Dispersant viscosity modifiers

Patent metadata

Field	Value
Publication number	US-9663744-B2
Application number	US-201414771574-A
Country	US
Kind code	B2
Filing date	Feb 14, 2014
Priority date	Mar 12, 2013
Publication date	May 30, 2017
Grant date	May 30, 2017

Abstract

The invention provides a dispersant viscosity modifier, and more specifically a metal free dispersant viscosity modifier. The invention provides compositions, including lubricating compositions containing the described dispersant viscosity modifier, such as heavy duty diesel lubricating compositions. The invention further relates to the use of the described dispersant viscosity modifier to improve the film thickness and/or antiwear performance of a lubricating composition, for example, a heavy duty diesel lubricating composition. The improved dispersant viscosity modifier of the invention is specially designed to protect against valve train and other crankcase wear in lubricating applications, including heavy soot conditions such as heavy duty diesel lubricating applications.

First claim

What is claimed:

1. A composition comprising a dispersant viscosity modifier comprising an olefin-based polymer and one or more functional groups each independently attached to the olefin-based polymer,
where the functional group comprises a linking group grafted onto the olefin-based polymer and an alpha-hydroxy or alpha-alkoxy carboxy group connected to the linking group.

2. The composition of claim 1 wherein each functional group is represented by the structure:
-M-C(═O)—C(R 1 ) 2 —O—R 2

where M is a linking group, each R 1 is independently hydrogen or a hydrocarbyl group, and R 2 is hydrogen or a hydrocarbyl group or a polyalkyleneglycol (PAG) group, where R 2 may contain a ring or be linked to a R 1 , when R 1 is a hydrocarbyl group, to form a ring.

3. The composition of claim 2 where R 2 is hydrogen or a linear alkyl group containing from 1 to 8 carbon atoms.

4. The composition of claim 1 wherein the dispersant viscosity modifier group is represented by the structure:
P-(M-C(═O)—C(R 1 ) 2 —O—R 2 ) n

where P is an olefin-based polymer backbone, n is an integer from 1 to 6, M is a linking group, each R 1 is independently hydrogen or a hydrocarbyl group, and each R 2 is independently hydrogen or a hydrocarbyl group or a polyalkyleneglycol (PAG) group, where R 2 may contain a ring or be linked to R 1 to form a ring.

5. The composition of claim 4 wherein P is an ethylene-olefin-based copolymer, n is an integer from 1 to 4, each R 1 is hydrogen, and R 2 is hydrogen or a hydrocarbyl group.

6. The composition of claim 4 where R 2 is hydrogen or a linear alkyl group containing from 1 to 8 carbon atoms.

7. The compositions of claim 1 wherein the olefin-based polymer has a number average molecular weight greater than 5000.

8. The compositions of claim 1 wherein the olefin-based polymer is an ethylene-olefin-based copolymer where ethylene makes up at least 10 percent of the monomer used to prepare the copolymer on a molar basis.

9. The composition of claim 1 where the linking group is derived from an (i) unsaturated carboxylic reactant and (ii) a hydroxy alkyl amine, an alkylene polyamine, a polyol, or a combination thereof.

10. The composition of claim 9 wherein the linking group is derived from maleic anhydride and a hydroxy alkyl amine.

11. A composition comprising a dispersant viscosity modifier comprising an olefin-based polymer which has been grafted with an unsaturated carboxylic reactant resulting in an olefin-based polymer with one or more acylating groups each independently attached to the polymer,
where the acylating groups are further modified by reaction with a hydroxy alkyl amine, an alkylene polyamine, or a combination thereof, resulting in an olefin-based polymer with one or more linking groups each independently attached along the polymer, and
where the linking groups are further modified by reaction with a material having the structure:
R 6 O—C(═O)—C(R 1 ) 2 —OR 2

where R 1 is hydrogen or a hydrocarbyl group; R 2 is hydrogen or a hydrocarbyl group or a polyalkyleneglycol (PAG) group; where R 2 may contain a ring or be linked to a R 1 , when R 1 is a hydrocarbyl group, to form a ring; where R 6 is hydrogen or a hydrocarbyl group;
resulting in a dispersant viscosity modifier.

12. A lubricant composition comprising a major amount of an oil of lubricating viscosity and a minor amount of the dispersant viscosity modifier of claim 1 .

13. The lubricant composition of claim 12 wherein the composition further comprises a dispersant, a detergent, an overbased detergent, an antioxidant a viscosity modifier, a friction modifier, a corrosion inhibitor, a pour point depressant, a seal swell agent, a demulsifier, an antiwear agent, or any combination thereof.

14. A process of making a dispersant viscosity modifier comprising the steps of:
(I) grafting one or more unsaturated carboxylic reactants onto the backbone of an olefin-based polymer, resulting in an olefin-based polymer with one or more acylating groups each independently attached along the polymer's backbone;
(II) reacting each acylating group with a hydroxy alkyl amine, an alkylene polyamine, a polyol, or a combination thereof, resulting in an olefin-based polymer with one or more linking groups each independently attached along the polymer's backbone;
(III) reacting each linking group with a material having the structure:
R 6 O—C(═O)—C(R 1 ) 2 —OR 2

where R 1 is hydrogen or a hydrocarbyl group; R 2 is hydrogen or a hydrocarbyl group or a polyalkyleneglycol (PAG) group; where R 2 may contain a ring or be linked to a R 1 , when R 1 is a hydrocarbyl group, to form a ring; where R 6 is hydrogen or a hydrocarbyl group;
resulting in a dispersant viscosity modifier.

15. A method of reducing wear in an internal combustion engine comprising lubricating said engine with the lubricating composition of claim 12 .

Assignees

• Lubrizol Corp

Inventors

• Zhang Yanshi
• Gieselman Matthew D
• Preston Adam J

Classifications

• C10M159/12

  Reaction products · CPC title

• C10N2040/25

  Internal-combustion engines · CPC title

• C10N2030/56

  Boundary lubrication or thin film lubrication · CPC title

• C08F8/48

  Isomerisation; Cyclisation · CPC title

• C08F8/14

  Esterification · CPC title