Electrically conductive adhesives, assemblies including the electrically conductive adhesives, and related methods

Patent metadata

Field	Value
Publication number	US-9963619-B2
Application number	US-201514951376-A
Country	US
Kind code	B2
Filing date	Nov 24, 2015
Priority date	Nov 24, 2015
Publication date	May 8, 2018
Grant date	May 8, 2018

Abstract

An assembly comprising a first article, a second article adjacent the first article, and an electrically conductive adhesive in electrical communication with the first article and the second article. The electrically conductive adhesive comprises nickel nanostrands dispersed in a matrix comprising a reaction product of bisphenol-F epoxy resin, resorcinol diglycidyl ether epoxy monomer, and at least one amine-containing curing agent. The electrically conductive adhesive exhibits a tensile adhesion strength greater than about 5,000 psi and a volume resistivity less than about 0.01 Ω·cm. Electrically conductive adhesives including nickel nanostrands, precursor packages of the electrically conductive adhesive, related methods of forming the electrically conductive adhesive and an assembly including the electrically conductive adhesive are also disclosed.

First claim

What is claimed is:

1. An assembly, comprising:
a first article;
a second article adjacent the first article; and
an electrically conductive adhesive comprising nickel nanostrands dispersed in a matrix comprising a reaction product of a diglycidyl ether of bisphenol-F epoxy resin, resorcinol diglycidyl ether epoxy monomer, and at least one amine-containing curing agent wherein the electrically conductive adhesive is in electrical communication with the first article and the second article wherein the reaction product comprises the following structure:

wherein the electrically conductive adhesive exhibits a tensile adhesion strength greater than about 5,000 psi and a volume resistivity less than about 0.01 Ω·cm.

2. The assembly of claim 1 , wherein the electrically conductive adhesive comprises between about two volume percent and about fifteen volume percent nickel nanostrands.

3. The assembly of claim 1 , wherein the electrically conductive adhesive further comprises another electrically conductive filler dispersed in the matrix.

4. The assembly of claim 1 , wherein the electrically conductive adhesive exhibits a tensile adhesion strength greater than about 6,000 psi.

5. The assembly of claim 1 , wherein the electrically conductive adhesive exhibits a volume resistivity less than about 0.005 Ω·cm.

6. The assembly of claim 1 , wherein at least one of the first article and the second article comprises a thermally insulative composite material.

7. The assembly of claim 1 , wherein at least one of the first article and the second article comprises an electrically conductive metallic mesh or an electrically conductive nonwoven material.

8. The assembly of claim 1 , wherein at least one of the first article and the second article comprises a bond strap and wherein the bond strap electrically connects the other of the first article and the second article to a third article.

9. The assembly of claim 1 , wherein the first article and the second article each comprise a thermally insulative, electrically conductive material.

10. The assembly of claim 1 , wherein the electrically conductive adhesive further comprises one or more conductive fillers selected from the group consisting of silver-coated microspheres, nickel-coated microspheres, silver-plated aluminum, nickel-coated graphite, silver-plated copper, silver-plated nickel, and combinations thereof.

11. The assembly of claim 1 , wherein the electrically conductive adhesive further comprises silver-coated ceramic spheres or silver-coated glass spheres.

12. The assembly of claim 1 , wherein the electrically conductive adhesive comprises between about 1 part and about 5 parts of the diglycidyl ether of bisphenol-F epoxy resin per 1 part of the resorcinol diglycidyl ether epoxy monomer.

13. The assembly of claim 1 , wherein the first article and the second article each comprise a portion of a space vehicle, an aerospace vehicle, or an aircraft.

14. The assembly of claim 1 , wherein the first article is secured to the second article with at least one fastener selected from the group consisting of a clevis fastener, a bolt, and a nut, the electrically conductive adhesive in electrical communication with each of the first article, the second article, and the at least one fastener.

15. An assembly including an electrically conductive adhesive, comprising the assembly comprising:
a first article and a second article; and
an electrically conductive adhesive comprising between about two volume percent and about fifteen volume percent nickel nanostrands dispersed within an adhesive matrix material, the adhesive matrix material comprising:
a reaction product of a diglycidyl ether of bisphenol-F epoxy resin and resorcinol diglycidyl ether epoxy monomer and at least one amine curing agent wherein the reaction product comprises the following structure:

wherein the electrically conductive adhesive exhibits a tensile strength greater than about 5,000 psi and a volume resistivity less than about 0.01 Ω·cm.

16. The assembly of claim 15 , wherein the electrically conductive adhesive exhibits a tensile adhesion strength of at least about 6,000 psi.

17. The assembly of claim 15 , wherein the adhesive matrix material comprises about ten volume percent nickel nanostrands dispersed therein.

18. The assembly of claim 15 , wherein the at least one amine curing agent comprises a polyetheramine.

19. The assembly of claim 15 , further comprising silver-coated microspheres dispersed within the adhesive matrix material.

20. The assembly of claim 15 , wherein the electrically conductive adhesive comprises:
about fifteen volume percent of the nickel nanostrands; and
between about two and about three parts diglycidyl ether of bisphenol-F epoxy resin per one part resorcinol diglycidyl ether epoxy monomer.

21. The assembly of claim 15 , wherein the adhesive matrix material comprises about 7 parts by weight of the diglycidyl ether of bisphenol-F epoxy resin for every about 3 parts by weight of the resorcinol diglycidyl ether epoxy monomer.

22. The assembly of claim 15 , wherein the electrically conductive adhesive exhibits a density less than about 2.5 g/cm 3 .

23. A method of forming an assembly, the method comprising:
providing at least a first article and at least a second article adjacent to the first article; and
disposing an electrically conductive adhesive comprising nickel nanostrands dispersed in a matrix comprising a reaction product of a diglycidyl ether of bisphenol-F epoxy resin, resorcinol diglycidyl ether epoxy monomer, and at least one amine-containing curing agent wherein the reaction product comprises the following structure:

 and exhibiting a tensile adhesion strength greater than about 5,000 psi and a volume resistivity less than about 0.01 Ω·cm between a surface of the first article and a surface of the second article to electrically interconnect the first article and the second article.

24. The method of claim 23 , further comprising selecting at least one of the at least a first article and the at least a second article to comprise at least one of a composite material, a ground strip, or a bond strap.

Assignees

• Orbital Atk Inc

Inventors

• Larson Robert S

Classifications

• C09J9/02 Primary

  Electrically-conducting adhesives · CPC title

• B32B2457/00

  Electrical equipment · CPC title

• B32B2307/304

  Insulating · CPC title

• C09J5/00

  Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers · CPC title

• H05K1/0296

  Conductive pattern lay-out details not covered by sub groups H05K1/02 - H05K1/0295 (H05K1/11 takes precedence; lay-out adapted to mounted component configuration H05K1/18) · CPC title