Method of storing electron hole pairs

Patent metadata

Field	Value
Publication number	US-10205208-B2
Application number	US-201514734403-A
Country	US
Kind code	B2
Filing date	Jun 9, 2015
Priority date	Aug 8, 2011
Publication date	Feb 12, 2019
Grant date	Feb 12, 2019

Abstract

A method and device for harvesting and storing solar energy is provided. The device converts solar energy to electrical energy via the photovoltaic effect. The device includes a pair of electrodes, at least one of which is transparent to allow solar energy to pass through. A medium is disposed between the electrodes which exhibits a combination of photovoltaic and ferroelectric properties. When solar energy passes through the transparent electrode and is received by the medium, electron-hole pairs establish a voltage potential between electrodes in the device via the photovoltaic effect. The voltage potential may be retained and the mobile charge may be stored in the absence of solar energy via the ferroelectric effect.

First claim

We claim:

1. A method of storing electron hole pairs generated from light energy, the method comprising the steps of:
providing a transparent electrode having an outer surface directable towards a source of incident light and an inner surface;
positioning a second electrode opposite from the transparent electrode;
disposing a medium between the transparent electrode and the second electrode, the medium including a semiconductor layer adjacent to the transparent electrode such that the incident light passing through the transparent electrode engages the semiconductor layer and a membrane layer disposed between the semiconductor layer and the second electrode;
exposing the transparent electrode to incident light having the light energy, the medium receiving the light energy passing through the transparent electrode;
generating electron-hole pairs in the medium from the light energy of the incident light;
injecting holes of each electrode hole pair into the transparent electrode;
retaining the electrons of each electrode hole pair in the medium, such that a voltage potential is established between the transparent electrode and the second electrode; and
storing the holes of each electrode hole pair in the transparent electrode and the electrons of each electrode hole pair in the medium in electrical contact with the second electrode so as to maintain the voltage potential between the transparent electrode and the second electrode when the incident light is removed.

2. The method of claim 1 wherein the electron-hole pairs are generated in the semiconductor material via photovoltaic effect.

3. The method of claim 2 wherein the medium includes a ferroelectric material which operates to maintain the voltage potential when the incident light is removed.

4. The method of claim 1 wherein the semiconductor layer includes:
a dipolar aprotic solvent;
a plurality of ferroelectric particles dissolved in the dipolar aprotic solvent; and
a plurality of semiconductor particles mixed in the solution of ferroelectric particles and dipolar aprotic solvent; and

wherein the membrane layer includes:
an anhydrous aprotic solvent;
a plurality of ferroelectric particles dissolved in the anhydrous aprotic solvent; and
an electrolyte mixed in the solution of ferroelectric particles and anhydrous aprotic solvent.

5. A method of harvesting and storing solar energy, the method comprising the steps of:
providing a transparent electrode having an outer surface directable towards a source of incident light and an inner surface;
positioning a second electrode opposite from the transparent electrode;
disposing a medium between the transparent electrode and the second electrode, the medium including a semiconductor layer adjacent to the inner surface of the transparent electrode such that the incident light passing through the transparent electrode engages the semiconductor layer and a membrane layer disposed between the semiconductor layer and the second electrode;
exposing the medium to incident light passing through the transparent electrode;
generating electron-hole pairs via photovoltaic effect responsive to solar energy being supplied by the incident light absorbed within the medium;

injecting holes of each electrode hole pair into the transparent electrode and retaining the electrons of each electrode hole pair a in the medium so as to establish an ionic concentration gradient in the medium responsive to the electron-hole pair generation; and
maintaining the ionic concentration within the medium via ferroelectric effect so as to store the solar energy in the device as a voltage potential between the transparent electrode and the second electrode when the incident light no longer engages the transparent electrode.

Assignees

• Wisconsin Alumni Res Found

Inventors

• Jiang Hongrui
• Li Chensha
• Lo Chi-Wei

Classifications

• H01M10/465

  with solar battery as charging system · CPC title

• H01M10/0565

  Polymeric materials, e.g. gel-type or solid-type · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01G9/2045 Primary

  comprising a semiconductor electrode comprising elements of the fourth group of the Periodic Table with or without impurities, e.g. doping materials · CPC title

• H01M14/005 Primary

  Photoelectrochemical storage cells (light sensitive devices H01G9/20, semiconductors sensitive to light H10F) · CPC title