Tritertbutyl aluminum reactants for vapor deposition

US10118828B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-10118828-B2
Application numberUS-201615239389-A
CountryUS
Kind codeB2
Filing dateAug 17, 2016
Priority dateOct 2, 2015
Publication dateNov 6, 2018
Grant dateNov 6, 2018

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  1. Title

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  2. Abstract

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  3. Assignees and inventors

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  4. Key dates

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  5. First independent claim

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  6. CPC / IPC classifications

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  7. Citations and related patents

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Abstract

Official abstract text for this publication.

Aluminum (Al) hydrocarbon precursor compositions are provided that can be used for vapor deposition of transition metal carbide thin films, for example aluminum-doped transition metal carbide thin films such as Al-doped titanium carbide thin films. In some embodiments, the precursor compositions comprise one or more isomers of tritertbutyl aluminum (TTBA). In some embodiments the precursor compositions comprise at least 50% of Isomer 1 of TTBA, at least 50% of Isomer 2 of TTBA, or at least 20% of a combination of Isomer 1 and Isomer 2, where Isomer 1 has the formula Al(tert-Bu) 2 (iso-Bu) and Isomer 2 has the formula Al(tert-Bu)(iso-Bu) 2 . A container containing a precursor composition comprising at least 50% of Isomer 1 or Isomer 2 or at least 20% of a combination of Isomer 1 and 2 of TTBA can be attached to a vapor deposition reactor and used to deposit transition metal carbide thin films such as Al-doped titanium carbide thin films by atomic layer deposition or chemical vapor deposition.

First claim

Opening claim text (preview).

What is claimed is: 1. A vapor deposition precursor composition comprising at least 50% Isomer 1, at least 50% Isomer 2, or greater than 20% of a combination of Isomer 1 and Isomer 2 of Al(tert-Bu) 3 (TTBA), wherein Isomer 1 has the formula Al(tert-Bu) 2 (iso-Bu) and Isomer 2 has the formula Al(tert-Bu)(iso-Bu) 2 . 2. The composition of claim 1 comprising at least 70% Isomer 1. 3. The composition of claim 1 comprising at least 80% Isomer 1. 4. The composition of claim 1 comprising at least 70% Isomer 2. 5. The composition of claim 1 comprising greater than 50% of a combination of Isomer 1 and Isomer 2. 6. The composition of claim 1 comprising greater than 80% of a combination of Isomer 1 and Isomer 2. 7. The composition of claim 1 comprising at least 80% Isomer 2. 8. The composition of claim 1 , wherein the composition further comprises Al(tert-Bu) 3 . 9. The composition of claim 1 , wherein the composition does not comprise Isomer 3 wherein Isomer 3 has the formula Al(iso-Bu) 3 . 10. The composition of claim 1 , additionally comprising Isomer 3 of Al(tert-Bu) 3 , wherein Isomer 3 has the formula Al(iso-Bu) 3 . 11. The composition of claim 10 , wherein the composition comprises at most 5% Isomer 3. 12. A container configured to be attached to a deposition reactor, the container comprising a composition comprising at least 50% Isomer 1, at least 50% Isomer 2 or at least 20% of a combination of Isomer 1 and Isomer 2 of Al(tert-Bu) 3 , wherein Isomer 1 has the formula Al(tert-Bu) 2 (iso-Bu) and Isomer 2 has the formula Al(tert-Bu)(iso-Bu) 2 . 13. The container of claim 12 , wherein the composition comprises at least 70% Isomer 1. 14. The container of claim 12 , wherein the composition comprises at least 90% Isomer 1. 15. The container of claim 12 , wherein the composition comprises at least 70% Isomer 2. 16. The container of claim 12 , wherein the composition comprises at least 90% Isomer 2. 17. The container of claim 12 , wherein the composition comprises at least 50% of a combination of Isomer 1 and Isomer 2. 18. The container of claim 12 , wherein the composition comprises at least 80% of a combination of Isomer 1 and Isomer 2. 19. The container of claim 12 , wherein the composition comprises only a combination of Isomer 1 and Isomer 2. 20. The container of claim 12 , wherein the composition additionally comprises Isomer 3 of Al(tert-Bu) 3 , wherein Isomer 3 has the formula Al(iso-Bu) 3 . 21. The container of claim 20 , wherein the composition comprises at most 5% Isomer 3.

Assignees

Inventors

Classifications

  • Atomic layer deposition [ALD] · CPC title

  • C23C16/32Primary

    Carbides · CPC title

  • C01B32/921Primary

    Titanium carbide · CPC title

  • C01B31/305Primary

    Chemistry & Metallurgy · mapped topic

  • characterized by the use of precursors specially adapted for ALD · CPC title

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What does patent US10118828B2 cover?
Aluminum (Al) hydrocarbon precursor compositions are provided that can be used for vapor deposition of transition metal carbide thin films, for example aluminum-doped transition metal carbide thin films such as Al-doped titanium carbide thin films. In some embodiments, the precursor compositions comprise one or more isomers of tritertbutyl aluminum (TTBA). In some embodiments the precursor comp…
Who is the assignee on this patent?
Asm Ip Holding Bv
What technology area does this patent fall under?
Primary CPC classification C23C16/32. Mapped technology areas include Chemistry & Metallurgy.
When was this patent published?
Publication date Tue Nov 06 2018 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 6 related publications on this page (citations in our corpus or others sharing the same primary CPC).