Method for producing peroxymonosulfuric acid and apparatus for continuously producing peroxymonosulfuric acid

Patent metadata

Field	Value
Publication number	US-9988269-B2
Application number	US-201514872462-A
Country	US
Kind code	B2
Filing date	Oct 1, 2015
Priority date	Oct 18, 2006
Publication date	Jun 5, 2018
Grant date	Jun 5, 2018

Abstract

The invention provides a method for producing a peroxymonosulfuric acid solution with high stability, including the steps of mixing 35 mass % or more of hydrogen peroxide and 70 mass % or more of sulfuric acid to react them, cooling the reaction solution to 80° C. or lower within five minutes after initiation of the mixing step, and diluting the reaction solution with water four times or more as much as the reaction solution by mass.

First claim

The invention claimed is:

1. An apparatus for continuously producing peroxymonosulfuric acid, comprising:
a first static mixer for mixing hydrogen peroxide with sulfuric acid to react them, thereby obtaining a reaction solution;
a second static mixer for mixing the reaction solution obtained in the first static mixer with a dilution water;
a reaction solution transporting pipe for transporting the reaction solution from the first static mixer to the second static mixer, with the first static mixer and the reaction solution transporting pipe being disposed underwater in a vessel, and
a pump for feeding, as the dilution water, water held in the vessel into the second static mixer.

2. The apparatus of claim 1 , further comprising a hydrogen peroxide feed pipe and a sulfuric acid feed pipe which are located upstream from the first static mixer, each of the hydrogen peroxide feed pipe and the sulfuric acid feed pipe being equipped with a back pressure control valve.

3. The apparatus of claim 1 , wherein the reaction solution transporting pipe and a dilution water feed pipe are located upstream from the second static mixer, each of the reaction solution transporting pipe and the dilution water feed pipe being equipped with a back pressure control valve.

4. The apparatus of claim 1 , wherein the second static mixer is disposed underwater.

5. The apparatus of claim 1 , further comprising means for detecting the amount of water held in the vessel and means for controlling the amount of water to be fed into the vessel according to the detected water amount.

6. The apparatus of claim 1 , further comprising a detector for detecting a peroxide or an acid present in water held in the vessel.

7. The apparatus of claim 1 , further comprising means for detecting the temperature of the reaction solution released from the first static mixer and means for cutting, according to the detected temperature of the reaction solution released from the first static mixer, the hydrogen peroxide supply, the sulfuric acid supply or the supply of the hydrogen peroxide and the sulfuric acid.

8. The apparatus of claim 1 , further comprising means for detecting the temperature of the reaction solution released from the second static mixer and means for cutting, according to the detected temperature of the reaction solution released from the second static mixer, the hydrogen peroxide supply, the sulfuric acid supply or the supply of the hydrogen peroxide and the sulfuric acid.

9. The apparatus of claim 1 , wherein the reaction solution is further mixed with an aqueous alkaline solution in the second static mixer.

10. The apparatus of claim 1 , further comprising a third static mixer for mixing the reaction solution with an aqueous alkaline solution, located downstream from the first static mixer and upstream from the second static mixer.

11. The apparatus of claim 1 , further comprising a third static mixer for mixing the diluted reaction solution with an aqueous alkaline solution, located downstream from the second static mixer.

12. The apparatus of claim 9 , wherein the aqueous alkaline solution is fed through an aqueous alkaline solution feed pipe that is equipped with a back pressure control valve.

13. The apparatus of claim 10 , wherein the third static mixer is disposed underwater.

Assignees

• Mitsubishi Gas Chemical Co
• Mitsubishi Gas Chemical Co

Inventors

• Yoshida Kiyoshi
• Koshitsuka Tetsuo
• Tsuyuki Kaoru
• Uesugi Wakana

Classifications

• B01F15/065

  Operations & Transport · mapped topic

• B01J2219/002

  inside the reactor · CPC title

• B01J2219/00099

  the reactor being immersed in the heat exchange medium · CPC title

• B01J2219/00051

  Controlling the temperature · CPC title

• C01B15/08 Primary

  Peroxysulfates · CPC title