Uniformly, highly dispersed metal catalyst and process for producing the same

Patent metadata

Field	Value
Publication number	US-RE46145-E
Application number	US-200613940053-A
Country	US
Kind code	E1
Filing date	Jun 19, 2006
Priority date	Jun 20, 2005
Publication date	Sep 13, 2016
Grant date	Sep 13, 2016

Abstract

Provided are: a uniformly, highly dispersed metal catalyst including a catalyst carrier and a catalyst metal being loaded thereon dispersed throughout the carrier, the uniformly, highly dispersed metal catalyst having excellent performances with respect to catalytic activity, selectivity, life, etc.; and a method of producing the same. The uniformly, highly dispersed metal catalyst includes a catalyst carrier made of a metal oxide and a catalyst metal having catalytic activity, the catalyst metal being loaded on the catalyst carrier, in which the catalyst carrier is a sulfur-containing catalyst carrier having sulfur or a sulfur compound almost evenly distributed throughout the carrier and the catalyst metal is loaded on the sulfur-containing catalyst carrier in a substantially evenly dispersed manner over the entire carrier substantially according to the distribution of the sulfur or the sulfur compound.

First claim

The invention claimed is:

1. An uniformly, highly dispersed metal catalyst, comprising:
a catalyst carrier made of a metal oxide; and
a catalyst metal having catalytic activity,
the catalyst metal being loaded on the catalyst carrier, wherein:
the catalyst carrier is a sulfur-containing catalyst carrier which comprises an aluminum a porous γ-alumina carrier having a surface area of 150 m 2 /g or larger, a fine pore volume of 0.4 cm 3 /g or larger, an average fine pore diameter of 40 to 300 Å, and the proportion of fine pores having an a diameter within ±30 Å of the average fine pore diameter of 30 Å is 60% or higher with respect to a total pore volume and sulfur or a sulfur compound which is dispersed throughout a cross section of the aluminum porous γ-alumina carrier and whose content is 0.15 to 3.0% by weight in terms of a sulfur element; and
in the sulfur-containing catalyst porous γ-alumina carrier, platinum or rhodium is dispersed in a dispersion ratio of greater than 60% but not greater than 80% as measured by a CO pulse adsorption method and loaded as the catalyst metal over an entire cross section of the catalyst carrier substantially in agreement with distribution of the sulfur or the sulfur compound.

2. An uniformly, highly dispersed metal catalyst according to claim 1 , wherein the sulfur or the sulfur compound is one or two or more members selected from sulfur (S), sulfuric acid, a sulfate, and an organosulfur compound.

3. An uniformly, highly dispersed metal catalyst according to claim 1 , wherein a loading amount of the catalyst metal is 0.1 to 3.0% by weight in terms of catalyst metal (Me).

4. An uniformly, highly dispersed metal catalyst according to claim 1 , wherein the sulfur-containing catalyst porous γ-alumina carrier is a compact or powder comprising a sulfur-containing porous γ-alumina carrier.

5. An uniformly, highly dispersed metal catalyst according to claim 1 , wherein the catalyst metal is dispersed on the sulfur-containing catalyst carrier in a dispersion ratio of 40% or more measured by a CO pulse adsorption method.

6. A method of dehydrogenating a hydrogenated aromatic, comprising dehydrogenating hydrogenated aromatic using the uniformly, highly dispersed metal catalyst according to any one of claim claims 1 , 2 , 3 , or 4 , or 5 .

7. A method of dehydrogenating a hydrogenated aromatic according to claim 6 , wherein the hydrogenated aromatic is one member or a mixture of two or more members selected from a hydride of monocyclic aromatic, a hydride of bicyclic aromatic, and a hydride of compound having three or more aromatic rings.

8. A method of producing an uniformly, highly dispersed metal catalyst, comprising:
carrying out a pH swing process of a slurry of aluminum hydroxide generated by neutralizing aluminum salt to grow crystals of alumina hydrogel in which a pH of alumina hydrogel is alternately fluctuated between a pH range of the dissolution of alumina hydrogel and a pH range of the precipitation of boehmite gel and simultaneously an alumina hydrogel forming substance is added when the pH is fluctuated from at least either one of the pH ranges to the other one of the pH ranges;
kneading sulfur powder in an aluminum gel the obtained alumina hydrogel serving as a precursor of an alumina;
forming the resulting gel hydrogel into a predetermined shape, followed by drying and calcining to prepare a sulfur-containing catalyst porous γ-alumina carrier in which sulfur or a sulfur compound is dispersed throughout a cross section thereof;
impregnating the obtained sulfur-containing catalyst porous γ-alumina carrier with an aqueous solution of catalyst metal compound of platinum and/or rhodium;
drying the resulting catalyst porous γ-alumina carrier to obtain a dried matter loading the catalyst metal compound;
reducing the dried matter loading the catalyst metal compound as it is in a hydrogen atmosphere; or calcining the obtained dried matter loading the catalyst metal compound to obtain a calcined matter loading catalyst metal; and
reducing the obtained calcined matter loading the catalyst metal with hydrogen to produce a uniformly, highly dispersed metal catalyst in which platinum and/or rhodium is dispersed in a dispersion ratio of greater than 60% but not greater than 80% as measured by a CO pulse adsorption method and loaded as the catalyst metal over an entire cross section of the catalyst carrier substantially in agreement with distribution of the sulfur or the sulfur compound.

9. A method of producing the uniformly, highly dispersed metal catalyst according to claim 8 , comprising, at the time of impregnating the sulfur-containing catalyst porous γ-alumina carrier with a solution of catalyst metal compound, adjusting a pH value of the impregnation solution within a range of 1.8 to 3.0.

10. A method of producing the uniformly, highly dispersed metal catalyst according to claim 8 or 9 , wherein the sulfur-containing catalyst carrier is a sulfur-containing porous γ-alumina carrier.

11. A method of producing the uniformly, highly dispersed metal catalyst according to claim 10 9, wherein the sulfur-containing porous γ-alumina carrier has a surface area of 150 m 2 /g or more, a fine pore volume of 0.40 cm 3 /g, an average fine pore diameter of 40 to 300 , and the proportion of fine pores with having a diameter within ±30 of the average fine pore diameter of ±30 occupying 60% or more of a total fine pore volume.

12. A method of producing the uniformly, highly dispersed metal catalyst according to claim 10 9, wherein the sulfur-containing catalyst porous γ-alumina is prepared at a calcination temperature of 350 to 800° C. for a calcination time of 1.0 to 24 hours.

13. The method of claim 1, wherein the content of the sulfur or the sulfur compound is 0.15 to 0.5% by weight in terms of a sulfur element.

14. The method of claim 8, wherein the content of the sulfur or the sulfur compound is 0.15 to 0.5% by weight in terms of a sulfur element.

Assignees

• Chiyoda Corp
• Makabe Katsutoshi
• Makabe Kiyoshi
• Nishijima Takako

Inventors

• Okada Yoshimi
• Makabe Toshiji
• Saito Masashi
• Nishijima Hiroaki

Classifications

• B01J35/1038

  Operations & Transport · mapped topic

• B01J37/0201

  Impregnation · CPC title

• B01J21/04

  Alumina · CPC title

• B01J23/42

  Platinum · CPC title

• C07C15/02

  Monocyclic hydrocarbons · CPC title