes · CPC title

• H01C7/008 Primary

  Thermistors (H01C7/02 - H01C7/06 take precedence) · CPC title

• H01H37/32

  Thermally-sensitive members · CPC title

• H01B1/24

  the conductive material comprising carbon-silicon compounds, carbon or silicon · CPC title

• C08J5/005

  Reinforced macromolecular compounds with nanosized materials, e.g. nanoparticles, nanofibres, nanotubes, nanowires, nanorods or nanolayered materials · CPC title