Method for smelting magnesium quickly and continuously

Patent metadata

Field	Value
Publication number	US-10047413-B2
Application number	US-201415118205-A
Country	US
Kind code	B2
Filing date	Aug 26, 2014
Priority date	Jul 21, 2014
Publication date	Aug 14, 2018
Grant date	Aug 14, 2018

Abstract

A method for smelting magnesium quickly and continuously includes: preparing dolomite or magnesite with reductants and fluorite at a predetermined ratio, uniformly mixing the prepared ingredients to obtain pellets, and calcining the obtained pellets in an argon or nitrogen atmosphere; continuously feeding the high-temperature calcined pellets (without being cooled) under argon protection into a reduction furnace, and performing a high-temperature reduction reaction in a flowing argon atmosphere to obtain high-temperature magnesium steam; and enabling the high-temperature magnesium steam to be carried out of the high-temperature reduction furnace by an argon flow, and performing condensation to obtain metal magnesium. The present invention eliminates a vacuum system and a vacuum reduction tank, so that quick and continuous production of the metal magnesium is realized, the reduction time is shortened to 90 min or less, and the recovery rate of magnesium is increased to 88% or more.

First claim

What is claimed is:

1. A method for smelting magnesium quickly and continuously, comprising the following steps of:
Step 1: ingredient preparing and pelletizing
ingredient preparing: preparing dolomite, 75Si—Fe alloy and fluorite at a mass ratio of 110:(10-13):(3.0-4.0), uniformly mixing the prepared ingredients so as to obtain a mixture, and then adding soluble glass as a bonding agent which accounts for 1.0-2.0% of the total mass of the prepared ingredients and water which accounts for 2.0-5.0% of the total mass of the prepared ingredients;
or, preparing dolomite, Al and fluorite at a mass ratio of 115:(10-13):(2.0-3.0), uniformly mixing the prepared ingredients so as to obtain a mixture, and then adding soluble glass as a bonding agent which accounts for 1.0-2.0% of the total mass of the prepared ingredients and water which accounts for 2.0-5.0% of the total mass of the prepared ingredients;
pelletizing: uniformly mixing the prepared ingredients so as to obtain a mixture, pelletizing the mixture so as to obtain pellets with particle sizes of 5-20 mm, and naturally drying the pellets for 10-24 h;
Step 2: pellet calcining
placing the dried pellets in a high-temperature furnace, a rotary kiln or a fluidized bed, heating the dried pellets to 150-250° C., keeping the temperature for 30-60 min, dehydrating the dried pellets after the temperature is kept, then heating the dehydrated dried pellets to 850-1050° C. in an argon or nitrogen atmosphere, keeping the temperature, and performing calcination for 30-120 min;
Step 3: continuous high-temperature reduction of calcined pellets
continuously feeding the high-temperature calcined pellets without being cooled under argon protection into a closed high-temperature reduction furnace, then performing a high-temperature reduction reaction in a flowing argon atmosphere with a reduction temperature of 1300-1600° C., a reduction time of 20-90 min, and an argon flow rate of 2.0-5.0 m 3 /h in order to continuously obtain high-temperature magnesium steam, mixing the magnesium steam with argon gas to form a high-temperature gas mixture, and besides, continuously discharging reduction slag out of the high-temperature reduction furnace; and
Step 4: condensing of high-temperature magnesium steam
enabling the high-temperature magnesium steam to be carried out of the high-temperature reduction furnace by the argon flow, and to be delivered through a sealed pipeline to a condensation system for condensation so as to obtain metal magnesium.

2. A method for smelting magnesium quickly and continuously, comprising the following steps of:
Step 1: ingredient preparing and pelletizing
ingredient preparing: preparing magnesite, 75Si—Fe alloy, CaO and fluorite at a mass ratio of 45:(10-13):(16-20):(2.0-3.0), uniformly mixing the prepared ingredients so as to obtain a mixture, and then adding soluble glass as a bonding agent which accounts for 2.0-3.0% of the total mass of the prepared ingredients and water which accounts for 2.0-6.0% of the total mass of the prepared ingredients;
or, preparing magnesite, Al, CaO and fluorite at a mass ratio of 48:(10-13):(15-18):(2.0-3.0), uniformly mixing the prepared ingredients so as to obtain a mixture, and then adding soluble glass as a bonding agent which accounts for 2.0-3.0% of the total mass of the prepared ingredients and water which accounts for 2.0-6.0% of the total mass of the prepared ingredients;
Step 2: pellet calcining
placing the dried pellets in a high-temperature furnace, a rotary kiln or a fluidized bed, heating the dried pellets to 150-250° C., keeping the temperature for 30-60 min, dehydrating the dried pellets after the temperature is kept, then heating the dehydrated dried pellets to 850-1050° C. in an argon or nitrogen atmosphere, keeping the temperature, and performing calcination for 30-120 min;
Step 3: continuous high-temperature reduction of calcined pellets
continuously feeding the high-temperature calcined pellets without being cooled under argon protection into a closed high-temperature reduction furnace, then performing a high-temperature reduction reaction in a flowing argon atmosphere with a reduction temperature of 1300-1600° C., a reduction time of 20-90 min, and an argon flow rate of 2.0-5.0 m 3 /h in order to continuously obtain high-temperature magnesium steam, mixing the magnesium steam with argon gas to form a high-temperature gas mixture, and besides, continuously discharging reduction slag out of the high-temperature reduction furnace; and
Step 4: condensing of high-temperature magnesium steam
enabling the high-temperature magnesium steam to be carried out of the high-temperature reduction furnace by the argon flow, and to be delivered through a sealed pipeline to a condensation system for condensation so as to obtain metal magnesium.

3. The method for smelting magnesium quickly and continuously according to claim 1 , wherein the Al or 75Si—Fe alloy in Step 1 is replaced with composite reductants selected from one of the following three groups:
(1) Al+75Si—Fe alloys; (2) Ca+75Si—Fe alloys; (3) Al+Ca+75Si—Fe alloy;
the standard dosage of the composite reductants are: 1 mass unit of Al can be replaced with 2.2 mass units of Ca; 1 mass unit of 75Si—Fe alloy can be replaced with 2.2 mass units of Ca; and 1 mass unit of Al is equivalent to 1 mass unit of 75Si—Fe alloy.

4. The method for smelting magnesium quickly and continuously according to claim 1 , wherein the condensing way in Step 4 is in direct condensation or atomizing condensation.

5. The method for smelting magnesium quickly and continuously according to claim 2 , wherein the Al or 75Si—Fe alloy in Step 1 is replaced with composite reductants selected from one of the following three groups:
(1) Al+75Si—Fe alloys; (2) Ca+75Si—Fe alloys; (3) Al+Ca+75Si—Fe alloy;
the standard dosage of the composite reductants are: 1 mass unit of Al can be replaced with 2.2 mass units of Ca; 1 mass unit of 75Si—Fe alloy can be replaced with 2.2 mass units of Ca; and 1 mass unit of Al is equivalent to 1 mass unit of 75Si—Fe alloy.

6. The method for smelting magnesium quickly and continuously according to claim 2 , wherein the condensing way in Step 4 is in direct condensation or atomizing condensation.

Assignees

• Univ Northeastern

Inventors

• Zhang Ting'An
• Dou Zhihe
• Zhang Zimu
• Liu Yan
• Lv Guozhi
• He Jicheng

Classifications

• C22B5/04

  by aluminium, other metals or silicon · CPC title

• C22B26/22 Primary

  Obtaining magnesium · CPC title

• C22B1/243

  inorganic · CPC title

• C22B5/16

  with volatilisation or condensation of the metal being produced · CPC title

• C22B1/16

  Sintering; Agglomerating · CPC title