High flow polyaryletherketone composition

Patent metadata

Field	Value
Publication number	US-9988529-B2
Application number	US-201615352635-A
Country	US
Kind code	B2
Filing date	Nov 16, 2016
Priority date	Nov 20, 2015
Publication date	Jun 5, 2018
Grant date	Jun 5, 2018

Abstract

A polymer composition that contains a polyaryletherketone and thermotropic liquid crystalline polymer, which are melt processed in the presence of a flow modifier. The flow modifier is a functional compound that contains one or more hydroxyl functional groups.

First claim

What is claimed is:

1. A polymer composition that comprises at least one polyaryletherketone and from about 1 to about 100 parts of at least one liquid crystalline polymer per 100 parts of the polyaryletherketone, wherein the composition is formed by melt processing the polyaryletherketone and the liquid crystalline polymer in the presence of a flow modifier, wherein the flow modifier includes a functional compound that includes a metal hydroxide, metal alkoxide, metal salt hydrate, or a combination thereof.

2. The polymer composition of claim 1 , wherein the functional compound is present in an amount from about 0.05 to about 5 parts by weight per 100 parts by weight of the polyaryletherketone.

3. The polymer composition of claim 1 , wherein the ratio of the melt viscosity of the polymer composition to the melt viscosity of the polyaryletherketone is about 0.80 or less, as determined in accordance with ISO Test No. 11443:2005 at a temperature of 400° C. and a shear rate of 1000 s −1 .

4. The polymer composition of claim 1 , wherein the polymer composition has a melt viscosity of from about 0.1 to about 250 Pa-s as determined in accordance with ISO Test No. 11443:2005 at a temperature of 400° C. and shear rate of 1000 s −1 .

5. The polymer composition of claim 1 , wherein the liquid crystalline polymer contains repeating units derived from naphthenic hydroxycarboxylic acids, naphthenic dicarboxylic acids, or a combination thereof in an amount of no more than about 8 mol.%.

6. The polymer composition of claim 1 , wherein the liquid crystalline polymer consists essentially of repeating units derived from 4-hydroxybenzoic acid; repeating units derived from terephthalic acid and/or isophthalic acid; and repeating units derived from 4,4′-biphenol and/or hydroquinone.

7. The polymer composition of claim 6 , wherein the monomer units derived from 4-hydroxybenzoic acid constitute from about 40 mol.% to about 85 mol.% of the liquid crystalline polymer.

8. The polymer composition of claim 7 , wherein the monomer units derived from terephthalic acid and isophthalic acid each constitute from about 1 mol.% to about 30 mol.% of the liquid crystalline polymer, and the monomer units derived from hydroquinone and 4,4-biphenol each constitute from about 1 mol.% to about 30 mol.% of the liquid crystalline polymer.

9. The polymer composition of claim 1 , wherein the polyaryletherketone has a glass transition temperature of from about 110° C. to about 200° C.

10. The polymer composition of claim 1 , wherein the polyaryletherketone has a melt viscosity of about 80 Pa-s or more, as determined in accordance with ISO Test No. 11443:2013 at a shear rate of 1000 s −1 and temperature of 400° C.

11. The polymer composition of claim 1 , wherein the polyaryletherketone contains a moiety having the structure of Formula (I) and/or Formula (II):

wherein,
m and r are independently zero or a positive integer;
s and w are independently zero or a positive integer;
E and E′ are independently an oxygen atom or a direct link;
G is an oxygen atom, a direct link, or —O-Ph-O— where Ph is a phenyl group; and
Ar is one of the following moieties (i) to (vi), which is bonded via one or more of phenyl moieties to adjacent moieties:

12. The polymer composition of claim 11 , wherein the polyaryletherketone contains a repeat unit of the following general Formula (III):

wherein,
A and B are independently 0 or 1.

13. The polymer composition of claim 11 , wherein the polyaryletherketone contains a repeat unit of the following general Formula (IV):

wherein,
A and B are independently 0 or 1.

14. The polymer composition of claim 1 , wherein the polyaryletherketone is polyetheretherketone, polyetherketone, polyetherketoneketone, polyetherketoneetherketoneketone, polyetheretherketoneketone, polyether-diphenyl-ether -ether-diphenyl-ether-phenyl-ketone-phenyl, or a blend or copolymer thereof.

15. The polymer composition of claim 1 , wherein the functional compound includes a metal hydroxide compound.

16. The polymer composition of claim 15 , wherein the metal hydroxide compound is copper (II) hydroxide, potassium hydroxide, sodium hydroxide, magnesium hydroxide, calcium hydroxide, aluminum hydroxide, or a combination thereof.

17. The polymer composition of claim 1 , wherein the functional compound includes a metal alkoxide, metal salt hydrate, or a combination thereof.

18. The polymer composition of claim 17 , wherein the hydrate is CaCl 2 .H 2 O, ZnCl 2 .4H 2 O, CoCl 2 .6H 2 O, CaSO 4 .2H 2 O, MgSO 4 .7H 2 O, CuSO 4 .5H 2 O, Na 2 SO 4 .10H 2 O, Na 2 CO 3 .10H 2 O, Na 2 B 4 O 7 .10H 2 O, Ba(OH) 2 .8H 2 O, or a combination thereof.

19. The polymer composition of claim 1 , wherein the functional compounds further includes a hydroxy-functional organic compound, carboxy-functional organic compound, or a combination thereof.

20. The polymer composition of claim 1 , wherein the polymer composition contains no more than about 5 wt.% of fillers.

21. The polymer composition of claim 20 , wherein the polyaryletherketone constitutes from about 60 wt.% to about 99.5 wt.% of the composition.

22. The polymer composition of claim 1 , wherein the polymer composition contains from about 5 wt.% to about 70 wt.% of fillers.

23. The polymer composition of claim 22 , wherein the polyaryletherketone constitutes from about 10 wt.% to about 80 wt.% of the composition.

24. The polymer composition of claim 20 , wherein the filler includes glass fibers.

25. The polymer composition of claim 24 , wherein the glass fibers have an aspect ratio of from about 1.5 to about 10, the aspect ratio being defined as the cross-sectional width of the fibers divided by the cross-sectional thickness of the fibers.

26. A molded article comprising the polymer composition of claim 1 .

27. A method for forming the polymer composition of claim 1 , the method comprising melt processing the polyaryletherketone and the liquid crystalline polymer in the presence of the flow modifier.

28. The method of claim 27 , wherein melt processing occurs at a temperature of from about 250° C. to about 400° C.

29. The method of claim 27 , wherein the ratio of the melt viscosity of the polymer composition to the melt viscosity of the polyaryletherketone is about 0.80 or less, as determined in accordance with ISO Test No. 11443:2005 at a temperature of 400° C. and a shear rate of 1000 s −1 .

Assignees

• Ticona Llc

Inventors

• Lu Bing
• Luo Rong
• Yu Yuehua
• Zhao Xinyu

Classifications

• C08L71/00 Primary

  Compositions of polyethers obtained by reactions forming an ether link in the main chain (of polyacetals C08L59/00; of epoxy resins C08L63/00; of polythioether-ethers C08L81/02; of polyether-sulfones C08L81/06); Compositions of derivatives of such polymers · CPC title

• C08G2650/40

  containing ketone groups, e.g. polyarylethylketones, PEEK or PEK · CPC title

• C08L2205/12

  containing additives being liquid crystalline or anisotropic in the melt · CPC title

• C08G65/4012

  Other compound (II) containing a ketone group, e.g. X-Ar-C(=O)-Ar-X for polyetherketones · CPC title

• C08L67/04

  Polyesters derived from hydroxycarboxylic acids, e.g. lactones (C08L67/06 takes precedence) · CPC title