Impact resistant transparent thermoplastic compositions

Patent metadata

Field	Value
Publication number	US-9988527-B2
Application number	US-201314435873-A
Country	US
Kind code	B2
Filing date	Oct 15, 2013
Priority date	Oct 16, 2012
Publication date	Jun 5, 2018
Grant date	Jun 5, 2018

Abstract

The invention relates to impact-modified, thermoplastic compositions, where the measured refractive index difference between the impact modifier particles and the matrix composition is greater than 0.008 units, yet a blend of the impact modifier particles in the matrix produces a transparent composition. The impact modifier particles are preferably impact modifier composite particles, being intimately blended with one or more polymeric process aids or dispersing aids. The polymeric process aids are physically or chemically attached to the impact modifier particles, forming composite particles that allow for facile powder isolation. The impact modifier composite particles provide improved physical, chemical, and/or rheological properties to the thermoplastic composition. Preferably the impact modifier particles of the invention are core-shell impact modifiers.

First claim

What is claimed is:

1. A transparent, impact-modified composition comprising:
a) 20-95 weight percent of a thermoplastic matrix, and
b) 5 to 80 weight percent of composite impact modifier particles, wherein said composite impact modifier particles comprise from 10 to 75 weight percent of one or more polymeric process aids, and from 25 to 90 weight percent of impact modifier particles, wherein said process aids and said impact modifier are physically and/or chemically attached,
wherein the difference in refractive index (R.I.) between the thermoplastic matrix and composite impact modifier particles is greater than +/−0.008, and wherein said transparent impact-modified composition has a haze of less than 40, and a total white light transmission of greater than 50, as measured by ASTM D1003 on a plaque having a thickness of 3 mm.

2. The transparent, impact-modified composition of claim 1 , wherein the difference in refractive index between the thermoplastic matrix and impact modifier particles is greater than +/−0.010.

3. The transparent, impact-modified composition of claim 1 , wherein the difference in refractive index between the thermoplastic matrix and impact modifier particles is greater than +/−0.012.

4. The transparent, impact-modified composition of claim 1 , wherein said impact modifiers are selected from the group consisting of core-shell impact modifiers, linear block copolymers, and nano-structured latex particles.

5. The transparent, impact-modified composition of claim 1 , wherein said impact modifier has a core-shell polymer structure.

6. The transparent, impact-modified composition of claim 5 , wherein said core-shell polymer comprises one or more layers having a refractive index of at least +/−0.005 units different from the R.I. of a different layer of the core-shell polymer.

7. The transparent, impact-modified composition of claim 1 , wherein said thermoplastic matrix is an acrylic.

8. The transparent, impact-modified composition of claim 7 , wherein said matrix is an acrylic matrix comprising from 50 to 100 weight percent of methylmethacrylate units.

9. The transparent, impact-modified composition of claim 7 , wherein said acrylic matrix is an alloy comprising 40-95 percent by weight of acrylic polymer, and from 5-60 weight percent of a low melt viscosity polymer.

10. The transparent, impact-modified composition of claim 9 , wherein said acrylic matrix alloy comprises from 5-60 weight percent of polylactic acid.

11. The transparent, impact-modified composition of claim 1 , wherein said polymeric process aid comprises a polymethyl methacrylate polymer or copolymer wherein said copolymer comprises more than 80 weight percent of methyl methacrylate monomer units.

12. The transparent, impact-modified composition of claim 11 , wherein said polymeric process aid comprises a polymethyl methacrylate copolymer having greater than 80 weight percent of methyl methacrylate monomer units and at least 1 percent by weight of ethyl acrylate monomer units.

13. The process of claim 1 , wherein the difference in refractive index between the thermoplastic matrix and impact modifier particles is greater than +/−0.010.

14. The transparent, impact-modified composition of claim 12 , wherein said polymethyl methacrylate polymer or copolymer polymeric process aid has a molecular weight of greater than 1,000,000 g/mol.

Assignees

• Arkema France
• Barsotti Robert J

Inventors

• Barsotti Robert J
• Macy Noah E
• Aubart Mark A
• Wanat Robert A
• Fellenger Paul D
• Mehlmann Florence
• Roland Thomas F

Classifications

• C08L33/12

  Homopolymers or copolymers of methyl methacrylate · CPC title

• C08L51/06

  grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond · CPC title

• C08J3/005

  Processes for mixing polymers · CPC title

• C08L2205/06

  having improved processability or containing aids for moulding methods · CPC title

• C08F2/22

  Emulsion polymerisation · CPC title