Method of reducing corrosion and corrosion byproduct deposition in a crude unit

Patent metadata

Field	Value
Publication number	US-9969947-B2
Application number	US-201715475340-A
Country	US
Kind code	B2
Filing date	Mar 31, 2017
Priority date	Nov 3, 2008
Publication date	May 15, 2018
Grant date	May 15, 2018

Abstract

A method of optimizing system parameters in a crude unit to reduce corrosion and corrosion byproduct deposition in the crude unit is disclosed and claimed. The method includes measuring or predicting properties associated with the system parameters and using an automated controller to analyze the properties to cause adjustments in the chemical program to optimize the system parameters. Adjusting the system parameters effectively controls corrosion in the crude unit by reducing the corrosiveness of a fluid in the process stream and/or by protecting the system from a potentially corrosive substance. System parameter sensing probes are arranged at one or more locations in the process stream to allow accurate monitoring of the system parameters in the crude unit.

First claim

The claimed invention is:

1. A method of inhibiting corrosion in a crude unit comprising a distillation tower equipped with an overhead heat exchanger and optionally an accumulator boot, the method comprising:
measuring and/or predicting pH of dew point water at an overhead heat exchanger of the distillation tower;
if the measured and/or predicted pH is outside of an optimum range associated with pH, causing a change in an influx of neutralizer into the crude unit, the neutralizer capable of adjusting the pH in a manner to bring the measured and/or predicted pH within said optimum range associated with pH;
measuring and/or predicting chloride concentration of the dew point water at the overhead heat exchanger of the distillation tower; and
if the measured and/or predicted chloride concentration is outside of an optimum range associated with chloride concentration, causing a change in an influx caustic agent into the crude unit, the caustic agent capable of adjusting the chloride concentration in a manner to bring the measured and/or predicted chloride concentration within said optimum range associated with chloride concentration.

2. The method of claim 1 , further comprising measuring and/or predicting iron concentration of water in the accumulator boot of the distillation tower; and
if the measured and/or predicted iron concentration is outside of an optimum range associated with iron concentration, causing a change in an influx of filming inhibitor into the crude unit, the filming inhibitor capable of adjusting the iron concentration in a manner to bring the measured and/or predicted iron concentration within said optimum range associated with iron concentration.

3. The method of claim 2 , including sampling the accumulator boot water with an online, optionally automated, sampling device.

4. The method of claim 2 , wherein the influx of filming inhibitor into the crude unit is upstream of an overhead heat exchanger bank.

5. The method of claim 2 , wherein the filming inhibitor is selected from an oil soluble blend of amides, an oil soluble blend of imidazolines, and combinations thereof.

6. The method of claim 1 , including sampling the dew point water with an online, optionally automated, sampling device.

7. The method of claim 1 , wherein the optimum range of pH and/or chloride concentration is user-defined.

8. The method of claim 1 , including operating the method continuously, automatically, online, or on a batch basis.

9. The method of claim 1 , wherein the influx of neutralizer into the crude unit is upstream of an overhead heat exchanger bank.

10. The method of claim 1 , wherein the influx of caustic agent into the crude unit is at a crude oil charge of the distillation tower.

11. The method of claim 1 , wherein the neutralizer is selected from 3-methoxypropylamine, monoethanolamine, N,N-dimethylaminoethanol, methoxyisopropylamine, and combinations thereof.

12. The method of claim 1 , wherein the caustic agent is sodium hydroxide.

Assignees

• Ecolab Usa Inc

Inventors

• Scattergood Glenn L
• Ferguson Sam

Classifications

• C10G7/12

  Controlling or regulating · CPC title

• C10G75/00 Primary

  Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general (C10G7/10, C10G9/16 take precedence) · CPC title

• C10G2300/4075

  Limiting deterioration of equipment · CPC title

• C10G75/02

  by addition of corrosion inhibitors · CPC title

• C10G7/10 Primary

  Inhibiting corrosion during distillation · CPC title