Ink composition for light sintering, wiring board using same and manufacturing method therefor

Patent metadata

Field	Value
Publication number	US-10091875-B2
Application number	US-201515301341-A
Country	US
Kind code	B2
Filing date	Apr 1, 2015
Priority date	Apr 1, 2014
Publication date	Oct 2, 2018
Grant date	Oct 2, 2018

Abstract

The present invention relates to an ink composition for light sintering, a wiring board using the same, and a method of fabricating the wiring board. The present invention aims to provide formation of a wiring pattern without damage to thin and soft wiring boards such as a flexible printed circuit board. The present invention provides an ink composition for light sintering including copper oxide nanoparticles having copper oxide films, a reducing agent for reducing copper oxidized by light irradiation to form copper nanoparticles, a dispersing agent, a binder, and a solvent.

First claim

What is claimed is:

1. An ink composition for light sintering, comprising:
copper oxide nanoparticles having copper oxide films on surfaces of copper nanoparticles;
a reducing agent for forming copper nanoparticles by reducing copper oxidized by light irradiation comprising (i) an aldehyde-based compound, (ii) an acid comprising ascorbic acid, (iii) a phosphorous compound, (iv) a metallic reducing agent, (v) p-benzoquinone, (vi) hydroquinone, or (vii) anthraquinone;
a dispersing agent;
a binder;
a solvent; and
silver oxide;
wherein a composition ratio of the silver oxide: the copper oxide nanoparticles is 0.1: 9.9 to 4:6.

2. The ink composition according to claim 1 , wherein the copper oxide nanoparticles are formed by coating surfaces of copper nanoparticles with a copper oxide film so as to have a thickness of 500 nm or less and have a particles size of less than 1 μm.

3. The ink composition according to claim 2 , wherein the dispersing agent comprises an amine-based polymeric dispersing agent, a hydrocarbon-based polymeric dispersing agent having a carboxylic acid group, or a polymeric dispersing agent having a polar group.

4. The ink composition according to claim 3 , wherein the binder comprises PVP, PVA, PVC, a cellulose-based resin, a polyvinyl chloride-based resin, a copolymerized resin, a polyvinyl alcohol-based resin, a polyvinyl pyrrolidone-based resin, an acrylic resin, a vinyl acetate-acrylic ester copolymer resin, a butyral resin, an alkyd resin, an epoxy resin, a phenolic resin, a rosin ester resin, a polyester resin, or silicone.

5. The ink composition according to claim 4 , wherein the solvent comprises ethylene glycol (EG), diethylene glycol (DEG), dibasic ester (DBE), carbitol acetate (CA), dipropylene glycol methyl ether (DPM or DPGME), butyl carbitol acetate (BCA), butyl carbitol (BC), Texanol, terpineol, or butyl acrylate (BA).

6. The ink composition according to claim 1 , wherein the silver oxide and the copper oxide nanoparticles, except for the solvent, are comprised in an amount of 70 to 94% by weight.

7. The ink composition according to claim 1 , wherein a powder size of the silver oxide is 2 μm or less and the copper oxide nanoparticles have D50 of 900 nm or less and Dmax of 2 μm or less.

8. The ink composition according to claim 1 , further comprising pure copper particles, on exteriors of which an oxidation resistant film is formed.

9. The ink composition according to claim 8 , wherein a composition ratio of the pure copper particles: the copper oxide nanoparticles is 9:1 to 1:9.

10. The ink composition according to claim 8 , wherein the pure copper particles are spherical particles having D50 of 2 μm or less or plate-shaped particles having D50of 4 μm or less, and the copper oxide nanoparticles are core-shell type particles on which a copper oxide film is formed so as to have a thickness of 50 nm or less.

11. The ink composition according to claim 8 , wherein the pure copper particles and the copper oxide nanoparticles, except for the solvent, are comprised in an amount of 70 to 94% by weight.

12. A wiring board comprising
a wiring pattern comprising a board body coated with an ink composition of claim 1 .

13. The wiring board according to claim 12 , wherein the ink composition for light sintering further comprises silver oxide.

14. The wiring board according to claim 12 , wherein the ink composition for light sintering further comprises pure copper particles, on exteriors of which an oxidation resistant film is formed.

Assignees

• Korea Electronics Technology

Inventors

• Kim Yoonjin
• Cho Jinwoo
• Shin Kwonwoo
• Seo Yonggon
• Kim Yeonwon
• Jang Sanghyeon
• Jo Namje

Classifications

• H05K2201/032

  Materials · CPC title

• B22F2301/10

  Copper · CPC title

• H01B1/20

  Conductive material dispersed in non-conductive organic material {(organic macromolecular compounds or compositions C08)} · CPC title

• C09D11/52

  Electrically conductive inks · CPC title

• B22F2302/25

  Oxide · CPC title