Separation method

Patent metadata

Field	Value
Publication number	US-10035078-B2
Application number	US-201113695993-A
Country	US
Kind code	B2
Filing date	May 4, 2011
Priority date	May 4, 2010
Publication date	Jul 31, 2018
Grant date	Jul 31, 2018

Abstract

A process for recovering metal from a process material comprising the metal and a component that is more volatile than the metal, which process comprises:
transporting the process material in a retort provided in a furnace, the retort being operated under vacuum and at a temperature sufficient to cause sublimation of the component from the process material thereby producing purified metal; depositing the component that has been sublimed on a cool surface; removing purified metal from the retort; and removing deposited component from the cool surface.

First claim

The claims defining the invention are as follows:

1. A process for recovering a metal from a process material comprising the metal and at least one component that is more volatile than the metal, which process comprises:
transporting the process material in a retort provided in a single furnace, the retort being operated under vacuum and at a temperature sufficient to cause sublimation of the at least one component from the process material thereby producing purified metal as a solid, the process material comprising the metal and the at least one component which includes one or more volatile salts of another metal;
depositing via deposition the at least one component that has been sublimed on a cool surface that is in continuous direct communication with the retort;
removing the purified metal from the retort; and
removing the at least one component that has been deposited on the cool surface from the cool surface, wherein the process is operated on a continuous basis with fresh process material being supplied to the retort and furnace, with the purified metal being removed continuously and with the at least one component deposited on the cool surface being removed continuously.

2. The process of claim 1 , wherein the metal is selected from titanium, zirconium and hafnium and the process material is a reduction reaction product including the metal reduction reaction by-products.

3. The process of claim 1 , wherein the metal is titanium and the process material is produced by reduction of titanium tetrachloride with magnesium.

4. The process of claim 1 , wherein the process material is transported in the retort using a rotating screw.

5. The process of claim 1 , wherein a temperature gradient is provided so that process material transported in the retort is transported into a hot zone where sublimation of the at least one component from the process material takes place.

6. The process of claim 1 , wherein multiple components that are more volatile than the metal are removed from the process material via sublimation and deposition.

7. The process of claim 1 , wherein the process material is in particulate form.

8. The process of claim 7 , wherein temperature and pressure is controlled to avoid formation of liquid phases.

Assignees

• Chryss Andrew
• Monch Andreas
• Khosa Jasbir
• Richards Matthew
• Freeman David
• Commw Scient Ind Res Org

Inventors

• Chryss Andrew
• Monch Andreas
• Khosa Jasbir
• Richards Matthew
• Freeman David

Classifications

• C22B9/04

  Refining by applying a vacuum · CPC title

• C22B34/129

  obtaining metallic titanium from titanium compounds by dissociation, e.g. thermic dissociation of titanium tetraiodide, or by electrolysis or with the use of an electric arc · CPC title

• B01D1/24 Primary

  to obtain dry solids · CPC title

• C22B34/00

  Obtaining refractory metals · CPC title

• C22B9/02

  Refining by liquating, filtering, centrifuging, distilling, or supersonic wave action {including acoustic waves; (C22B9/003, C22B9/006, C22B9/05, C22B9/22 take precedence)} · CPC title