Thermal conductivity detector and detector module

Patent metadata

Field	Value
Publication number	US-10060866-B2
Application number	US-201615157710-A
Country	US
Kind code	B2
Filing date	May 18, 2016
Priority date	May 20, 2015
Publication date	Aug 28, 2018
Grant date	Aug 28, 2018

Abstract

A thermal conductivity detector for a gas chromatograph includes a heatable resistive detector element configured to be physically arranged in a flow of analytes eluting from a chromatography column and electrically arranged together with resistors in separate arms of a measuring bridge, wherein to provide a new configuration of the thermal conductivity detector to allow high detector sensitivity and to meet intrinsic safety requirements, the detector element includes at least two equal detector sub-elements that are configured to be physically arranged in series in the flow of analytes and electrically arranged in parallel with each other, where the detector element in one arm and a reference resistor in the other arm of the same half of the measuring bridge are configured such that the total resistance of the parallel detector sub-elements at operating temperature is at least approximately equal to the resistance of the reference resistor.

First claim

What is claimed is:

1. A thermal conductivity detector for a gas chromatograph comprising: a measuring bridge having separate arms; and a heatable resistive detector element configured to be physically arranged in a flow of analytes eluting from a chromatography column and electrically arranged together with resistors in separate arms of the measuring bridge; wherein the heatable resistive detector element comprises at least two equal detector sub-elements which are configured to be physically arranged in series in the flow of the analytes and electrically arranged in parallel with each other; and wherein further the heatable resistive detector element in one arm and a reference resistor in another arm of the same half of the measuring bridge are configured such that a total resistance of the parallel at least two equal detector sub-elements is at least substantially equal to a resistance of the reference resistor at operating temperature.

2. The thermal conductivity detector of claim 1 , wherein the heatable resistive detector element comprises three detector sub-elements.

3. The thermal conductivity detector of claim 1 , wherein the heatable resistive detector element is a silicon-based micro-machined element.

4. The thermal conductivity detector of claim 2 , wherein the heatable resistive detector element is a silicon-based micro-machined element.

5. The thermal conductivity detector of claim 1 , further comprising: an amplifier configured to detect a differential voltage between connecting nodes of arms of respective halves of the measuring bridge and further configured to apply an output voltage to the connecting nodes of the halves of the measuring bridge in order to maintain the detector sub-elements at the operating temperature.

6. The thermal conductivity detector of claim 1 , wherein at least a half of the measuring bridge containing the detector element is configured to meet an intrinsic safety requirement.

7. A thermal conductivity detector module comprising at least two thermal conductivity detectors in accordance with claim 1 .

8. The thermal conductivity detector module of claim 7 , wherein four of said thermal conductivity detectors 7 are provided.

Assignees

• Siemens Ag

Inventors

• Gellert Udo
• Schmidt Glen Eugene

Classifications

• G01N2030/025

  Gas chromatography · CPC title

• G01N30/66 Primary

  Thermal conductivity detectors · CPC title

• G01N30/30

  of temperature · CPC title

• G01N25/18 Primary

  by investigating thermal conductivity (by calorimetry G01N25/20; by measuring change of resistance of an electrically-heated body G01N27/18) · CPC title

• G01N2030/3053

  using resistive heating · CPC title