Thermally stable materials, cutter elements with such thermally stable materials, and methods of forming the same

Patent metadata

Field	Value
Publication number	US-10077608-B2
Application number	US-201213717116-A
Country	US
Kind code	B2
Filing date	Dec 17, 2012
Priority date	Dec 30, 2011
Publication date	Sep 18, 2018
Grant date	Sep 18, 2018

Abstract

A thermally stable ultra-hard material, a cutting element incorporating such thermally stable ultra-hard material, and methods for forming the same. A thermally stable ultra-hard diamond element is combined with a second ultra-hard material volume forming an assembly. One or more surfaces of the thermally stable diamond element that face the second diamond volume are coated with a coating prior to combining the thermally stable diamond element with the second diamond volume. The assembly is sintered at high pressure and high temperature to form PCD from the second diamond volume.

First claim

What is claimed is:

1. A method for making an ultra-hard construction comprising:
applying a coating on a surface of a thermally stable ultra-hard element having a theoretical density of at least 98%, wherein the coating comprises a metal solvent catalyst;
combining the thermally stable ultra-hard element with a second ultra-hard material volume to form an assembly, with the coated surface of the thermally stable element facing the second ultra-hard material volume; and
sintering the assembly at high pressure and high temperature wherein the coating melts to form a slip plane during said sintering allowing the thermally stable ultra-hard element to shift relative to the second ultra-hard material volume during sintering;
wherein sintering the assembly comprises sintering the second ultra hard material volume in the presence of a catalyst material to promote the formation of a sintered ultra-hard element, and wherein the coating comprises a melting temperature that is higher than a melting temperature of the catalyst material,
wherein during sintering the melted coating remains substantially between the thermally stable ultra-hard element and the second ultra-hard material volume,
wherein the thermally stable ultra-hard element is bonded to the sintered ultra-hard element to form an ultra-hard body having a working surface and/or a cutting edge, and
wherein the thermally stable ultra-hard element forms at least a portion of the working surface and/or the cutting edge of the ultra-hard body.

2. The method of claim 1 , wherein the thermally stable ultra-hard element is a thermally stable diamond element having a diamond volume content of at least 90%.

3. The method of claim 2 , further comprising melting the coating during the sintering.

4. The method of claim 2 , wherein the thermally stable diamond element comprises a material microstructure comprising bonded-together diamond crystals substantially devoid of interstitial regions between the diamond crystals and has a diamond volume content of at least 98%.

5. The method of claim 4 , further comprising forming the thermally stable diamond element by phase-transforming graphite into diamond during a first high pressure high temperature sintering process at a temperature of about 1600-2500° C. and a pressure of about 100-160 kbar, prior to sintering the assembly.

6. The method of claim 2 , further comprising forming the thermally stable diamond element by sintering a mixture of diamond particles in the presence of a carbonate catalyst material to form a material microstructure comprising bonded-together diamond crystals and interstitial spaces between the diamond crystals, with the carbonate catalyst material residing in the interstitial spaces.

7. The method of claim 2 , wherein the thermally stable diamond element has a diamond volume content of at least 95%.

8. The method of claim 1 , further comprising shrinking the second ultra-hard volume relative to the thermally stable ultra-hard element during the sintering.

9. The method of claim 1 , further comprising infiltrating the coating in substantially one direction into the second ultra-hard material volume and away from the thermally stable element during sintering.

10. The method of claim 1 , further comprising mounting the ultra-hard construction on a bit body.

11. The method of claim 1 , wherein the melting temperature of the coating is below the maximum temperature reached during sintering.

12. The method of claim 1 , wherein said bond is formed during cooling of said melted coating.

13. The method of claim 1 , wherein the coating comprises at least one of a cobalt, iron, or nickel and combinations thereof.

14. A method for making a diamond construction comprising:
applying a coating on a surface of a thermally stable diamond element having a theoretical density of at least 98% and a diamond volume content of at least 90%;
combining the thermally stable diamond element with a second diamond volume to form an assembly, with the coated surface of the thermally stable element facing the second diamond volume, wherein the second diamond volume comprises a diamond powder, and wherein the coating comprises a metal solvent catalyst;
sintering the assembly at high pressure and high temperature in the presence of a catalyst material to form a polycrystalline diamond element from the diamond powder, wherein sintering comprises melting the catalyst material;
melting the coating during the sintering, wherein the coating melts after the catalyst material melts, and wherein melting the coating comprises forming a slip plane between the thermally stable diamond element and the second diamond volume during the sintering, allowing the thermally stable element and the second diamond volume to shift relative to each other along the melted coating forming the slip plane,
wherein during sintering the melted coating remains substantially between the thermally stable diamond and the second diamond volume; and
cooling the coating to bond the polycrystalline diamond element to the thermally stable diamond element to form a diamond body having a working surface and/or a cutting edge, wherein the thermally stable diamond element forms at least a portion of the working surface or the cutting edge of the diamond body.

15. The method of claim 14 , further comprising mounting the diamond construction on a bit body.

16. The method of claim 14 , wherein the coating comprises a material having a melting point above the melting point of the catalyst material and below the maximum temperature reached during sintering.

Assignees

• Smith International

Inventors

• Belnap J Daniel

Classifications

• B01J3/06 Primary

  Processes using ultra-high pressure, e.g. for the formation of diamonds; Apparatus therefor, e.g. moulds or dies (B01J3/04 takes precedence) · CPC title

• B24D3/00

  Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents · CPC title

• E21B10/567 Primary

  with preformed cutting elements mounted on a distinct support, e.g. polycrystalline inserts · CPC title

• B24D18/00

  Manufacture of grinding tools {or other grinding devices}, e.g. wheels, not otherwise provided for · CPC title