Method and a device for synthesizing 1.2-dichloroethane

Patent metadata

Field	Value
Publication number	US-9981890-B2
Application number	US-201515329992-A
Country	US
Kind code	B2
Filing date	Jul 27, 2015
Priority date	Jul 29, 2014
Publication date	May 29, 2018
Grant date	May 29, 2018

Abstract

The invention relates to a method for synthesizing 1.2-dichloroethane from ethylene and chlorine via low temperature direct chlorination of ethylene in the presence of a catalyst under conditions in which the synthesized 1.2-dichloroethane is condensed out, however, the ethylene and the chlorine are gaseous, in a reactor ( 3 ), wherein the stoichiometric ratio of ethylene to chlorine is adjusted in the reactor ( 3 ) such that there is an excess of ethylene. The invention further relates to a device for synthesizing 1.2-dichloroethane from ethylene and chlorine via low temperature direct chlorination of ethylene in the presence of a catalyst under conditions in which the synthesized 1.2-dichloroethane is condensed out, however, the ethylene and the chlorine are gaseous, in a reactor ( 3 ), wherein the stoichiometric ratio of ethylene to chlorine is adjustable in the reactor ( 3 ) such that there is an excess of ethylene.

First claim

What is claimed is:

1. A method for synthesizing 1,2-dichloroethane from ethylene and chlorine by low temperature direct chlorination of ethylene in the presence of a catalyst in a reactor under conditions where the synthesized 1,2-dichloroethane condenses out while the ethylene and the chlorine are gaseous, which method comprises the step of adjusting the stoichiometric ratio of ethylene to chlorine in the reactor such that ethylene is present in excess.

2. The method as claimed in claim 1 , wherein the stoichiometric ratio of ethylene to chlorine is not less than 1.01:1.

3. The method as claimed in claim 1 , wherein the stoichiometric ratio of ethylene to chlorine in the reactor is monitored and the feed of ethylene and chlorine to the reactor is closed loop controlled such that ethylene is present in excess.

4. The method as claimed in claim 1 , wherein a 1,2-dichloroethane liquid stream is withdrawn from the reactor and is partly vaporized in a vaporizing device.

5. The method as claimed in claim 4 , wherein less than 50% of the 1,2-dichloroethane stream removed from the reactor is vaporized in the vaporizing device.

6. The method as claimed in claim 4 , wherein the proportion to which the 1,2-dichloroethane stream removed from the reactor is vaporized in the vaporizing device corresponds to the 1,2-dichloroethane quantity produced in said reactor.

7. The method as claimed in claim 4 , wherein the vaporizing device is configured as a falling stream evaporator.

8. The method as claimed in claim 4 , wherein the nonvaporized proportion of the 1,2-dichloroethane stream withdrawn from the reactor is returned into the reactor.

9. The method as claimed in claim 4 , wherein the vaporizing device is heated using the reaction heat from a plant for high temperature direct chlorination of ethylene.

10. The method as claimed in claim 4 , wherein the vaporous 1,2-dichloroethane stream emerging from the vaporizing device is fed into a distillation column.

11. The method as claimed in claim 4 , wherein the vaporizing device is heated using the condensation heat from the vapor of a distillation column.

12. The method as claimed in claim 10 , wherein the distillation column is used to separate off compounds having a higher boiling point than 1,2-dichloroethane.

13. The method as claimed in claim 11 , wherein the distillation column is operated at an overhead temperature in the range from 120° C. to 150° C.

14. The method as claimed in claim 4 , wherein before being fed to the vaporizing device, the 1,2-dichloroethane stream removed from the reactor is preheated using a 1,2-dichloroethane stream withdrawn from the vaporizing device and/or using a 1,2-dichloroethane stream from a plant for high temperature direct chlorination of ethylene.

15. The method as claimed in claim 1 , wherein the catalyst comprises FeCl 3 and/or NaCl.

16. The method as claimed in claim 1 , wherein an ethylene-containing off-gas from a high temperature direct chlorination reactor is fed to the reactor.

17. A device for synthesizing 1,2-dichloroethane from ethylene and chlorine according to the method of claim 1 , wherein the device is configured for low temperature direct chlorination of ethylene in the presence of a catalyst in a reactor under conditions where the synthesized 1,2-dichloroethane condenses out while the ethylene and the chlorine are gaseous, wherein the stoichiometric ratio of ethylene to chlorine in the reactor is adjustable such that ethylene is present in excess.

18. The method as claimed in claim 4 , wherein the vaporizing device is single-staged.

19. The method as claimed in claim 13 , wherein the overhead temperature is in the range from 127° C. to 135° C.

20. The method as claimed in claim 14 , wherein the 1,2-dichloroethane stream is liquid.

Assignees

• Thyssenkrupp Ind Solutions Ag
• Thyssenkrupp Ag
• Vinnolit Gmbh & Co Kg

Inventors

• Benje Michael

Classifications

• B01J2219/24

  Stationary reactors without moving elements inside · CPC title

• C07C17/02 Primary

  to unsaturated hydrocarbons · CPC title

• B01J19/24

  Stationary reactors without moving elements inside (B01J19/08, B01J19/26 take precedence; with stationary particles B01J8/02) · CPC title