Environmental sensor and a method for determining relative vapour pressure

Patent metadata

Field	Value
Publication number	US-9945765-B2
Application number	US-201414905384-A
Country	US
Kind code	B2
Filing date	Jun 25, 2014
Priority date	Jul 16, 2013
Publication date	Apr 17, 2018
Grant date	Apr 17, 2018

Abstract

An apparatus for use in determining the relative vapor pressure of a fluid in an environment in which the apparatus is located, the apparatus comprising a first layer ( 512 ) configured to enable a flow of charge carriers from a source electrode ( 505 ) to a drain electrode ( 506 ), a second layer ( 513 ) configured to control the conductance of the first layer ( 512 ) using an electric field formed between the first ( 512 ) and second layers ( 513 ) and a third layer ( 514 ) positioned between the first and second layers to prevent a flow of charge carriers therebetween to enable formation of the electric field, wherein the second layer ( 513 ) is configured to exhibit a charge distribution on interaction with the fluid, the charge distribution giving rise to the electric field between the first ( 512 ) and second ( 513 ) layers, and wherein the second layer ( 513 ) is configured such that the charge distribution and electric field strength are dependent upon the relative vapor pressure of the fluid in the environment ( 516 ), thereby allowing the relative vapor pressure to be derived from a measurement of the conductance of the first layer ( 512 ).

First claim

The invention claimed is:

1. An apparatus for determining a relative vapour pressure of a fluid in an environment in which the apparatus is located, the apparatus comprising:
a source electrode formed on a first layer;
a drain electrode formed on the first layer;
the first layer, patterned to form a channel between the source and drain electrode, and configured to enable a flow of charge carriers from the source electrode to the drain electrode;
a second layer configured as a gate electrode, open to at least the fluid in the environment, and comprising one or more materials having one or more functional groups configured to release charged particles on interaction with the fluid to produce a charge distribution, wherein the charge distribution gives rise to an electric field between the first and second layers; and
a third layer positioned between the first and second layers and configured to prevent a flow of charge carriers therebetween to enable formation of the electric field, the third layer covering exposed surfaces of the channel of the first layer and the source and drain electrodes;
wherein the second layer is configured such that the charge distribution and electric field strength are dependent upon the relative vapour pressure of the fluid in the environment, thereby allowing the relative vapour pressure to be derived from a measurement of the conductance of the first layer.

2. The apparatus of claim 1 , wherein the first layer comprises graphene.

3. The apparatus of claim 1 , wherein the one or more materials of the second layer comprise graphene oxide.

4. The apparatus of claim 1 , wherein the one or more materials of the second layer comprise a first material having one or more functional groups configured to release charged particles on interaction with the fluid to produce the charge distribution.

5. The apparatus of claim 4 , wherein the one or more materials of the second layer comprise a second material also having one or more functional groups configured to release charged particles on interaction with the fluid to produce the charge distribution, wherein the second material is different from the first material.

6. The apparatus of claim 5 , wherein the first material contacts the second material, wherein the first material and the second material have a junction at their contact, and wherein the first material has a higher concentration of charge-releasing functional groups than the second material such that a concentration gradient of charged particles is produced at the junction on exposure of the second layer to the fluid.

7. The apparatus of claim 4 , wherein the charged particles are protons.

8. The apparatus of claim 4 , wherein the charge-releasing functional groups comprise one or more of a carboxyl, hydroxyl and epoxy group.

9. The apparatus of claim 4 , wherein the first material comprises graphene oxide.

10. The apparatus of claim 9 , wherein the graphene oxide comprises a plurality of fully or partially oxidised graphene flakes.

11. The apparatus of claim 9 , wherein the third layer comprises one or more of boron nitride, aluminium oxide, hafnium oxide, silicon dioxide and parylene.

12. The apparatus of claim 9 , wherein one or more of the first, second and third layers have a thickness of one atomic layer.

13. The apparatus of claim 9 , wherein the apparatus comprises a protective layer over exposed surfaces of at least the second layer, and wherein the protective layer comprises a fluid-permeable material to enable the second layer to be open to the fluid.

14. The apparatus of claim 9 , wherein the apparatus comprises a back electrode configured to influence the charge distribution within the second layer.

15. The apparatus of claim 9 , wherein the fluid comprises water, and wherein the relative vapour pressure of the fluid provides an indication of the relative humidity of the environment.

16. The apparatus of claim 9 , wherein the apparatus is one or more of an electronic device, a portable electronic device, a portable telecommunications device, a sensor and a module for any of the aforementioned devices.

17. The apparatus of claim 1 , wherein the third layer comprises one or more dielectric materials.

18. The apparatus of claim 17 , wherein the first layer comprises graphene and the second layer comprises graphene oxide.

19. A method of using an apparatus in determining the relative vapour pressure of a fluid in an environment in which the apparatus is located, the method comprising:
causing in a sensor of the apparatus a potential difference between a source electrode and a drain electrode in a first layer of the sensor, wherein the first layer is patterned to form a channel between the source and drain electrode and enable a flow of charge carriers at a first layer from the source electrode to the drain electrode in response to the potential difference;
wherein the sensor comprises a second layer configured as a gate electrode, open to at least the fluid in the environment, and comprising one or more materials having one or more functional groups configured to release charged particles on interaction with the fluid to produce a charge distribution, wherein the charge distribution gives rise to an electric field between the first and second layers;
wherein the sensor comprises a third layer positioned between the first and second layers and preventing a flow of prevent a flow of charge carriers between the first and second layers to enable formation of the electric field, the third layer covering exposed surfaces of the channel of the first layer and the source and drain electrodes;
wherein the second layer is configured such that the charge distribution and electric field strength are dependent upon the relative vapour pressure of the fluid in the environment, thereby allowing the relative vapour pressure to be derived from a measurement of a conductance of the first layer;
causing the conductance of the first layer to be measured by the apparatus; and
causing the apparatus to derive the relative vapour pressure of the fluid in the environment from the measured conductance of the first layer.

20. A computer program comprising a non-transitory computer-readable medium containing computer code, the computer code configured to cause an apparatus to perform a method comprising:
causing in a sensor of the apparatus a potential difference between a source electrode and a drain electrode in a first layer of the sensor, wherein the first layer is patterned to form a channel between the source and drain electrode and enables a flow of charge carriers at a first layer from the source electrode to the drain electrode in response to the potential difference;
wherein the sensor comprises a second layer configured as a gate electrode, open to at least the fluid in the environment, and comprising one or more materials having one or more functional groups configured to release charged particles on interaction with the fluid to produce a charge distribution, wherein the charge distribution gives rise to an electric field between the first and second layers;
wherein the sensor comprises a third layer positioned between the first and second layers and preventing a flow of prevent a flow of charge carriers between the first and second layers to enable formation of the electric field, the third layer covering exposed surfaces of the channel of the first layer and the source and drain electrodes;
wherein the second layer is configured such that the charge distribution and electric field strengt

Assignees

• Provenance Asset Group Llc

Inventors

• White Richard
• Borini Stefano

Classifications

• G01N27/02 Primary

  by investigating impedance · CPC title

• G01N7/14 Primary

  by allowing the material to emit a gas or vapour, e.g. water vapour, and measuring a pressure or volume difference {(determining urea G01N33/48742)} · CPC title

• G01N27/048

  for determining moisture content of the material · CPC title

• G01N27/4141 Primary

  specially adapted for gases · CPC title

• G01L19/00

  Details of, or accessories for, apparatus for measuring steady or quasi-steady pressure of a fluent medium insofar as such details or accessories are not special to particular types of pressure gauges · CPC title