Polycrystalline diamond compact including substantially single-phase polycrystalline diamond body, methods of making same, and applications therefor

Patent metadata

Field	Value
Publication number	US-9254554-B1
Application number	US-201213397977-A
Country	US
Kind code	B1
Filing date	Feb 16, 2012
Priority date	Feb 16, 2012
Publication date	Feb 9, 2016
Grant date	Feb 9, 2016

Abstract

Embodiments of the invention relate to polycrystalline diamond compacts (“PDC”) exhibiting enhanced diamond-to-diamond bonding. In an embodiment, PDC includes a sintered substantially single-phase polycrystalline diamond (“PCD”) body consisting essentially of bonded-together diamond grains exhibiting a morphology different than that of a PCD body formed by sintering diamond crystals. A substrate is bonded to the sintered substantially single-phase PCD body. Other embodiments are directed to methods of forming such PDCs, and various applications for such PDCs in rotary drill bits, bearing apparatuses, and wire-drawing dies.

First claim

What is claimed is:

1. A method of fabricating a polycrystalline diamond compact, the method comprising:
forming a sintered substantially single-phase polycrystalline diamond body;
disposing at least two layers comprising diamond particles between the sintered substantially single-phase polycrystalline diamond body and a substrate; and
sintering the at least two layers to bond the substrate to at least one of the at least two layer and bond the sintered substantially single-phase polycrystalline diamond body to at least one of the at least two layers.

2. The method of claim 1 , further comprising:
forming recesses in an interfacial surface of the sintered substantially single-phase polycrystalline diamond body by laser ablating diamond material from the interfacial surface of the sintered substantially single-phase polycrystalline diamond body; and
wherein bonding the sintered substantially single-phase polycrystalline diamond body to a substrate comprises infiltrating the recesses with an infiltrant from the substrate.

3. The method of claim 1 , further comprising converting the at least two layers of diamond particles into an intermediate polycrystalline diamond region that is bonded to the sintered substantially single-phase polycrystalline diamond body and is also bonded to the substrate, the intermediate polycrystalline diamond region including a plurality of bonded diamond grains defining a plurality of interstitial regions having a metal-solvent catalyst disposed therein.

4. The method of claim 1 , wherein disposing at least two layers comprising diamond particles between the sintered substantially single-phase polycrystalline diamond body and the substrate comprises providing:
a first layer adjacent to the substrate including fine-sized diamond particles exhibiting a fine-sized average particle size;
a second layer adjacent to the first layer including medium-sized diamond particles exhibiting a medium-sized average particle size greater than the fine-sized average particle size;
a third layer between the second layer and the sintered substantially single-phase polycrystalline diamond body including coarse-sized diamond particles exhibiting a coarse-sized average particle size greater than the medium-sized average particle size; and
wherein the coarse-sized average particle size is at least about 2 times that of the medium-sized average particle size, and the coarse-sized average particle size is at least about 5 times that of the fine-sized average particle size.

5. The method of claim 4 wherein bonding the sintered substantially single-phase polycrystalline diamond body to the substrate comprises:
infiltrating the first layer with a first amount of a metal-solvent catalyst and the second layer with a second amount of the metal-solvent catalyst that is less than the first amount, and the third layer with a third amount of the metal-solvent catalyst that is less than the second amount.

6. The method of claim 1 , further comprising disposing at least two layers comprising non-diamond carbon particles between the substrate and the sintered substantially single-phase polycrystalline diamond body.

7. The method of claim 6 , further comprising converting the at least two layers comprising non-diamond carbon particles into an intermediate polycrystalline diamond region that bonds the sintered substantially single-phase polycrystalline diamond body to the substrate, the intermediate polycrystalline diamond region including a plurality of bonded diamond grains defining a plurality of interstitial regions having a metal-solvent catalyst disposed therein.

8. The method of claim 6 wherein disposing at least two layers comprising non-diamond carbon particles between the substrate and the sintered substantially single-phase polycrystalline diamond body comprises providing:
a first layer adjacent to the substrate including fine-sized non-diamond carbon particles exhibiting a fine-sized average particle size;
a second layer adjacent to the first layer including medium-sized non-diamond carbon particles exhibiting a medium-sized average particle size greater than the fine-sized average particle size;
a third layer between the second layer and the sintered substantially single-phase polycrystalline diamond body including coarse-sized non-diamond carbon particles exhibiting a coarse-sized average particle size greater than the medium-sized average particle size; and
wherein the coarse-sized average particle size is at least about 2 times that of the medium-sized average particle size, and the coarse-sized average particle size is at least about 5 times that of the fine-sized average particle size.

9. The method of claim 8 further comprising:
infiltrating the first layer with a first amount of a metal-solvent catalyst and the second layer with a second amount of the metal-solvent catalyst that is less than the first amount, and the third layer with a third amount of the metal-solvent catalyst that is less than the second amount.

10. The method of claim 1 wherein forming the sintered substantially single-phase polycrystalline diamond body comprises providing a preformed polycrystalline diamond body.

11. The method of claim 1 wherein forming the sintered substantially single-phase polycrystalline diamond body comprises converting non-diamond carbon to bonded-together diamond grains exhibiting a morphology different than that of a polycrystalline diamond body formed by sintering diamond crystals in a high-pressure/high-temperature process.

12. A method of fabricating a polycrystalline diamond compact, the method comprising:
forming an assembly including at least one first layer comprising non-diamond carbon positioned adjacent to at least one second layer comprising a mixture including non-diamond carbon particles and sacrificial particles;
subjecting the assembly to a high-pressure/high-temperature process effective to form a polycrystalline diamond structure including a sintered substantially single-phase polycrystalline diamond body bonded to a polycrystalline diamond portion, the polycrystalline diamond portion including a sacrificial material therein;
at least partially leaching the sacrificial material from the polycrystalline diamond portion to form an at least partially leached polycrystalline diamond portion; and
infiltrating the at least partially leached polycrystalline diamond portion with an infiltrant to bond the at least partially leached polycrystalline diamond portion to a substrate.

13. The method of claim 12 wherein the non-diamond carbon of the at least one first layer comprise at least one member selected from the group consisting of crystalline graphite particles, amorphous graphite particles, synthetic graphite particles, amorphous carbon, carbon-12, carbon-13, and carbon-14.

14. The method of claim 12 wherein the at least one second layer comprises a plurality of graphite particles and a plurality of sacrificial particles.

15. The method of claim 14 wherein the graphite particles in the at least one layer comprising graphite comprises at least one member selected from the group consisting of crystalline graphite particles, a polycrystalline graphite, amorphous graphite particles, synthetic graphite particles, carbon-12 particles, and carbon-13 particles.

16. The method of claim 12 wherein the non-diamond carbon particles in the at least one first layer comprise substantially only one of carbon-12, carbon-13, or carbon-14.

17. The method of claim 12 wherein infiltrating the at least partially leached polycrystalline diamond portion with an inf

Assignees

• Bertagnolli Kenneth E
• Mcmurray C Eugene
• Us Synthetic Corp

Inventors

• Bertagnolli Kenneth E
• Mcmurray C Eugene

Classifications

• B01J3/06

  Processes using ultra-high pressure, e.g. for the formation of diamonds; Apparatus therefor, e.g. moulds or dies (B01J3/04 takes precedence) · CPC title

• B24D18/00 Primary

  Manufacture of grinding tools {or other grinding devices}, e.g. wheels, not otherwise provided for · CPC title

• B01J3/062

  characterised by the composition of the materials to be processed · CPC title

• B01J2203/0685

  Crystal sintering · CPC title

• B01J2203/062

  Diamond · CPC title