Photocurable elastomer composition, gasket for hard disk drive, and hard disk drive

Patent metadata

Field	Value
Publication number	US-9982124-B2
Application number	US-201414762877-A
Country	US
Kind code	B2
Filing date	Feb 4, 2014
Priority date	Feb 4, 2013
Publication date	May 29, 2018
Grant date	May 29, 2018

Abstract

Disclosed is a photocurable elastomer composition that exhibits, when cured, excellent flexibility and barrier properties and has low compression set. The photocurable elastomer composition may comprise components (A) to (D) such that the mass ratio of the component (A) to the component (B) ((A):(B)) is from 25:75 to 75:25, and that the content of the component (C) is 50 mass % or less based on the total content of the components (A), (B), and (C).

First claim

The invention claimed is:

1. A photocurable elastomer composition comprising:
(A)
a styrene-based thermoplastic elastomer selected from the group consisting of a polystyrene-polybutadiene-polystyrene block copolymer, a polystyrene-polyisoprene-polystyrene block copolymer, a polystyrene-poly(vinyl/polyisoprene)-polystyrene block copolymer, a polystyrene-poly(isoprene/ethylene)-polystyrene block copolymer, and partially hydrogenated products thereof; and a polystyrene-polyisobutylene-polystyrene block copolymer, a polystyrene-poly(ethylene/butylene)-polystyrene block copolymer, a polystyrene-poly(ethylene/propylene)-polystyrene block copolymer, a polystyrene-poly(vinyl/ethylene/propylene)-polystyrene, and a polystyrene-poly(ethylene/ethylene/propylene)-polystyrene;

(B) a polymer having two or more reactive functional groups per molecule and containing, in its molecule, 80% or more of units derived from polyisoprene, the reactive functional groups being of at least one type selected from the group consisting of (meth)acrylic group, vinyl group, vinylidene group, and maleimide group;
(C) a (meth)acrylate monomer;
(D) a photopolymerization initiator; and
(E) at least one selected from an inorganic filler or an organic filler,
wherein the mass ratio of the component (A) to the component (B) ((A):(B)) is from 25:75 to 75:25, and the content of the component (C) is 50 mass % or less based on the total amount of the components (A), (B), and (C).

2. The photocurable elastomer composition according to claim 1 , wherein the component (C) is at least one (meth)acrylate selected from the group consisting of hydrocarbon (meth)acrylate having 6 or more carbon atoms, isobornyl (meth)acrylate, and (meth)acrylate derived from dicyclopentadiene.

3. The photocurable elastomer composition according to claim 1 , wherein the component (E) is a fumed silica.

4. The photocurable elastomer composition according to claim 1 , wherein the photocurable elastomer composition is used for a gasket for hard disk drives.

5. A gasket for hard disk drives, the gasket using the photocurable elastomer composition according to claim 1 in at least a portion thereof.

6. A hard disk drive comprising the gasket for hard disk drives according to claim 5 in at least a portion thereof.

Assignees

• Bridgestone Corp

Inventors

• Kurata Toshihiko

Classifications

• C08L2201/14

  Gas barrier composition · CPC title

• C08L51/006

  grafted on to block copolymers containing at least one sequence of polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• C09D151/003

  grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds (C09D151/04, C09D151/06 take precedence) · CPC title

• C09K2003/1062

  UV-curable materials · CPC title

• C08F290/048

  Polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 · CPC title