Method for the production of high internal phase emulsion foams
US-9574058-B2 · Feb 21, 2017 · US
US2016279840A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2016279840-A1 |
| Application number | US-201514665494-A |
| Country | US |
| Kind code | A1 |
| Filing date | Mar 23, 2015 |
| Priority date | Mar 23, 2015 |
| Publication date | Sep 29, 2016 |
| Grant date | — |
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Systems and methods for improving adhesion of an insulating foam to a molded polymeric insulating structure through use of ozone gas for functionalization of molded polymeric surfaces of an internal cavity of the insulating structure.
Opening claim text (preview).
We claim: 1 . A method of manufacturing an insulating container, comprising: molding an external structure of the insulating container from a polymer, the external structure comprising: an inner trough; an outer shell coupled to the inner trough by a top edge surface; an internal cavity spaced between the inner trough and the outer shell and extending around four sides and a base of the external structure; a first opening extending into the internal cavity at a first corner of a base surface of the outer shell; a second opening extending into the internal cavity at a second corner, opposite the first corner, of the base surface of the outer shell; positioning the external structure such that the second opening is above the first opening; injecting an ozone gas containing 5-7.5% ozone into the first opening; filling at least 80% of the cavity with the ozone gas to displace a mass of air out through the second opening; flushing the cavity with air to remove ozone gas from the cavity; and filling the cavity with an insulating foam. 2 . The method of claim 1 , wherein a volume flow rate of the ozone gas into the first opening is such that a volume of the cavity is filled in at least 4 minutes. 3 . The method of claim 1 , wherein a volume flow rate of the ozone gas into the first opening is such that a volume of the cavity is filled in at most 10 minutes. 4 . The method of claim 1 , wherein the flushing the cavity with air further comprises flushing for at least 2 minutes. 5 . The method of claim 1 , wherein the flushing the cavity with air to remove ozone gas comprises removing at least 95% of the ozone gas from the cavity. 6 . The method of claim 1 , wherein the flushing the cavity with air to remove ozone gas comprises removing at least 97% of the ozone gas from the cavity. 7 . The method of claim 1 , wherein the flushing the cavity with air to remove ozone gas comprises removing at least 99% of the ozone gas from the cavity. 8 . The method of claim 1 , wherein the molding of the external structure utilizes a rotational molding process. 9 . The method of claim 1 , wherein the polymer is polyethylene. 10 . The method of claim 1 , wherein the insulating foam is polyurethane. 11 . The method of claim 1 , wherein the ozone gas is injected at room temperature. 12 . The method of claim 1 , wherein the outer shell has a substantially cuboidal shape. 13 . A method for producing an insulating structure, comprising: (a) molding an outer shell of the insulating structure from a polymer, the outer shell comprising: an internal cavity; a first opening extending into the internal cavity; a second opening extending into the internal cavity; (b) positioning the outer shell such that the second opening is above the first opening; (c) injecting an ozone gas containing 5-7.5% ozone into the first opening; (d) filling the cavity with the ozone gas to displace a mass of air out through the second opening; (e) at a time after step (d), filling the cavity with a gas to remove at least 97% of the ozone gas from the cavity; and (f) injecting an insulating foam into the cavity. 14 . The method of claim 13 , wherein a volume flow rate of the ozone gas into the first opening is such that a volume of the cavity is filled in at least 4 minutes. 15 . The method of claim 13 , wherein a volume flow rate of the ozone gas into the first opening is such that a volume of the cavity is filled in approximately 4-10 minutes. 16 . The method of claim 13 , wherein step (e) begins approximately 4 to 10 minutes after step (c) began. 17 . The method of claim 13 , wherein step (e) is completed within no more than two minutes after step (e) began. 18 . The method of claim 13 , wherein step (d) of filling the cavity with the ozone gas to displace a mass of air out through the second opening comprises filling at least 90% of the cavity with ozone gas. 19 . The method of claim 13 , wherein step (d) of filling the cavity with the ozone gas to displace a mass of air out through the second opening comprises filling at least 95% of the cavity with ozone gas. 20 . The method of claim 13 , wherein the molding of the outer shell utilizes a rotational molding process. 21 . The method of claim 13 , wherein the polymer is polyethylene. 22 . The method of claim 13 , wherein the gas is air. 23 . The method of claim 13 , wherein the first opening is adjacent a bottom portion of the internal cavity and the second opening is adjacent a top portion of the internal cavity. 24 . A method for manufacturing a cooler, comprising: (a) molding an external structure of the cooler from polyethylene, the external structure comprising: an inner trough; an outer shell coupled to the inner trough by a top edge surface; an internal cavity spaced between the inner trough and the outer shell and extending around four sides and a base of the external structure; a first opening extending into the internal cavity at a first corner of a base surface of the outer shell; a second opening extending into the internal cavity at a second corner, opposite the first corner, of the base surface of the outer shell; (b) positioning the external structure such that the second opening is above the first opening; (c) injecting an ozone gas containing 5-7.5% ozone into the first opening; (d) filling at least 90% of the cavity with the ozone gas in at least four minutes to displace a mass of air out through the second opening; (e) flushing the cavity with air for at least two minutes to remove ozone gas from the cavity; and (f) filling the cavity with polyurethane insulating foam. 25 . The method of claim 24 , wherein the outer shell has a substantially cuboidal shape.
Use of {PU, i.e.} polyureas or polyurethanes {or derivatives thereof}, as moulding material · CPC title
by rotating a mould around its axis of symmetry (for concrete B28B21/30) · CPC title
Filling preformed cavities {(B29C44/1204 takes precedence)} · CPC title
PE, i.e. polyethylene · CPC title
Foaming under special conditions, e.g. in sub-atmospheric pressure, in or on a liquid · CPC title
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