Composite material, method for forming the composite material, electrode plated with the composite material, and connection structure having the composite material

Patent metadata

Field	Value
Publication number	US-9970121-B2
Application number	US-201514982048-A
Country	US
Kind code	B2
Filing date	Dec 29, 2015
Priority date	Jan 8, 2015
Publication date	May 15, 2018
Grant date	May 15, 2018

Abstract

A composite material includes a metal material having conductivity and an oxidation inhibitor mixed with the metal material. The oxidation inhibitor forms a complex with the metal material to exert a resistance to oxidation of the metal material. For example, the composite material is formed on a surface of a base material as a plating material. As another example, the composite material is plated on a surface of an electrode.

First claim

What is claimed is:

1. A composite material comprising:
a metal material having conductivity; and
an oxidation inhibitor mixed with the metal material, the oxidation inhibitor forming a complex with the metal material, the complex of the oxidation inhibitor and the metal material having an activation energy of oxidation higher than that of a simple substance of the metal material to exert a resistance to oxidation of the metal material, wherein
the metal material includes a plurality of metal atoms,
the oxidation inhibitor includes a plurality of oxidation inhibitor molecules,
a metal bonding between the metal atoms and a coordinate bonding between the metal atom and the oxidation inhibitor molecule are stronger than an intermolecular interaction between the oxidation inhibitor molecules,
the metal atoms are bonded to form a metal mass,
each of a plurality of unit components is made of the metal mass and the oxidation inhibitor molecules bonded to the metal mass,
the plurality of unit components are uniformly distributed, and
the oxidation inhibitor completely encapsulates the metal mass in each of the plurality of unit components to provide a constant conductivity throughout the plurality of unit components collectively.

2. The composite material according to claim 1 , wherein
the oxidation inhibitor includes the oxidation inhibitor molecules containing carbons atoms in a range from 0.5 to 5.5% by mass of a total mass percentage of all elements forming the metal material and the oxidation inhibitor.

3. The composite material according to claim 1 , wherein
the oxidation inhibitor molecules include at least one of 1,10-phenanthroline, 1,10-phenanthroline hydrochloride, thiourea, and ethylenediaminetetraacetic acid.

4. The composite material according to claim 1 , wherein
the metal atoms are one of copper, tin, nickel, and an alloy containing at least one of copper, tin and nickel as a main component.

5. The composite material according to claim 1 , wherein
the oxidation inhibitor is 1,10-phenanthroline.

6. The composite material according to claim 5 , wherein
the metal material is copper.

7. The composite material according to claim 1 , wherein
a diameter of each of the plurality of unit components in which the oxidation inhibitor completely encapsulates the metal mass is 20 nm and the diameter of the metal mass within each of the plurality of unit components is less than 20 nm.

8. An electrode comprising:
a composite material; and
a base material, wherein
the composite material includes a metal material having conductivity and an oxidation inhibitor mixed with the metal material, the oxidation inhibitor forming a complex with the metal material, the complex of the oxidation inhibitor and the metal material has an activation energy of oxidation higher than that of a simple substance of the metal material to exert a resistance to oxidation of the metal material,
the metal material includes a plurality of metal atoms,
the oxidation inhibitor includes a plurality of oxidation inhibitor molecules,
a metal bonding between the metal atoms and a coordinate bonding between the metal atom and the oxidation inhibitor molecule are stronger than an intermolecular interaction between the oxidation inhibitor molecules,
the metal atoms are bonded to form a metal mass,
each of a plurality of unit components is made of the metal mass and the oxidation inhibitor molecules bonded to the metal mass,
the plurality of unit components are uniformly distributed,
the oxidation inhibitor completely encapsulates the metal mass in each of the plurality of unit components to provide a constant conductivity throughout the plurality of unit components collectively, and
the composite material is disposed on a surface of the base material as a plating material.

9. The electrode according to claim 8 , wherein
the oxidation inhibitor is 1,10-phenanthroline, and
the metal material is copper.

10. The electrode according to claim 8 , wherein
a diameter of each of the plurality of unit components in which the oxidation inhibitor completely encapsulates the metal mass is 20 nm and the diameter of the metal mass within each of the plurality of unit components is less than 20 nm.

11. A connection structure comprising:
a first electrode; and
a second electrode, wherein
a part of the second electrode is pressed against the first electrode due to a reaction force of the second electrode so that the second electrode is electrically connected to the first electrode, and
at least one of the first electrode and the second electrode has a surface plated with the a composite material, wherein
the composite material includes a metal material having conductivity and an oxidation inhibitor mixed with the metal material, the oxidation inhibitor forming a complex with the metal material, the complex of the oxidation inhibitor and the metal material has an activation energy of oxidation higher than that of a simple substance of the metal material thereby to exert a resistance to oxidation of the metal material,
the metal material includes a plurality of metal atoms,
the oxidation inhibitor includes a plurality of oxidation inhibitor molecules,
a metal bonding between the metal atoms and a coordinate bonding between the metal atom and the oxidation inhibitor molecule are stronger than an intermolecular interaction between the oxidation inhibitor molecules,
the metal atoms are bonded to form a metal mass,
each of a plurality of unit components is made of the metal mass and the oxidation inhibitor molecules bonded to the metal mass,
the plurality of unit components are uniformly distributed, and
the oxidation inhibitor completely encapsulates the metal mass in each of the plurality of unit components to provide a constant conductivity throughout the plurality of unit components collectively.

12. The connection structure according to claim 11 , wherein
the oxidation inhibitor is 1,10-phenanthroline, and
the metal material is copper.

13. The connection structure according to claim 11 , wherein a diameter of each of the plurality of unit components in which the oxidation inhibitor completely encapsulates the metal mass is 20 nm and the diameter of the metal mass within each of the plurality of unit components is less than 20 nm.

Assignees

• Denso Corp

Inventors

• Ochi Kenji
• Miyake Toshihiro
• Ishihara Yasuo

Classifications

• C25D3/12

  of nickel or cobalt · CPC title

• H01R13/03

  characterised by the material, e.g. plating, or coating materials · CPC title

• C25D3/56

  of alloys · CPC title

• C25D15/00

  Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires · CPC title

• C25D9/02 Primary

  with organic materials · CPC title