Production of polyisocyanurate foam panels

Patent metadata

Field	Value
Publication number	US-9987775-B2
Application number	US-201615191675-A
Country	US
Kind code	B2
Filing date	Jun 24, 2016
Priority date	May 25, 2012
Publication date	Jun 5, 2018
Grant date	Jun 5, 2018

Abstract

The present invention discloses the production of panels by a discontinuous process. The panels are produced by injecting a polyisocyanurate foam forming composition into the mold cavity at reduced pressure. The combination of certain polyisocyanurate foam forming formulation and the reduced pressure in the mold cavity allows production of and resulting sandwich panels in a discontinuous process where the produced panels are characterized by improved fire resistance.

First claim

The invention claimed is:

1. A method of making a polyisocyanurate (PIR) foam, comprising:
A) injecting into a closed mold cavity, wherein said mold cavity is under an absolute pressure of from 300 to 950 mbar, a reaction mixture comprising:
a) an organic polyisocyanate;
b) a polyol mixture, wherein the polyol mixture comprises an aromatic polyester polyol, wherein the aromatic polyester polyol is at least 35 weight percent of the total amount of polyol;
c) a trimerisation catalyst;
d) at least one flame retardant;
e) optionally auxiliary substances; and
f) a blowing agent component,

wherein said reaction mixture has an isocyanate index of greater than 250 and a gel time of at least 50 seconds; and
B) curing to form a polyisocyanurate foam.

2. The method according to claim 1 , wherein said closed mold cavity is defined by two exterior shells and an annular frame.

3. The method according to claim 1 , wherein the aromatic polyester polyol is at least 50 weight percent of the total amount of polyol.

4. The method according to claim 1 , wherein the reaction mixture has an isocyanate index of greater than 350.

5. The method according to claim 1 , wherein the mold cavity absolute pressure is from 800 to 950 mbar.

6. The method according to claim 1 , wherein the blowing agent component comprises a physical and chemical blowing agent.

7. The method according to claim 6 , wherein the chemical blowing agent is water, formic acid or a combination thereof.

8. The method according to claim 6 , wherein the physical blowing agent is pentane.

9. The method according to claim 1 , wherein the foam has an applied density of 30 to 75 kg/m3.

10. The method according to claim 1 , wherein the reaction mixture additionally comprises a silicone surfactant.

11. The method according to claim 1 , wherein the flame retardant is a halogen free flame retardant.

12. The method according to claim 1 , wherein the aromatic polyester polyol is at least 50 weight percent and less than 80 weight percent of the total amount of polyol.

13. The method according to claim 12 , wherein the aromatic polyester polyol is derived from phthalic anhydride, phthalic acid, isophthalic acid, terephthalic acid, methyl esters of phthalic, isophthalic acid, terephthalic acid, dimethyl terephthalate, trimellitic anhydride, pyromellitic dianhydride, or mixtures thereof.

14. The method according to claim 1 , wherein the aromatic polyester polyol is derived from phthalic anhydride, phthalic acid, isophthalic acid, terephthalic acid, methyl esters of phthalic, isophthalic acid, terephthalic acid, dimethyl terephthalate, trimellitic anhydride, pyromellitic dianhydride, or mixtures thereof.

15. The method according to claim 1 , wherein the polyol mixture further includes from 10 to 60 weight percent of a novolac initiated polyether polyol, of the total amount of polyol.

Assignees

• Dow Global Technologies Llc

Inventors

• Bertucelli Luigi
• Fantera Giuseppe
• Golini Paolo

Classifications

• C08J9/0038

  containing phosphorus · CPC title

• C08J9/0019

  halogenated · CPC title

• C08G18/4018

  Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48 · CPC title

• B29K2105/0026

  Flame proofing or flame retarding agents · CPC title

• B29C44/42

  using pressure difference, e.g. by injection or by vacuum · CPC title