Method to improve halogenation reactions

Patent metadata

Field	Value
Publication number	US-9416073-B2
Application number	US-201514873346-A
Country	US
Kind code	B2
Filing date	Oct 2, 2015
Priority date	Oct 6, 2014
Publication date	Aug 16, 2016
Grant date	Aug 16, 2016

Abstract

In the halogenation reaction of olefin/halo-olefin (i.e., organic), an excess amount of halogen gas (fluorine, chlorine, vaporized bromine and iodine, or their combination) is normally used in order to achieve as complete as possible conversion of the organic. In a conventional process, the excess halogen gas in the off-gas stream is scrubbed by caustic solution which increases the consumption of halogen and generates waste for disposal. The present invention provides a novel process to recover and reuse the excess halogen gas and thus reduce the operating cost of the process.

First claim

What is claimed is:

1. A process for the halogenation reaction of an organic starting material comprising halo-olefin compounds comprising the steps of:
(a) conducting the halogenation reaction of the organic starting material in a first reactor using excess halogen, and
(b) conducting the halogenation reaction of the organic starting material in a second reactor using the excess halogen from step (a) to halogenate an excess amount of the organic starting material contained in the second reactor.

2. The process of claim 1 , wherein the reactors used in the process are halogenation reactors selected from the group consisting of CSTR, plug flow reactor, and combinations thereof.

3. The process of claim 1 , which is conducted in a batch mode.

4. The process of claim 1 , which is conducted in a continuous mode.

5. The process of claim 1 , wherein the halogen gas used in the process is selected from the group consisting of fluorine, chlorine, bromine, iodine, and combinations thereof.

6. The process of claim 1 , wherein the organic starting material comprises a halo-olefin compound.

7. The process of claim 1 , which comprises the chlorination of 1,1,3-trichloropropene (HCC-1240za) to make 1,1,1,2,3-pentachloropropane (HCC-240db).

8. The process of claim 7 , wherein the reactors used in the process are halogenation reactors selected from the group consisting of CSTR, plug flow reactor, and combinations thereof.

9. The process of claim 1 , wherein the reactors can be either empty or packed with a halogen-resistant material to assist with the reaction.

10. The process of claim 9 , wherein at least one reactor includes packing material.

11. The process of claim 10 , wherein the packing material is selected from the group consisting of Stainless Steel, Inconel, Monel, and metal alloys.

12. The process of claim 10 , wherein the packing material comprises fluorocarbon plastics.

13. The process of claim 12 , wherein the packing material comprises PFA.

14. The process of claim 12 , wherein the packing material comprises PTFE.

Assignees

• Honeywell Int Inc

Inventors

• Yang Terris
• Tung Hsueh Sung

Classifications

• B01J2219/30466

  Plastics · CPC title

• B01J2219/30408

  Metal · CPC title

• B01J19/30

  Loose or shaped packing elements, e.g. Raschig rings or Berl saddles, for pouring into the apparatus for mass or heat transfer · CPC title

• B01J19/245

  placed in series · CPC title

• B01J2219/24

  Stationary reactors without moving elements inside · CPC title