Separation and recovery of xylose using weakly basic anion exchange resins

Patent metadata

Field	Value
Publication number	US-9777342-B2
Application number	US-201314428490-A
Country	US
Kind code	B2
Filing date	Sep 19, 2013
Priority date	Sep 20, 2012
Publication date	Oct 3, 2017
Grant date	Oct 3, 2017

Abstract

The invention relates to a method of separating and recovering xylose from a xylose-containing plant-based solution. The method is performed in a chromatographic separation system, which comprises one or more weak base anion exchange resins and optionally one or more other resins selected from strong acid cation exchange resins and weak acid cation exchange resins, by passing the solution through the separation system, followed by recovering at least one fraction enriched in xylose. Optionally, a rhamnose fraction may also be recovered.

First claim

The invention claimed is:

1. A method of separating and recovering xylose from a xylose containing plant-based solution, comprising:
performing the separation in a chromatographic separation system, which comprises one or more weak base anion exchange resins or a combination thereof and optionally one or more other resins selected from strong acid cation exchange resins and weak acid cation exchange resins, by passing the solution through the separation system; and
recovering at least one fraction enriched in xylose wherein the recovered xylose fraction has a xylose purity of more than 45% on dissolved dry solids based on weight %.

2. The method according to claim 1 , wherein if the chromatographic separation system comprises one or more weak base anion exchange resins in combination with one or more weak acid cation exchange resins, the method further comprises recovering a fraction enriched in rhamnose.

3. The method according to claim 2 , wherein the yield of the fraction enriched in rhamnose recovered is at least 15%.

4. The method according to claim 1 , wherein the separation comprises first a separation with said one or more strong acid cation exchange resins and then a separation with said one or more weak base anion exchange resins.

5. The method according to claim 1 , wherein the separation comprises first a separation with said one or more weak acid cation exchange resins and then a separation with said one or more weak base anion exchange resins.

6. The method according to claim 1 , wherein said one or more weak base anion exchange resins and each of said other resins are arranged in one or more separate columns with one or more compartments.

7. The method according to claim 1 , wherein the strong acid cation exchange resin is in a multivalent, divalent, or monovalent cation form.

8. The method according to claim 1 , wherein the weak base anion exchange resin is based on a resin selected from the group consisting of acrylic resins, polystyrene resins, epichlorohydrin based anion exchange resins, aminated products of phenol or formaldehyde resins, aliphatic amines, and ammonia polycondensation resins.

9. The method according to claim 8 , wherein the weak base anion exchange resin is a resin with an acrylic matrix.

10. The method according to claim 9 , wherein the weak acid cation exchange resin is in a H+, Na+, K+, Ca2+, Mg2+, or combination thereof form.

11. The method according to claim 1 , wherein the resins are crosslinked with an aromatic crosslinker.

12. The method according to claim 1 , wherein the eluent for the chromatographic separation is selected from water, an aqueous solution, an alcohol, an evaporation condensate, an evaporation condensate containing acetic acid, or mixtures thereof.

13. The method according to claim 12 , wherein a portion of the eluent is replaced by one or more fractions collected from the chromatographic separation.

14. The method according to claim 1 , wherein the separation is performed at a temperature of 20° C. to 95° C.

15. The method as claimed in claim 1 , wherein the separation is performed by a method selected from a sequential simulated moving bed method, continuous simulated moving bed method, a batch method or combinations thereof.

16. The method as claimed in claim 1 , wherein the separation system comprises one or more loops and different resins are arranged in the same loop or in different loops.

17. The method as claimed in claim 16 , wherein the separation system comprises one or more separation profiles in a loop.

18. The method as claimed in claim 1 , wherein the method provides a xylose yield of more than 80%.

19. The method as claimed in claim 1 , wherein the xylose-containing plant-based solution used as the feed is selected from plant-based hydrolysates, plant-based extracts, or derivatives thereof.

20. The method as claimed in claim 19 , wherein the plant-based hydrolysate is a spent liquor obtained from a pulping process, hardwood pulping, or sulphite pulping.

21. The method as claimed in claim 19 , wherein the xylose-containing plant-based solution used as the feed is a mother liquor obtained from the crystallization of xylose.

22. The method according to claim 7 , wherein the strong acid cation exchange resin is in a divalent cation form, wherein said form is a Mg2+ or Ca2+ form.

23. The method according to claim 10 , wherein the weak acid cation exchange resin is a resin with an acrylic matrix in a H+/Mg2+ form.

24. The method according to claim 13 , wherein a portion of the eluent is replaced by one or more residual fractions collected from the chromatographic separation.

25. The method according to claim 14 , wherein the separation is performed at a temperature of 60° to 80° C.

Assignees

• Dupont Nutrition Biosci Aps

Inventors

• Lewandowski Jari
• Nurmi Nina
• Mattila Jari
• Laiho Kari
• Kekalainen Kati

Classifications

• B01D15/185

  characterised by the components to be separated · CPC title

• B01D15/362

  Cation-exchange · CPC title

• B01J39/26

  Cation exchangers for chromatographic processes · CPC title

• B01J47/10

  with moving ion-exchange material; with ion-exchange material in suspension or in fluidised-bed form · CPC title

• B01J41/14

  obtained by reactions only involving unsaturated carbon-to-carbon bonds · CPC title