Epoxy resin composition for fiber reinforced composite material, prepreg, and fiber reinforced composite material

Patent metadata

Field	Value
Publication number	US-9957387-B2
Application number	US-201113881790-A
Country	US
Kind code	B2
Filing date	Nov 7, 2011
Priority date	Nov 8, 2010
Publication date	May 1, 2018
Grant date	May 1, 2018

Abstract

An epoxy resin composition having components (A), (B), (C), and (D), wherein the epoxy resin composition has a viscosity at 40° C. of about 1×10 3 to about 1×10 4 Pa·s, a curing start temperature of about 90 to about 110° C., and a minimum viscosity at the curing start temperature of about 2 to about 20 Pa·s, wherein the components (A), (B), (C), and (D) are as follows: (A) About 60 weight parts or more of a tetraglycidyl amine type epoxy resin per 100 weight parts of the epoxy resin blend; (B) Dicyandiamide; (C) Diaminodiphenyl sulfone and (D) Urea compound.

First claim

What is claimed is:

1. A prepreg comprising an epoxy resin composition and a reinforcing fiber,
wherein the epoxy resin composition comprising components (A), (B), (C), and (D), wherein the epoxy resin composition has a viscosity at 40° C. of about 1×10 3 to about 1×10 4 Pa·s, a curing start temperature of about 90 to about 110° C., and a minimum viscosity at the curing start temperature of about 2 to about 20 Pa·s, wherein the components (A), (B), (C), and (D) comprise:
(A) about 60 weight parts or more of a tetraglycidyl amine type epoxy resin per 100 weight parts of the epoxy resin composition, wherein an amount of tetraglycidyl amine type epoxy resin in the component (A) is between about 60 and about 95 weight parts per 100 weight parts of the epoxy resin composition; and the component (A) further comprises between about 5 and about 40 weight parts of an epoxy resin other than the tetraglycidyl amine type epoxy resin;
(B) dicyandiamide;
(C) diaminodiphenyl sulfone; and
(D) an urea compound comprising 2,4-toluene bisdimethyl urea;
wherein the epoxy resin composition has an impregnation ratio of the prepreg in a range from about 30% and less than 50%;
wherein the reinforcing fiber comprises a plurality of unidirectionally aligned fibers;
wherein a void ratio of the prepreg is less than 0.5.

2. The prepreg according to claim 1 , wherein the epoxy resin other than the tetraglycidyl amine type epoxy resin is at least one type of epoxy resin selected from the group consisting of a bisphenol type epoxy resin, a glycidyl aniline type epoxy resin, an aminophenol type epoxy resin, a novolac type epoxy resin, and combinations thereof.

3. The prepreg according to claim 1 , wherein an amount of the component (C) is between about 5 and about 30 weight parts per 100 weight parts of the epoxy resin composition.

4. The prepreg according to claim 1 , wherein an amount of the component (D) is between about 3 and about 8 weight parts per 100 weight parts of the epoxy resin composition.

5. The prepreg according to claim 1 , wherein a flexural modulus E at 25° C. of a cured resin obtained by curing the epoxy resin composition at 130° C. for 2 hours is between about 3.5 and about 4.5 GPa.

6. The prepreg according to claim 1 , wherein a glass transition temperature of a cured resin obtained by curing the epoxy resin composition at 130° C. for 2 hours after immersing the cured resin in boiling water for 24 hours is about 120° C. or higher.

7. The prepreg according to claim 1 , wherein only one side of the prepreg is covered substantially by the epoxy resin composition.

8. A fiber reinforced composite material comprising a thermally cured prepreg made by curing an uncured prepreg, wherein the uncured prepreg comprises the prepreg according to claim 1 .

9. The prepreg of claim 1 wherein the further comprises a nonwoven material, a mat, a knit or a braid.

10. The prepreg of claim 1 , further comprising a multiaxial fabric, wherein the multiaxial fabric has a window area greater than zero percent to increase a permeability of the prepreg to reduce a outgas time for the prepreg.

11. A prepreg comprising an epoxy resin composition and a reinforcing fiber-containing material,
wherein the epoxy resin composition comprising components (A), (B), (C), and (D), wherein the epoxy resin composition has a viscosity at 40° C. of about 1×10 3 to about 1×10 4 Pa·s, a curing start temperature of about 90 to about 110° C., and a minimum viscosity at the curing start temperature of about 2 to about 20 Pa·s, wherein the components (A), (B), (C), and (D) comprise:
(A) about 60 weight parts or more of a tetraglycidyl amine type epoxy resin per 100 weight parts of the epoxy resin composition, wherein an amount of tetraglycidyl amine type epoxy resin in the component (A) is between about 60 and about 95 weight parts per 100 weight parts of the epoxy resin composition; and the component (A) further comprises between about 5 and about 40 weight parts of an epoxy resin other than the tetraglycidyl amine type epoxy resin;
(B) dicyandiamide;
(C) diaminodiphenyl sulfone; and
(D) an urea compound comprising 2,4-toluene bisdimethyl urea;
wherein the epoxy resin composition has an impregnation ratio of the prepreg in a range from about 30% and less than 50%;
wherein the reinforcing fiber-containing material comprises a multiaxial fabric;
wherein a void ratio of the prepreg is less than 0.5.

12. The prepreg according to claim 1 ,
wherein the epoxy resin composition has a viscosity at 40° C. of about 2×10 3 to about 6×10 3 Pa·s.

13. The prepreg according to claim 1 ,
wherein the minimum viscosity at the curing start temperature is about 3 to about 15 Pa·s.

14. The prepreg according to claim 11 , wherein the epoxy resin composition has a viscosity at 40° C. of about 2×10 3 to about 6×10 3 Pa·s.

15. The prepreg according to claim 11 , wherein the minimum viscosity at the curing start temperature is about 3 to about 15 Pa·s.

16. The prepreg of claim 1 , wherein the void ratio of the prepreg is less than 0.3.

17. The prepreg of claim 1 , wherein the void ratio of the prepreg is about 0.1.

18. The prepreg of claim 11 , wherein the void ratio of the prepreg is less than 0.3.

19. The prepreg of claim 11 , wherein the void ratio of the prepreg is about 0.1.

Assignees

• Arai Nobuyuki
• Haro Alfred P
• Hughes Jonathan C
• Natsume Norimitsu
• Toray Industries

Inventors

• Arai Nobuyuki
• Haro Alfred P
• Hughes Jonathan C
• Natsume Norimitsu

Classifications

• C08J5/24

  Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs · CPC title

• B32B37/003

  to avoid air inclusion · CPC title

• C08G59/3227

  Compounds containing acyclic nitrogen atoms · CPC title

• Y10T442/20

  Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer · CPC title

• C08L63/04 Primary

  Epoxynovolacs · CPC title