Solid oxide fuel cell structures, and related compositions and processes

Patent metadata

Field	Value
Publication number	US-9985295-B2
Application number	US-23555505-A
Country	US
Kind code	B2
Filing date	Sep 26, 2005
Priority date	Sep 26, 2005
Publication date	May 29, 2018
Grant date	May 29, 2018

Abstract

A solid oxide fuel cell is disclosed. The fuel cell includes a porous anode, formed of finely-dispersed nickel/stabilized-zirconia powder particles. The particles have an average diameter of less than about 300 nanometers. They are also characterized by a tri-phase length of greater than about 50 μm/μm 3 . A solid oxide fuel cell stack is also described, along with a method of forming an anode for a solid oxide fuel cell. The method includes the step of using a spray-agglomerated, nickel oxide/stabilized-zirconia powder to form the anode.

First claim

What is claimed is:

1. A solid oxide fuel cell, comprising:
(I) a porous anode, comprising a layer of finely-dispersed nickel oxide/stabilized-zirconia powder particles, wherein the particles have an average diameter of less than 200 nanometers; and wherein the layer of particles is further characterized by a tri-phase length of greater than 50 μm/μm 3 ;
(II) a porous cathode, spaced from the anode;
(III) an electrolyte, disposed between the anode and the cathode; and
(IV) at least one interconnect structure, attached to at least one of elements (I) or (II), and capable of accommodating the flow of fuel and/or oxidant through the fuel cell.

2. The solid oxide fuel cell of claim 1 , wherein the anode has a porosity of at least 10%.

3. The solid oxide fuel cell of claim 2 , wherein the anode has a porosity of at least 25%.

4. The solid oxide fuel cell of claim 1 , wherein the weight ratio of nickel oxide to stabilized zirconia is in the range of 20:80 to 80:20.

5. The solid oxide fuel cell of claim 1 , further comprising a porous support layer on which the anode is disposed.

6. The solid oxide fuel cell of claim 1 , wherein the porous cathode of component (II) comprises a material selected from the group consisting of stabilized zirconia impregnated with praseodymium oxide; stabilized zirconia impregnated with strontium-doped lanthanum; manganate (LSM); strontium-doped lanthanum ferrite (LSF); strontium-doped scandium cobaltite (SSC); La—Sr—Co—Fe—O-based materials, and combinations thereof; and the electrolyte of component (III) comprises a material selected from the group consisting of stabilized zirconia; scandia-doped cerium oxide, gadolinium-doped cerium oxide, strontium-magnesium-doped lanthanum gallate (LSGM), and combinations thereof.

7. The solid oxide fuel cell of claim 1 , wherein the electrolyte has a thickness which is less than 50 microns.

8. A solid oxide fuel cell, comprising a cathode-electrolyte-anode unit and at least one interconnect structure, wherein the anode comprises a layer of finely-dispersed nickel oxide/stabilized-zirconia powder particles which have an average diameter of less than 200 nanometers; and wherein the layer of particles is further characterized by a tri-phase length of greater than 50 μm/μm 3 .

9. A solid oxide fuel cell stack, comprising
a) a plurality of fuel cell units, each including an anode, a cathode, and an electrolyte which separates the anode and the cathode; and
b) at least one interconnect structure situated between each fuel cell unit; capable of accommodating the flow of fuel and/or oxidant through adjacent fuel cell units, and capable of completing an electrical circuit through the fuel cell stack;
wherein the anode in each fuel cell unit comprises a layer of finely-dispersed nickel oxide/stabilized-zirconia powder particles which have an average diameter of less than 200 nanometers; and wherein the layer of particles is further characterized by a tri-phase length of greater than about 50 μm/μm 3 .

10. A porous anode for a fuel cell, comprising a layer of finely dispersed nickel/stabilized-zirconia powder particles, wherein the particles have an average diameter of less than 200 nanometers; and wherein the layer of particles is further characterized by a tri-phase length of greater than 50 μm/μm 3 .

11. The solid oxide fuel cell of claim 1 , wherein the nickel oxide/stabilized-zirconia particles are spray-agglomerated.

12. The solid oxide fuel cell of claim 11 , wherein the spray-agglomerated particles are prepared by a combustion spray pyrolysis technique.

13. The solid oxide fuel cell of claim 1 , wherein the weight ratio of nickel oxide to stabilized zirconia is 60:40.

Assignees

• Korevaar Bastiaan Arie
• Lau Yuk Chiu
• Kebbede Anteneh
• Acharya Harish Radhakrishna
• Ramamurthi Badri Narayan
• Parker Gregory John
• Gen Electric

Inventors

• Korevaar Bastiaan Arie
• Lau Yuk-Chiu
• Kebbede Anteneh
• Acharya Harish Radhakrishna
• Ramamurthi Badri Narayan
• Parker Gregory John

Classifications

• H01M8/1246

  the electrolyte consisting of oxides · CPC title

• H01M4/9025 Primary

  Oxides specially used in fuel cell operating at high temperature, e.g. SOFC · CPC title

• H01M4/9066

  of metal-ceramic composites or mixtures, e.g. cermets · CPC title

• H01M4/8621

  containing only metallic or ceramic material, e.g. made by sintering or sputtering · CPC title

• Y02E60/525

  Cross-Sectional Technologies · mapped topic