Resin composition, prepreg and laminate

Patent metadata

Field	Value
Publication number	US-9944787-B2
Application number	US-201314388516-A
Country	US
Kind code	B2
Filing date	Mar 25, 2013
Priority date	Mar 30, 2012
Publication date	Apr 17, 2018
Grant date	Apr 17, 2018

Abstract

The present invention provides a resin composition which can simply provide, with good reproducibility, a laminate, a printed wiring board, and the like that not only have excellent heat dissipation properties but have good moldability, good mechanical drillability and excellent appearance, and a prepreg, a metal foil-clad laminate, and the like using the same. A resin composition having a cyanate ester compound (A), an epoxy resin (B), a first inorganic filler (C), a second inorganic filler (D), and a molybdenum compound (E), wherein an average particle diameter ratio of the first inorganic filler (C) to the second inorganic filler (D) is in a range of 1:0.02 to 1:0.2.

First claim

The invention claimed is:

1. A resin composition comprising a cyanate ester compound (A), an epoxy resin (B), a first inorganic filler (C), a second inorganic filler (D), and a molybdenum compound (E), wherein an average particle diameter ratio of the first inorganic filler (C) to the second inorganic filler (D) is in a range of 1:0.02 to 1:0.2, and wherein the molybdenum compound (E) forms a core particle, and an inorganic oxide is formed on at least part of a surface of the core particle.

2. The resin composition according to claim 1 , wherein a mass ratio of the first inorganic filler (C) to the second inorganic filler (D) is in a range of 1:0.03 to 1:0.5.

3. The resin composition according to claim 1 , wherein the first inorganic filler (C) and the second inorganic filler (D) are comprised in an amount of 200 to 800 parts by mass in total based on 100 parts by mass of a total of the cyanate ester compound (A) and the epoxy resin (B).

4. The resin composition according to claim 1 , wherein the molybdenum compound (E) is comprised in an amount of 0.1 to 20 parts by mass based on 100 parts by mass of the total of the cyanate ester compound (A) and the epoxy resin (B).

5. The resin composition according to claim 1 , wherein the first inorganic filler (C) is magnesium oxide and/or boehmite.

6. The resin composition according to claim 1 , wherein the first inorganic filler (C) has an average particle diameter of 0.5 to 10 μm.

7. The resin composition according to claim 1 , wherein the second inorganic filler (D) is at least one selected from the group consisting of alumina, magnesium oxide, boron nitride, and aluminum nitride.

8. The resin composition according to claim 1 , wherein the second inorganic filler (D) is spherical.

9. The resin composition according to claim 1 , wherein the first inorganic filler (C), the second inorganic filler (D), and the molybdenum compound (E) are comprised in an amount of 40 to 70% by volume in total based on a total volume of the resin composition.

10. The resin composition according to claim 1 , wherein the cyanate ester compound (A) is at least one selected from the group consisting of a naphthol aralkyl-based cyanate ester compound, a novolac-based cyanate ester compound, and a biphenyl aralkyl-based cyanate ester compound.

11. The resin composition according to claim 10 , wherein the naphthol aralkyl-based cyanate ester compound is represented by the following general formula (1), the novolac-based cyanate ester compound is represented by the following general formula (2), and the biphenyl aralkyl-based cyanate ester compound is represented by the following general formula (3):

wherein R each independently represents a hydrogen atom or a methyl group, and n represents an integer of 1 to 50;

wherein R each independently represents a hydrogen atom or a methyl group, and n represents an integer of 1 to 50;

wherein R each independently represents a hydrogen atom or a methyl group, R 1 each independently represents a hydrogen atom, an alkyl group having 2 or less carbon atoms, or an aryl group, and n represents an integer of 1 to 50.

12. The resin composition according to claim 1 , wherein the cyanate ester compound (A) is comprised in an amount of 10 to 90 parts by mass based on 100 parts by mass of the total of the cyanate ester compound (A) and the epoxy resin (B).

13. The resin composition according to claim 1 , wherein the epoxy resin (B) is at least one selected from the group consisting of a biphenyl aralkyl-based epoxy resin, a polyoxynaphthylene-based epoxy resin, a triphenolmethane-based epoxy resin, a bisphenol A-based epoxy resin, a bisphenol F-based epoxy resin, a phenol novolac-based epoxy resin, a cresol novolac-based epoxy resin, a bisphenol A novolac-based epoxy resin, a brominated bisphenol A-based epoxy resin, a brominated phenol novolac-based epoxy resin, a biphenyl-based epoxy resin, a phenol aralkyl-based epoxy resin, and a naphthol aralkyl-based epoxy resin.

14. The resin composition according to claim 1 , further comprising a silane coupling agent (F).

15. The resin composition according to claim 14 , wherein the silane coupling agent (F) is comprised in an amount of 3 to 30 parts by mass based on 100 parts by mass of the total of the cyanate ester compound (A) and the epoxy resin (B).

16. The resin composition according to claim 1 , further comprising a maleimide compound (G).

17. The resin composition according to claim 16 , wherein the maleimide compound (G) is comprised in an amount of 5 to 75 parts by mass based on 100 parts by mass of a total of the cyanate ester compound (A), the epoxy resin (B), and the maleimide compound (G).

18. The resin composition according to claim 16 , wherein the maleimide compound (G) is at least one selected from the group consisting of bis(4-maleimidephenyl)methane, 2,2-bis(4-(4-maleimidephenoxy)-phenyl)propane, and bis(3-ethyl-5-methyl-4-maleimidephenyl)methane.

19. A prepreg obtained by impregnating or coating a substrate with the resin composition according to claim 1 .

20. A laminate obtained by curing the prepreg according to claim 19 .

21. A metal foil-clad laminate obtained by laminating and curing the prepreg according to claim 19 and metal foil.

22. A printed wiring board comprising an insulating layer and a conductor layer formed on a surface of the insulating layer, wherein
the insulating layer comprises the resin composition according to claim 1 .

Assignees

• Mitsubishi Gas Chemical Co

Inventors

• Saito Chisato
• Ueyama Daisuke
• Sogame Masanobu
• Mabuchi Yoshinori
• Kato Yoshihiro

Classifications

• C08K3/22

  of metals · CPC title

• Y10T428/24893

  including particulate material · CPC title

• B32B2305/076

  Prepregs · CPC title

• B32B15/08

  of synthetic resin · CPC title

• C08L79/04

  Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors · CPC title