Determining modified TAN-IR in crude oil

Patent metadata

Field	Value
Publication number	US-9976092-B2
Application number	US-201514927618-A
Country	US
Kind code	B2
Filing date	Oct 30, 2015
Priority date	Nov 24, 2014
Publication date	May 22, 2018
Grant date	May 22, 2018

Abstract

A method for determining a TAN-IR for naphthenic acids in crude oil or crude oil fraction may include determining an IR spectrum of a sample of the crude oil or crude oil fraction. The method may include determining an IR spectrum of a neutralized sample of the crude oil or crude oil fraction. The method may include utilizing the IR spectra of the sample and the neutralized sample to determine a modified TAN-IR.

First claim

What is claimed is:

1. A method comprising:
obtaining a first sample and a second sample of a crude oil or crude oil fraction that contains naphthenic acid;
determining an IR spectrum of the first sample;
contacting the second sample with a metallic hydroxide to form a neutralized sample, wherein the metallic hydroxide comprises magnesium hydroxide, sodium hydroxide, or potassium hydroxide;
determining an IR spectrum of the neutralized sample, wherein the first sample, the neutralized sample, or both, are subjected to sonication prior to determining their IR spectrums;
subtracting the IR spectrum of the neutralized sample from the IR spectrum of the first sample to obtain a modified TAN-IR spectrum; and
using the modified TAN-IR spectrum to determine a formulation of a blend of the crude oil or crude oil fraction with additional crude oil or crude oil fraction, wherein the blend has a modified TAN-IR spectrum that is at or below a predetermined level.

2. The method of claim 1 , further comprising blending the crude oil or crude oil fraction with additional crude oil or crude oil fraction to form a blend having a modified TAN-IR at or below a predetermined level.

3. The method of claim 2 , further comprising feeding the blend to a distillation unit.

4. The method of claim 3 , wherein the distillation unit is an atmospheric or vacuum distillation unit.

5. The method of claim 1 , further comprising feeding the crude oil or crude oil fraction to a distillation unit.

6. The method of claim 5 , wherein the distillation unit is an atmospheric or vacuum distillation unit.

7. The method of claim 1 , wherein the second sample is contacted with an amount of the metallic hydroxide sufficient to neutralize all naphthenic acid in the crude oil or crude oil fraction.

8. The method of claim 1 , wherein each IR spectrum is taken within a wavelength range of from about 1,500 to about 2,500 cm −1 .

9. The method of claim 1 , further comprising evaluating a risk of corrosion in processing equipment in contact with the crude oil or crude oil fraction using the modified TAN-IR and a corrosion risk matrix by calculating an estimation of a corrosion rate.

10. The method of claim 1 , wherein the determination of the IR spectra and the determination of the modified TAN-IR spectrum is automated.

11. The method of claim 10 , further comprising using the determined modified TAN-IR spectrum in real-time, to determine the formulation of the blend of the crude oil or crude oil fraction with additional crude oil or crude oil fraction.

12. The method of claim 10 , further comprising using the determined modified TAN-IR spectrum, in real-time, to determine a naphthenic concentration in the crude oil or crude oil fraction.

13. The method of claim 10 , further comprising using the determined modified TAN-IR to determine adjustments to a formulation of a blend when the modified TAN-IR for the blend is above a predetermined level, wherein the blend comprises the crude oil or crude oil fraction and additional crude oil or crude oil fraction.

14. The method of claim 13 , wherein the modified TAN-IR and the adjustments to the formulation of the blend are determined while the blend is being fed to a distillation unit.

15. The method of claim 14 , further comprising adjusting the formulation of the blend to provide the blend with a modified TAN-IR that is at or below the predetermined level.

16. The method of claim 15 , wherein the formulation of the blend is adjusted while the blend is continuing to be fed to the distillation unit.

17. A method comprising:
determining a modified TAN-IR spectrum by subtracting an IR spectrum of a neutralized sample from an IR spectrum of a first sample, wherein the first sample comprises a portion of a crude oil or crude oil fraction that contains naphthenic acid, and wherein the neutralized sample comprises a portion of the crude oil or crude oil fraction after contact with a metallic hydroxide, wherein the metallic hydroxide comprises magnesium hydroxide, sodium hydroxide, or potassium hydroxide wherein the first sample, the neutralized sample, or both, are subjected to sonication prior to determining their IR spectrums; and
using the modified TAN-IR spectrum to determine a formulation of a blend of the crude oil or crude oil fraction with additional crude oil or crude oil fraction, wherein the blend has a modified TAN-IR spectrum that is at or below a predetermined level.

18. A method comprising:
obtaining a sample of a crude oil or crude oil fraction that contains naphthenic acid;
determining an IR spectrum of the sample;
contacting the sample with a metallic hydroxide to form a neutralized sample, wherein the metallic hydroxide comprises magnesium hydroxide, sodium hydroxide, or potassium hydroxide;
determining an IR spectrum of the neutralized sample; and
subtracting the IR spectrum of the neutralized sample from the IR spectrum of the sample to determine a modified TAN-IR spectrum, wherein the sample, the neutralized sample, or both, are subjected to sonication prior to determining their IR spectrums; and
using the modified TAN-IR spectrum to determine a formulation of a blend of the crude oil or crude oil fraction with additional crude oil or crude oil fraction, wherein the blend has a modified TAN-IR spectrum that is at or below a predetermined level.

Assignees

• Fina Technology

Inventors

• Déhais Fabrice
• Roumeau Xavier
• Wang Jun
• Jones Ryan
• Kelly Kevin

Classifications

• G01N2021/3595

  using FTIR · CPC title

• C10G19/02

  with aqueous alkaline solutions · CPC title

• C10G2300/203

  Naphthenic acids, TAN · CPC title

• G01N21/3577

  for analysing liquids, e.g. polluted water · CPC title

• C10G7/10 Primary

  Inhibiting corrosion during distillation · CPC title