Catalyst system for polymerization of an olefin

Patent metadata

Field	Value
Publication number	US-9944731-B2
Application number	US-201415105291-A
Country	US
Kind code	B2
Filing date	Dec 19, 2014
Priority date	Dec 20, 2013
Publication date	Apr 17, 2018
Grant date	Apr 17, 2018

Abstract

A process for the preparation of a procatalyst suitable for preparing a catalyst composition for olefin polymerization, the procatalyst obtained or obtainable by the process; and a catalyst composition for olefin polymerization comprising the procatalyst. In particular a benzamide can be used as an activator in the preparation of a supported Ziegler-Natta type procatalyst useful for a process for the preparation of polyolefins. The Polyolefins and polypropylene homopolymers are also disclosed.

First claim

The invention claimed is:

1. A process for the preparation of a procatalyst for preparing a catalyst composition for olefin polymerization, said process comprising:
providing a magnesium-based support, contacting said magnesium-based support with a Ziegler-Natta type catalytic species, an internal donor, and an activator, to yield a procatalyst, wherein the activator is a benzamide according to formula X:

wherein R 70 and R 71 are each independently selected from hydrogen or an alkyl, and R 72 , R 73 , R 74 , R 75 , and R 76 are each independently selected from hydrogen, a heteroatom or a hydrocarbyl group; and wherein the internal donor is selected from the group consisting of 1,3-diethers represented by the Formula VII,

wherein R 51 and R 52 are each independently selected from a hydrogen or a hydrocarbyl group selected from alkyl, alkenyl, aryl, aralkyl, alkoxycarbonyl or alkylaryl groups, and one or more combinations thereof and wherein R 53 and R 54 are each independently selected from a hydrocarbyl group.

2. The process according to claim 1 , comprising:
A) providing said procatalyst obtained via a process comprising:
i) contacting a compound R z 4 MgX 2-z 4 with an alkoxy- or aryloxy-containing silane compound to give a first intermediate reaction product, being a solid Mg(OR 1 ) x X 2-x 1 , wherein: R 4 is the same as R 1 being a linear, branched or cyclic hydrocarbyl group independently selected from alkyl, alkenyl, aryl, aralkyl or alkylaryl groups, and one or more combinations thereof; wherein said hydrocarbyl group is substituted or unsubstituted, optionally comprises one or more heteroatoms and has from 1 to 20 carbon atoms; X 4 and X 1 are each independently selected from fluoride (F − ), chloride (Cl − ), bromide (Br − ) or iodide (I − ); z is in a range of larger than 0 and smaller than 2, being 0<z<2;
ii) contacting the solid Mg(OR 1 ) x X 1 2-x obtained in step i) with at least one activating compound of formula M 1 (OR 2 ) v-w (OR 3 )w or M 2 (OR 2 ) v-w (R 3 ) w , to obtain a second intermediate product; wherein: M 1 is a metal selected from Ti, Zr, Hf, Al or Si; M 2 is a metal being Si; v is the valency of M 1 or M 2 ; R 2 and R 3 are each a linear, branched or cyclic hydrocarbyl group independently selected from alkyl, alkenyl, aryl, aralkyl or alkylaryl groups, and one or more combinations thereof; wherein said hydrocarbyl group is substituted or unsubstituted, optionally comprises one or more heteroatoms, and has from 1 to 20 carbon atoms; and
iii) contacting the first or second intermediate reaction product, obtained respectively in step i) or ii), with a halogen-containing Ti-compound, an activator according to Formula X and an internal electron donor according to Formula VII to obtain said procatalyst.

3. The process according to claim 1 , wherein the hydrocarbyl groups R 53 and R 54 each have from 1 to 10 carbon atoms.

4. The process according to claim 1 , wherein the internal donor is selected from the group consisting of 1,3-dimethoxypropane, 1,3-diethoxypropane, 1,3-dibutoxypropane, 1-methoxy-3-ethoxypropane, 1-methoxy-3-butoxypropane, 1-methoxy-3-cyclohexoxypropane, 2,2-dimethyl-1,3-dimethoxypropane, 2,2-diethyl-1,3-dimethoxypropane, 2,2-di-n-butyl-1,3-dimethoxypropane, 2,2-diisobutyl-1,3-dimethoxypropane, 2-ethyl-2-n-butyl-1,3-dimethoxypropane, 2-n-propyl-2-cyclopentyl-1,3-dimethoxypropane, 2,2-dimethyl-1,3-diethoxypropane, 2-n-propyl-2-cyclohexyl-1,3-diethoxypropane, 2-(2-ethylhexyl)-1,3-dimethoxypropane, 2-isopropyl-1,3-dimethoxypropane, 2-n-butyl-1,3-dimethoxypropane, 2-sec-butyl-1,3-dimethoxypropane, 2-cyclohexyl-1,3-dimethoxypropane, 2-phenyl-1,3-diethoxypropane, 2-cumyl-1,3-diethoxypropane, 2-(2-phenyllethyl)-1,3-dimethoxypropane, 2-(2-cyclohexylethyl)-1,3-dimethoxypropane, 2-(p-chlorophenyl)-1,3-dimethoxypropane, 2-(diphenylmethyl)-1,3-dimethoxypropane, 2-(1-naphthyl)-1,3-dimethoxypropane, 2-(fluorophenyl)-1,3-dimethoxypropane, 2-(1-decahydronaphthyl)-1,3-dimethoxypropane, 2-(p-t-butylphenyl)-1,3-dimethoxypropane, 2,2-dicyclohexyl-1,3-dimethoxypropane, 2,2-di-npropyl-1,3-dimethoxypropane, 2-methyl-2-n-propyl-1,3-dimethoxypropane, 2-methyl-2-benzyl-1,3-dimethoxypropane, 2-methyl-2-ethyl-1,3-dimethoxypropane, 2-methyl-2-phenyl-1,3-dimethoxypropane, 2-methyl-2-cyclohexyl-1,3-dimethoxypropane, 2,2-bis(pchlorophenyl)-1,3-dimethoxypropane, 2,2-bis(2-cyclohexylethyl)-1,3-dimethoxypropane, 2-methyl-2-isobutyl-1,3-dimethoxypropane, 2-methyl-2-(2-ethylhexyl)-1,3-dimethoxy propane, 2-methyl-2-isopropyl-1,3-dimethoxypropane, 2,2-diphenyl-1,3-dimethoxypropane, 2,2-dibenzyl-1,3-dimethoxypropane, 2,2-bis(cyclohexylmethyl)-1,3-dimethoxypropane, 2,2-diisobutyl-1,3-diethoxypropane, 2,2-diisobutyl-1,3-di-n-butoxypropane, 2-isobutyl-2-isopropyl-1,3-dimethoxypropane, 2,2-di-sec-butyl-1,3-dimethoxypropane, 2,2-di-t-butyl-1,3-dimethoxypropane, 2,2-dineopentyl-1,3-dimethoxypropane, 2-isopropyl-2-isopentyl-1,3-dimethoxypropane, 2-phenyl-2-benzyl-1,3-dimethoxypropane, 2-cyclohexyl-2-cyclohexylmethyl-1,3-dimethoxypropane, 2-isopropyl-2-(3,7-dimethyloctyl) 1,3-dimethoxypropane, 2,2-diisopropyl-1,3-dimethoxypropane, 2-isopropyl-2-cyclohexylmethyl-1,3-dimethoxypropane, 2,2-diisopentyl-1,3-dimethoxypropane, 2-isopropyl-2-cyclohexyl-1,3-dimethoxypropane, 2-isopropyl-2-cyclopentyl-1,3-dimethoxypropane, 2,2-dicylopentyl-1,3-dimethoxypropane, 2-n-heptyl-2-n-pentyl-1,3-dimethoxypropane, 9,9-bis(methoxymethyl)fluorene, 1,3-dicyclohexyl-2,2-bis(methoxymethyl)propane, 3,3-bis(methoxymethyl)-2,5-dimethylhexane, or any combination of the foregoing, for example wherein the internal donor is selected from the group of 1,3-dicyclohexyl-2,2-bis(methoxymethyl)propane, 3,3-bis(methoxymethyl)-2,5-dimethylhexane, 2,2-dicyclopentyl-1,3-dimethoxypropane and any combinations thereof.

5. The process according to claim 1 , wherein the internal donor is 9,9-bis(methoxymethyl)fluorene.

6. The process according to claim 1 , wherein in the activator according to Formula X, at least one of R 70 and R 71 is an alkyl group, wherein the alkyl has from 1 to 6 carbon atoms.

7. The process according to claim 1 , wherein the activator is N,N-dimethylbenzamide.

8. The process according to claim 1 , wherein the benzamide is present in the procatalyst, in an amount of from 0.1 to 4 wt. % as measured using HPLC.

9. A procatalyst obtained by the process according to claim 1 .

10. A catalyst composition for olefin polymerization comprising a procatalyst comprising
a benzamide according to formula X,

wherein R 70 and R 71 are each independently selected from hydrogen or an alkyl, and R 72 , R 73 , R 74 , R 75 , and R 76 are each independently selected from hydrogen, a heteroatom or a hydrocarbyl group, and wherein the benzamide according to formula X is present in an amount of from 0.1 to 3.5 wt. %, based on the procatalyst as measured using HPLC; and further comprising
an internal donor selected from 1,3-diethers represented by Formula VII

wherein R 51 and R 52 are each independently selected from a hydrogen or a hydrocarbyl group selected from alkyl, alkenyl, aryl, aralkyl, alkoxycarbonyl or alkylaryl groups, and one or more combinations thereof and wherein R 53 and R 54 are each independently selected from a hydrocarbyl group.

11. The catalyst composition of claim 1

Assignees

• Saudi Basic Ind Corp
• Sabic Global Technologies Bv
• Zuideveld Martin Alexander
• Batinas Geurts Aurora Alexandra
• Bukatov Gennadii Dimitrievich
• Sergeev Sergei Andreevich
• Zakharov Vladimir Aleksandrovich

Inventors

• Zuideveld Martin Alexander
• Batinas-Geurts Aurora Alexandra
• Bukatov Gennadii Dimitrievich
• Sergeev Sergei Andreevich
• Zakharov Vladimir Aleksandrovich

Classifications

• C08F4/6557

  and metals of C08F4/64 or compounds thereof · CPC title

• C08F2500/12

  Melt flow index or melt flow ratio · CPC title

• C08F2/38 Primary

  Polymerisation using regulators, e.g. chain terminating agents {, e.g. telomerisation} · CPC title

• C08F4/651

  Pretreating with non-metals or metal-free compounds · CPC title

• C08F110/06 Primary

  Propene · CPC title