Inorganic material for removing harmful substance from wastewater and method of preparing the same, and method for wastewater treatment

Patent metadata

Field	Value
Publication number	US-10052623-B2
Application number	US-201615195216-A
Country	US
Kind code	B2
Filing date	Jun 28, 2016
Priority date	Jun 29, 2015
Publication date	Aug 21, 2018
Grant date	Aug 21, 2018

Abstract

An inorganic material for removing a harmful substance from wastewater is provided. The inorganic material includes a plurality of porous silicate particles having a glass phase structure, wherein the plurality of porous silicate particles include silicon dioxide, aluminum oxide, barium oxide, cesium oxide, and boron oxide, and have a zeta potential of a negative value at pH of from 1 to 5, and wherein the average pore diameter of the porous silicate particles is in a range of from 3 to 50 nm. Moreover, a method for preparing an inorganic material for removing a harmful substance from wastewater and a method for wastewater treatment are further provided.

First claim

What is claimed is:

1. An inorganic material for removing a harmful substance from wastewater, comprising:
A plurality of porous silicate particles having a glass phase structure, wherein the porous silicate particles comprise silicon dioxide, aluminum oxide, barium oxide, cesium oxide, and boron oxide, and wherein the porous silicate particles have an average pore diameter of from 3 nm to 50 nm, a specific surface area of from 65 m 2 /g to 500 m 2 /g, and have a zeta potential of a negative value at pH of from 1 to 5.

2. The inorganic material of claim 1 , wherein pore diameters of at least 60% pore volume of the porous silicate particles are in a range of from 3 nm to 50 nm.

3. The inorganic material of claim 1 , wherein the porous silicate particles have a specific weight of from 0.5 g/cm 3 to 0.8 g/cm 3 .

4. The inorganic material of claim 1 , wherein the silicon dioxide and the aluminum oxide in the component of the porous silicate particles are at a weight ratio of from 2 to 5.

5. The inorganic material of claim 1 , further comprising an active metal adsorbed into the glass phase structure of the porous silicate particles.

6. The inorganic material of claim 5 , wherein the active metal comprises at least one of sodium, potassium, calcium, and magnesium.

7. The inorganic material of claim 5 , wherein the active metal is in an amount of from 3% to 21%, based on a weight of the inorganic material.

8. The inorganic material of claim 1 , wherein the inorganic material has an adsorption capability of higher than 10 mg/g for a heavy metal.

9. The inorganic material of claim 8 , wherein the heavy metal comprises at least one of a transitional metal and arsenic.

10. The inorganic material of claim 1 , wherein the porous silicate particles have a crystal of the harmful substance crystallized thereon.

11. The inorganic material of claim 10 , wherein the crystal of the harmful substance is at least one of an arsenic crystal, a boron crystal, a phosphor crystal and a fluorine crystal.

12. A method for preparing an inorganic material for removing a harmful substance from wastewater, comprising:
Preparing a silicate powder comprising silicon dioxide, aluminum oxide, barium oxide, cesium oxide and boron oxide; and
Reacting the silicate powder with a metal compound at a reaction temperature of from 800° C. to 1500° C. to form a plurality of porous silicate particles having a glass phase structure, wherein the porous silicate particles have an average pore diameter of from 3 nm to 50 nm, a specific surface area of from 65 m 2 /g to 500 m 2 /g, and a zeta potential of a negative value at pH of from 1 to 5, and wherein the silicate powder and the metal compound are at a weight ratio of from 1:1 to 1:20.

13. The method of claim 12 , wherein the silicate powder is prepared from LCD panel glass as a raw material.

14. The method of claim 12 , wherein a content of the boron oxide is higher than 5%, based on a weight of the silicate powder, and the content of the boron oxide is less than 5%, based on a weight of the porous silicate particles.

15. The method of claim 12 , wherein the silicon dioxide and the aluminum oxide in the component of the silicate powder are at a weight ratio of from 2 to 5.

16. The method of claim 12 , wherein the metal compound is at least one selected from the group consisting of potassium carbonate, sodium carbonate, calcium carbonate and magnesium carbonate.

17. A method for treating wastewater containing a harmful substance, comprising:
Feeding the wastewater containing a harmful substance into a fluidized bed reactor containing a support for the harmful substance in the wastewater to be crystallized on the support and removed to obtain treated water, wherein the support comprises the inorganic material of claim 1 ; and
Feeding the treated wastewater out from the fluidized bed reactor.

18. The method of claim 17 , wherein the porous silicate particles have a particle diameter in a range of from 0.1 mm to 0.4 mm.

Assignees

• Ind Tech Res Inst

Inventors

• Tsai Cheng-Kuo
• Hung Huan-Yi
• Liu Pang-Hung
• Tai Hsien-Hui
• Huang Gaw-Hao
• Hsu Shu-Fang
• Horng Ren-Yang

Classifications

• C02F2101/20

  Heavy metals or heavy metal compounds · CPC title

• C02F2103/346

  from semiconductor processing, e.g. waste water from polishing of wafers · CPC title

• C03C2204/00

  Glasses, glazes or enamels with special properties · CPC title

• C03C3/091

  containing aluminium · CPC title

• C03C4/18

  for ion-sensitive glass · CPC title