Method of measurement and estimation of the coefficient of thermal expansion in components

Patent metadata

Field	Value
Publication number	US-9958406-B1
Application number	US-201414559214-A
Country	US
Kind code	B1
Filing date	Dec 3, 2014
Priority date	Dec 6, 2013
Publication date	May 1, 2018
Grant date	May 1, 2018

Abstract

Methods and systems for measuring and/or estimating a coefficient of thermal expansion (CTE) of a component of a fuel cell system. A CTE measurement technique includes securing a measurement member over a surface of the component via a seal having a melting point, heating the seal above its melting point of the seal, cooling the component, measurement member and seal to a second temperature below the melting point of the seal, and determining the CTE of the component based on the change in the span of the measurement member after cooling. A fuel cell component characterization technique includes measuring an electrical resistivity (ER), conductivity (EC), resistance or conductance of the component, measuring at least one additional property of the component which, together with ER, EC, resistance or conductance, correlates to the CTE of the component, and sorting the component based on the measurements.

First claim

What is claimed is:

1. A method for measuring a coefficient of thermal expansion (CTE) of a component of a fuel cell system, comprising:
securing a measurement member over a surface of the component via a seal having a melting point, the measurement member being secured to a first portion of the seal and a second portion of the seal;
heating the component, measurement member and seal to a first temperature above the melting point of the seal;
cooling the component, measurement member and seal to a second temperature below the melting point of the seal;
measuring a length of the measurement member at the second temperature;
measuring a distance between the first portion of the seal and the second portion of the seal;
calculating the difference in temperature between the melting point of the seal and the second temperature; and
determining the CTE of the component based on the length of the measurement member after cooling, a distance between the first and second portions of the seal and the difference in temperature between the melting point of the seal and the second temperature.

2. The method of claim 1 , wherein the measurement member comprises a sheet of a material having a known CTE, wherein the known CTE is less than the CTE of the component.

3. The method of claim 1 , wherein at least one of:
(i) the component comprises an interconnect for a fuel cell stack; and
(ii) the seal comprises a glass or glass-ceramic seal.

4. The method of claim 3 , wherein the component comprises an interconnect, and the interconnect comprises 95-96 wt % chromium and 4-6 wt % iron.

5. The method of claim 1 , wherein the component and the measurement member expand independently of each other at a temperature above the melting point of the seal and contract together at a temperature below the melting point of the seal.

6. The method of claim 5 , wherein the contraction of the component and the measurement member causes the measurement member to assume a bowed profile, and the length of the measurement member comprises a line integral of the bowed profile, wherein the line integral is measured along a length of the measurement member after cooling the component, measurement member and seal.

7. The method of claim 6 , wherein the CTE of the component is determined based on the line integral of the bowed profile, the distance between the first and second portions of the seal, the known CTE of the measurement member, and a temperature differential between the melting point of the seal and the second temperature of the component, seal and measurement member after cooling using a formula:
CTE IC =CTE MM +( L−x )/( x·dT ),
where CTE IC is the CTE of the component, CTE MM is the known CTE of the measurement member, L is the line integral of the bowed profile, x is the distance between the first and second portions of the seal, and dT is the temperature differential between the melting point of the seal and the second temperature of the component, seal and measurement member.

8. An apparatus for measuring a coefficient of thermal expansion (CTE) of a component of a fuel cell system comprising a measurement member and a seal for securing the measurement member over a surface of the component, wherein the apparatus measures the CTE of the component in accordance with the method of claim 1 .

9. The method of claim 1 , further comprising determining the melting point of the seal by relative movement between the component and the measurement member.

10. The method of claim 1 , wherein the melting point of the seal is known melting point.

11. The method of claim 7 , wherein the second temperature is room temperature.

Assignees

• Bloom Energy Corp

Inventors

• Lin Cheng-Yu
• Darga Daniel
• Groesch Michael
• Herchen Harald
• Srivatsan Vijay

Classifications

• G01N25/16 Primary

  by investigating thermal coefficient of expansion · CPC title

• G01N27/026

  Dielectric impedance spectroscopy (electrochemical impedance spectroscopy for measuring corrosion G01N17/02) · CPC title