Pressure sensitive adhesive foam

Patent metadata

Field	Value
Publication number	US-2016145406-A1
Application number	US-201414905562-A
Country	US
Kind code	A1
Filing date	Jul 29, 2014
Priority date	Aug 1, 2013
Publication date	May 26, 2016
Grant date	—

Abstract

The present disclosure relates to a pressure sensitive adhesive foam comprising a rubber-based elastomeric material and at least one hydrocarbon tackifier, wherein the hydrocarbon tackifier(s) have a Volatile Organic Compound (VOC) value of less than 1000 ppm and a Volatile Fogging Compound (FOG) value of less than 1500 ppm, when measured by thermogravimetric analysis according to the weight loss test methods described in the experimental section. The present disclosure also relates to a method of manufacturing such a pressure sensitive adhesive foam and uses thereof.

First claim

1 . A pressure sensitive adhesive foam comprising (a) a rubber-based elastomeric material, (b) at least one hydrocarbon tackifier, and (c) at least one polyisobutylene plasticizer, wherein the hydrocarbon tackifier(s) have a Volatile Organic Compound (VOC) value of less than 1000 ppm and a Volatile Fogging Compound (FOG) value of less than 1500 ppm, when measured by thermogravimetric analysis according to the weight loss test methods described in the experimental section.

2 . A pressure sensitive adhesive foam according to claim 1 , wherein the hydrocarbon tackifier(s) have a Volatile Organic Compound (VOC) value of less than 800 ppm, when measured by thermogravimetric analysis according to the weight loss test method described in the experimental section.

3 . A pressure sensitive adhesive foam according to claim 1 , wherein the hydrocarbon tackifier(s) have a Volatile Fogging Compound (FOG) value of less than 1000 ppm when measured by thermogravimetric analysis according to the weight loss test method described in the experimental section.

4 . (canceled)

5 . (canceled)

6 . A pressure sensitive adhesive foam according to claim 1 , wherein the polyisobutylene plasticizer(s) have a Volatile Organic Compound (VOC) value of less than 1000 ppm, when measured by thermogravimetric analysis according to the weight loss test methods described in the experimental section.

7 . A pressure sensitive adhesive foam according to claim 1 , which is crosslinked.

8 . A pressure sensitive adhesive foam according to claim 1 , which further comprises at least one filler material which is preferably selected from the group consisting of expandable microspheres, glass bubbles, and any combinations or mixtures thereof.

9 . A pressure sensitive adhesive foam according to claim 1 , wherein the rubber-based elastomeric material is selected from the group consisting of halogenated butyl rubbers; halogenated isobutylene-isoprene copolymers; olefinic block copolymers; butyl rubbers; synthetic polyisoprene; ethylene-octylene rubbers; ethylene-propylene rubbers; ethylene-propylene random copolymers; ethylene-propylene-diene monomer rubbers; polyisobutylenes; poly(alpha-olefin); ethylene-alpha-olefin copolymers; ethylene-alpha-olefin block copolymers; styrenic block copolymers; styrene-isoprene-styrene block copolymers; styrene-butadiene-styrene block copolymers; styrene-ethylene/butadiene-styrene block copolymers; styrene-ethylene/propylene-styrene block copolymers; styrene-butadiene random copolymers; olefinic polymers and copolymers; ethylene-propylene random copolymers; ethylene-propylene-diene terpolymers, and any combinations or mixtures thereof.

10 . A pressure sensitive adhesive foam according to claim 1 , wherein the rubber-based elastomeric material is selected from the group consisting of bromo-isobutylene-isoprene copolymers, chloro-isobutylene-isoprene copolymers, ethylene-octylene block copolymers, ethylene-propylene-butylene copolymers, and any combinations or mixtures thereof.

11 . A pressure sensitive adhesive foam according to claim 1 , which comprises:
a) from 20 wt % to 80 wt % of the rubber-based elastomeric material, based on the weight of the pressure sensitive adhesive foam; b) from 5 wt % to 60 wt % of the hydrocarbon tackifier(s), based on the weight of the pressure sensitive adhesive foam; c) from 1 wt % to 40 wt % of a polyisobutylene plasticizer, based on the weight of the pressure sensitive adhesive foam; d) optionally, from 2 wt % to 30 wt % of filler material preferably selected from the group of expandable microspheres and glass bubbles, based on the weight of the pressure sensitive adhesive foam; and e) optionally, from 0.1 wt % to 10 wt % of a crosslinking additive, based on the weight of the pressure sensitive adhesive foam, and wherein the crosslinking additive is preferably selected from the group of multifunctional (meth)acrylate compounds.

12 . A pressure sensitive adhesive assembly comprising a pressure sensitive adhesive foam according to claim 1 .

13 . A pressure sensitive adhesive assembly according to claim 12 , which is crosslinked.

14 . A method of manufacturing a pressure sensitive adhesive foam according to claim 1 , which comprises the steps of:
a) compounding a rubber-based elastomeric material; at least one hydrocarbon tackifier; a polyisobutylene plasticizer; optionally, a filler material selected from the group of expandable microspheres and glass bubbles; optionally, a crosslinking agent which is selected from the group of multifunctional (meth)acrylate compounds; and wherein the hydrocarbon tackifier(s) have a Volatile Organic Compound (VOC) value of less than 1000 ppm and a Volatile Fogging Compound (FOG) value of less than 1500 ppm when measured by thermogravimetric analysis according to the weight loss test methods described in the experimental section; thereby forming a pressure sensitive adhesive foam formulation; and b) optionally, crosslinking the pressure sensitive adhesive foam formulation.

15 . (canceled)

Assignees

• 3M Innovative Properties Co

Inventors

• Bieber Pierre Reinhard
• Stegmaier Petra M
• Goeb Siegfried R

Classifications

• C08J2353/02

  of vinyl aromatic monomers and conjugated dienes · CPC title

• C08J2309/00

  Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title

• C08J2353/00

  Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers · CPC title

• C08J9/0066

  Use of inorganic compounding ingredients · CPC title

• C08J2423/22

  Copolymers of isobutene; butyl rubber · CPC title