Method for preparing hot-melt adhesive composition and hot-melt adhesive composition prepared thereby

Patent metadata

Field	Value
Publication number	US-10023769-B2
Application number	US-201615007036-A
Country	US
Kind code	B2
Filing date	Jan 26, 2016
Priority date	Jun 19, 2015
Publication date	Jul 17, 2018
Grant date	Jul 17, 2018

Abstract

Disclosed is a method for preparing a hot-melt adhesive composition and a hot-melt adhesive composition prepared thereby. The method comprises: preparing and mixing raw materials, including a butyl rubber, an ethylene propylene diene (EPDM) rubber, a styrene block copolymer, an amorphous poly-alpha-olefin (APAO) and a tackifier resin; and performing vacuum degassing of the mixed raw materials, wherein the styrene block copolymer comprises a styrene-isoprene-styrene (SIS) rubber. The hot-melt adhesive composition has high resistance in temperature cycles between low and high temperatures so as to maintain its physical properties, and thus has an excellent property of sealing a headlamp for a long period of time until the end of the lifespan of the headlamp. Also, the composition generates no gas in the sealed state of the headlamp, and thus does not create bubbles or voids and does not pose a water tightness problem.

First claim

What is claimed is:

1. A method for preparing a hot-melt adhesive composition, the method comprising;
mixing raw materials comprising a butyl rubber, an ethylene propylene diene (EPDM) rubber, a styrene block copolymer, an amorphous poly-alpha-olefin (APAO) and a tackifier resin; and
performing vacuum degassing of the mixed raw materials,
wherein the styrene block copolymer comprises a styrene-isoprene-styrene (SIS) rubber,
wherein the vacuum degassing is performed using a vacuum pump at a temperature between about 150° C. and about 210° C. at a vacuum level of about 70-150 mmHg for about 3-10 hours.

2. The method of claim 1 , wherein the tackifier resin is one or more selected from the group consisting of aliphatic petroleum resin, rosin ester and terpene resin.

3. The method of claim 2 , wherein the tackifier resin comprises about 35-65 wt % of the aliphatic petroleum resin, about 15-35 wt % of the rosin ester, and about 15-35 wt % of the terpene resin.

4. The method of claim 1 , wherein the raw materials further include a plasticizer containing polyisobutylerte, a phenol-based antioxidant, and a UV stabilizer.

5. The method of claim 1 , wherein the raw materials comprise:
about 1.4.5-14.7 wt % of the butyl rubber;
about 14.5-14.7 wt % of the ethylene propylene diene (EPDM) rubber;
about 9.6-9.8 wt % of the styrene block copolymer;
about 7.7-7.9 wt % of the amorphous poly-alpha-olefin (APAO);
about 19.4-19.7 wt % of aliphatic petroleum resin;
about 9.6-9.9 wt % of rosin ester;
about 9.6-9.9 wt % of terpene resin;
about 9.6-9.9 wt % of a plasticizer containing polyisobutylene;
about 2-4 wt % of maleic anhydride polypropylene;
about 0.5-1 wt % of a phenol-based antioxidant; and
about 0.1-0.5 wt % of a UV stabilizer.

Assignees

• Hyundai Mobis Co Ltd
• Okong Corp

Inventors

• Kim Seong Ho
• Lee Jung Hwan
• Lee Woo Sik
• Hong In Oh
• Park Jong Il

Classifications

• C08L2312/00

  Crosslinking · CPC title

• C08L2205/035

  containing four or more polymers in a blend · CPC title

• C09J11/08

  Macromolecular additives · CPC title

• C08L23/16

  Ethylene-propylene or ethylene-propylene-diene copolymers · CPC title

• C08L53/02

  of vinyl-aromatic monomers and conjugated dienes · CPC title