Method for recovering an acid from acid/sugar solutions

Patent metadata

Field	Value
Publication number	US-9945000-B2
Application number	US-201615133529-A
Country	US
Kind code	B2
Filing date	Apr 20, 2016
Priority date	Apr 21, 2015
Publication date	Apr 17, 2018
Grant date	Apr 17, 2018

Abstract

Acid hydrolysis of biomass is an important step for releasing the component sugars before converting them to fuels and/or biochemicals. During such a process, a significant amount of mineral acid, such as sulfuric acid, is used. In most cases, the residual acid is neutralized with lime before the sugar conversion step. By doing so, a waste calcium sulphate stream is generated and sent to disposal. The efficient separation of acid from the sugars would allow the recycle of the acid and make the entire process more economically viable. We found that a resin bed packed with an acid retardation resin can be used to achieve an efficient separation (i.e. 98.5% recovery of the acid) of the sulfuric acid from the sugars. The resin bed can be simply regenerated with water.

First claim

The invention claimed is:

1. A method for treating a biomass hydrolysate solution containing an acid and non-ionic organic compound, the method comprising:
feeding the hydrolysate solution to a fixed-resin bed of an acid retardation unit, the acid retardation unit comprising a base and a top opposite the base, and the fixed-resin incorporating a particulate quaternary ammonium resin retaining the acid and rejecting the non-ionic organic compound; and
eluting the acid retained in the fixed-resin with water to recover a purified acid,
wherein more than 90% by weight of the acid in the biomass hydrolysate solution is recovered.

2. The method of claim 1 wherein more than 75% by weight of the non-ionic organic compound in the biomass hydrolysate is recovered.

3. The method of claim 1 wherein the hydrolysate is fed into a base of the acid retardation unit up through the fixed-resin bed.

4. The method claim 1 wherein the water eluting the acid is into the top of the acid retardation unit down through the fixed-resin bed.

5. The method of claim 1 wherein the acid is at least one of sulfuric acid, phosphoric acid, nitric acid, hydrochloric acid, formic acid, lactic acid and succinic acid.

6. The method of claim 5 wherein the acid is sulfuric acid from 1 to 98% H2SO4.

7. The method of claim 1 wherein the non-ionic organic compound is at least one of a soluble sugar and soluble alcohol.

8. The method of claim 1 wherein the non-ionic organic compound is a sugar.

9. The method of claim 1 wherein the particulate quaternary ammonium resin is under compression within the fixed-resin bed.

10. The method of claim 1 , wherein the particulate quaternary ammonium resin has a constant average particle size of 50 μm.

11. The method of claim 1 , wherein the feeding of the hydrolysate has a duration of 2 to 5 minutes.

12. The method of claim 1 , wherein the eluting the acid has a duration of 2 to 5 minutes.

Assignees

• Fpinnovations

Inventors

• Jemaa Naceur
• Paleologou Michael
• Mahmood Talat

Classifications

• C13B20/146 Primary

  using only anionic ion-exchange material (C13B20/148 takes precedence) · CPC title

• C01B17/905

  Removal of organic impurities · CPC title

• C13K13/002

  Xylose · CPC title

• B01J41/13

  obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds · CPC title

• C13K1/02

  obtained by saccharification of cellulosic materials (manufacture of fodder A23K10/32) · CPC title