Reformer gas-based reducing method with reduced NOx emission

Patent metadata

Field	Value
Publication number	US-10030911-B2
Application number	US-201514810580-A
Country	US
Kind code	B2
Filing date	Jul 28, 2015
Priority date	Jul 31, 2009
Publication date	Jul 24, 2018
Grant date	Jul 24, 2018

Abstract

In a process and apparatus for the reduction of metal oxides ( 3 ) to form metalized material by contact with hot reducing gas, which is produced at least partially by catalytic reformation of a mixture of
a gas containing carbon dioxide (CO 2 ) and/or steam (H 2 O) with gaseous hydrocarbons,

the heat for the endothermal reformation processes which take place during the reformation is provided at least partially by the combustion of a fuel gas.

First claim

What is clamed is:

1. An apparatus for reduction of metal oxides, comprising:
a reduction unit for the reduction of metal oxides to form metalized material,
a reformer that carries out catalytic reformation of a first mixture of a gas containing at least one of carbon dioxide (CO 2 ) and steam with gaseous hydrocarbons,
wherein the reformer is provided with the first mixture supply line for supplying the first mixture, and
wherein the reformer is provided with burners that, through combustion of fuel gas, provide heat for the catalytic reformation by the reformer, a reducing gas supply line for hot reducing gas from the reformer into the reduction unit, a discharge line for top gas from the reduction unit, and a drawing-off line for drawing off combustion off-gas from the reformer, the drawing-off line comprising an apparatus for cooling the combustion off-gas and removing water from the combustion off-gas, and the drawing off line and the reducing gas supply line being separate lines out of the reformer,
wherein the burners are provided with an apparatus for supplying fuel gas and with an apparatus for supplying a second mixture of gas produced from pure oxygen and a partial quantity of the combustion off-gas, obtained after passing through the at least one apparatus for cooling, and removing water.

2. The apparatus according to claim 1 , wherein the apparatus for supplying the second mixture of gas comprises a gas mixture line which branches off from the drawing-off line, and further comprising an oxygen supply line in communication with the gas mixture line.

3. The apparatus according to claim 1 , further comprising an apparatus in the drawing-off line for producing CO 2 from the combustion off-gas.

4. The apparatus according to claim 1 , wherein the apparatus for supplying the second mixture of gas includes an apparatus for heating the second mixture.

5. The apparatus according to claim 4 , wherein the apparatus for heating the second mixture of gas is a recuperator for transfer of heat from combustion off-gas to the second mixture.

6. The apparatus according to claim 1 , wherein the reduction unit is a fluidized bed cascade.

7. The apparatus according to claim 1 , wherein the reduction unit is a fixed-bed reduction shaft.

8. A system for the reduction of metal oxides to form metalized material by contact with hot reducing gas,
wherein the reducing gas is produced at least partially by catalytic reformation, in a reformer, of a mixture of a gas containing at least one of carbon dioxide and steam with gaseous hydrocarbons,
the system comprising:
a reducing gas supply line that supplies reducing gas produced in the reformer,
a heater that combusts a fuel gas to provide at least part of the heat for the endothermal reformation processes which take place during the reformation in the reformer, and
a line from the reformer that draws off the produced combustion off-gas, the line that draws off the produced combustion off gas being different from the reducing gas supply line,
wherein the system is configured to cool the combustion off-gas and to remove water from the combustion off-gas, and
wherein the system is configured to supply to the heater the oxygen required for the combustion of the fuel gas to the fuel gas with a gas mixture produced from pure oxygen and a partial quantity of the combustion off-gas, which has been cooled and from which water has been removed.

Assignees

• Primetals Technologies Austria GmbH

Inventors

• Millner Robert
• Peer Guenter

Classifications

• C21B2100/64

  Controlling the physical properties of the gas, e.g. pressure or temperature · CPC title

• C01B2203/06

  Integration with other chemical processes · CPC title

• Y02P10/143

  of methane [CH4] · CPC title

• C21B13/0073

  Selection or treatment of the reducing gases · CPC title

• C01B2203/148

  involving a recycle stream to the feed of the process for making hydrogen or synthesis gas · CPC title