Layered infrared transmitting optical elements and method for making same

Patent metadata

Field	Value
Publication number	US-9981459-B2
Application number	US-201414210828-A
Country	US
Kind code	B2
Filing date	Mar 14, 2014
Priority date	Mar 15, 2013
Publication date	May 29, 2018
Grant date	May 29, 2018

Abstract

A method for bonding infrared transmitting glasses into an optical element without interlayer voids by stacking at least two different infrared transmitting glasses inside a vessel where each glass has a different refractive index, a different dispersion, or both, and where the glasses all have similar viscosities, thermal expansion coefficients, and glass transition temperatures; placing a weight on top of the stack; applying a vacuum to the vessel; applying an isostatic pressure of at least 1500 psi; and after releasing the isostatic pressure, annealing at a temperature within 10° C. of the glass transition temperature at a pressure between 0 and 1000 psi. Applying the vacuum, applying the isostatic pressure, and annealing are done sequentially and with no intermediate transitions to ambient temperature or pressure. Also disclosed is the related optical element made by this method.

First claim

What is claimed as new and desired to be protected by Letters Patent of the United States is:

1. A method for bonding infrared transmitting glasses into an optical element without interlayer voids, comprising:
stacking at least two different infrared transmitting glasses inside a vessel to form a stack of glasses, wherein each glass has a different refractive index, a different dispersion, or both, wherein the at least two different infrared transmitting glasses all have similar viscosities, thermal expansion coefficients, and glass transition temperatures, wherein the stack of glasses is placed between two non-reactive plates, and wherein one or both non-reactive plates have a flat center portion and a raised perimeter or wherein one or both non-reactive plates are in the shape of a ring;
placing a weight on top of the stack of glasses;
applying a vacuum to the vessel;
applying an isostatic pressure of at least 1500 psi; and
after releasing the isostatic pressure, annealing at a temperature within 10° C. of the glass transition temperature at a pressure between 0 and 1000 psi, wherein applying the vacuum, applying the isostatic pressure, and annealing are done sequentially and with no intermediate transitions to ambient temperature or pressure.

2. The method of claim 1 , wherein each glass comprises S, Se, Te, Ga, GeAs, Sn, Sb, Ag, or any combination thereof.

3. The method of claim 1 , wherein at least one glass comprises F, Cl, Br, I, or any combination thereof.

4. The method of claim 1 , wherein a guide sleeve is used to constrain lateral movement of the stack of glasses.

5. The method of claim 1 , wherein the vacuum is between 0.1 and 100 mTorr.

6. The method of claim 1 , where the vacuum is held for between 10 seconds and 60 minutes.

7. The method of claim 1 , wherein the isostatic pressure is between 1500 and 3000 psi.

8. The method of claim 1 , wherein the isostatic pressure is held for between 5 and 60 minutes.

9. The method of claim 1 , wherein the annealing is for a time between 20 minutes and 2 hours.

10. The method of claim 1 , wherein the at least two different infrared transmitting glasses are substantially flat prior to bonding.

11. The method of claim 1 , wherein after bonding the at least two different infrared transmitting glasses are slumped or molded.

12. A method for bonding infrared transmitting glasses into an optical element without interlayer voids, comprising:
stacking at least two different infrared transmitting glasses inside a vessel to form a stack of glasses, wherein each glass has a different refractive index, a different dispersion, or both, wherein the at least two different infrared transmitting glasses all have similar viscosities, thermal expansion coefficients, and glass transition temperatures, and wherein the at least two different infrared transmitting glasses have a convex curvature on at least one face prior to bonding;
placing a weight on top of the stack of glasses;
applying a vacuum to the vessel;
applying an isostatic pressure of at least 1500 psi; and
after releasing the isostatic pressure, annealing at a temperature within 10° C. of the glass transition temperature at a pressure between 0 and 1000 psi, wherein applying the vacuum, applying the isostatic pressure, and annealing are done sequentially and with no intermediate transitions to ambient temperature or pressure.

13. The method of claim 12 , wherein each glass comprises S, Se, Te, Ga, GeAs, Sn, Sb, Ag, or any combination thereof.

14. The method of claim 12 , wherein at least one glass comprises F, Cl, Br, I, or any combination thereof.

15. The method of claim 12 , wherein a guide sleeve is used to constrain lateral movement of the stack of glasses.

16. The method of claim 12 , wherein the vacuum is between 0.1 and 100 mTorr.

17. The method of claim 12 , where the vacuum is held for between 10 seconds and 60 minutes.

18. The method of claim 12 , wherein the isostatic pressure is between 1500 and 3000 psi.

19. The method of claim 12 , wherein the isostatic pressure is held for between 5 and 60 minutes.

20. The method of claim 12 , wherein the annealing is for a time between 20 minutes and 2 hours.

Assignees

• Gibson Daniel J
• Kotov Mikhail
• Chin Geoff
• Bayya Shyam S
• Sanghera Jasbinder S
• Us Navy

Inventors

• Gibson Daniel J
• Kotov Mikhail
• Chin Geoff
• Bayya Shyam S
• Sanghera Jasbinder S

Classifications

• B32B37/1018

  using only vacuum · CPC title

• B32B37/144

  using layers with different mechanical or chemical conditions or properties, e.g. layers with different thermal shrinkage, layers under tension during bonding (constructional features for tensioning B32B38/1825) · CPC title

• B32B2309/62

  Inert · CPC title

• B32B2037/0092

  in which absence of adhesives is explicitly presented as an advantage · CPC title

• B32B37/003

  to avoid air inclusion · CPC title