Catalyst composition for polymerization of olefins

Patent metadata

Field	Value
Publication number	US-9688790-B2
Application number	US-201314410248-A
Country	US
Kind code	B2
Filing date	Jun 24, 2013
Priority date	Jun 29, 2012
Publication date	Jun 27, 2017
Grant date	Jun 27, 2017

Abstract

The present invention relates to a catalyst composition comprising the compound represented by the Fischer projection of formula (I) as an internal electron donor, (I) wherein: R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are the same or different and are independently selected from a group consisting of hydrogen, straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R 7 is selected from a group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; and R 8 is selected from a group consisting of aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; N is nitrogen atom; O is oxygen atom; and C is carbon atom. The present invention also relates to a process for preparing said polymerization catalyst composition and to a polymerization catalyst system comprising said catalyst composition, a cocatalyst and optionally an external electron donor. Furthermore, the present invention relates to a polyolefin obtainable by the process according to the present invention and to the use of the compound of formula (I) as in internal electron donor in catalysts for polymerization of olefins.

First claim

The invention claimed is:

1. A catalyst composition for polymerization of olefins, which comprises the compound represented by the Fischer projection of formula (I) as an internal electron donor,

wherein:
R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are the same or different and are independently selected from the group consisting of hydrogen and straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl groups having 1 to 20 carbon atoms;
R 7 is selected from the group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl groups having 1 to 20 carbon atoms; and
R 8 is selected from the group consisting of aromatic substituted and unsubstituted hydrocarbyl groups having 6 to 20 carbon atoms; and
N is nitrogen atom; O is oxygen atom; and C is carbon atom.

2. The catalyst according to claim 1 , wherein R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are independently selected from the group consisting of hydrogen; C 1 -C 10 straight and branched alkyl groups; C 3 -C 10 cycloalkyl groups; C 6 -C 10 aryl groups; and C 7 -C 10 alkaryl and aralkyl groups.

3. The catalyst according to claim 2 , wherein R 1 and R 2 is each a hydrogen atom and R 3 , R 4 , R 5 and R 6 are independently selected from the group consisting of C 1 -C 10 straight and branched alkyl groups; C 3 -C 10 cycloalkyl groups; C 6 -C 10 aryl groups; and C 7 -C 10 alkaryl and aralkyl groups.

4. The catalyst according to claim 2 , wherein when one of R 3 and R 4 and one of R 5 and R 6 has at least one carbon atom, then the other one of R 3 and R 4 and of R 5 and R 6 are each a hydrogen atom.

5. The catalyst according to claim 1 , wherein R 7 is selected from the group consisting of methyl, ethyl, propyl, isopropyl, butyl, tert-butyl, phenyl, benzyl, substituted benzyl and halophenyl groups.

6. The catalyst according to claim 1 , wherein R 8 is selected from the group consisting of C 6 -C 10 aryl groups; and C 7 -C 10 alkaryl and aralkyl groups.

7. The catalyst composition according to claim 1 , wherein the internal electron donor is selected from the group consisting of 4-[benzoyl(methyl)amino]pentan-2-yl benzoate; 2,2,6,6-tetramethyl-5-(methylamino)heptan-3-ol dibenzoate; 4-[benzoyl (ethyl)amino]pentan-2-yl benzoate; and 4-(methylamino)pentan-2-yl bis (4-methoxy)benzoate).

8. A process for preparing the catalyst composition according to claim 1 , comprising contacting a magnesium-containing support with a halogen-containing titanium compound and an internal electron donor, wherein the internal electron donor is represented by the Fischer projection of formula (I),

wherein:
R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are the same or different and are independently selected from the group consisting of hydrogen and straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl groups having 1 to 20 carbon atoms;
R 7 is selected from the group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl groups having 1 to 20 carbon atoms; and
R 8 is selected from the group consisting of aromatic substituted and unsubstituted hydrocarbyl groups having 6 to 20 carbon atoms;
N is nitrogen atom; O is oxygen atom; and C is carbon atom.

9. The process according to claim 8 , which comprises the steps of:
i) contacting a compound of the formula R 9 z MgX 2-z wherein R 9 is selected from the group consisting of aromatic, aliphatic, and cyclo-aliphatic hydrocarbyl groups containing 1 to 20 carbon atoms, X is a halide, and z is in a range of larger than 0 and smaller than 2, with an alkoxy- or aryloxy-containing silane compound to give a first intermediate reaction product;
ii) contacting the first intermediate reaction product with at least one activating compound selected from the group consisting of electron donors, compounds of the formula M(OR 10 ) v-w OR 11 w wherein M is Ti, Zr, Hf or Al, and compounds of the formula M(OR 10 ) v-w (R 11 ) w wherein M is Si, wherein each R 10 and R 11 , independently, are selected from the group consisting of alkyl groups, alkenyl groups, and aryl groups, v is the valency of M, and w is smaller than v, to give a second intermediate reaction product; and
iii) contacting the second intermediate reaction product with a halogen-containing Ti-compound and an internal electron donor represented by the Fischer projection in formula (I),

wherein:
R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are the same or different and are independently selected from the group consisting of hydrogen and straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl groups having 1 to 20 carbon atoms;
R 7 is selected from the group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl groups having 1 to 20 carbon atoms; and
R 8 is selected from the group consisting of aromatic substituted and unsubstituted hydrocarbyl groups having 6 to 20 carbon atoms;
N is nitrogen atom; O is oxygen atom; and C is carbon atom.

10. The process according to claim 9 , wherein the first intermediate reaction product is contacted with an alcohol electron donor and a titanium tetraalkoxide in step ii).

11. A polymerization catalyst system comprising the catalyst composition according to claim 1 , a co-catalyst, and optionally an external electron donor.

12. A process of making a polyolefin, comprising contacting an olefin with the catalyst system according to claim 11 .

13. The catalyst according to claim 1 , wherein
R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are independently selected from the group consisting of hydrogen; C 1 -C 10 straight and branched alkyl groups; C 3 -C 10 cycloalkyl groups; C 6 -C 10 aryl groups; and C 7 -C 10 alkaryl and aralkyl groups, wherein when one of R 3 and R 4 and one of R 5 and R 6 has at least one carbon atom, then the other one of R 3 and R 4 and of R 5 and R 6 is each a hydrogen atom;
R 7 is selected from the group consisting of methyl, ethyl, propyl, isopropyl, butyl, tert-butyl, phenyl, benzyl, substituted benzyl, and halophenyl groups; and
R 8 is selected from the group consisting of C 6 -C 10 aryl groups; and C 7 -C 10 alkaryl and aralkyl groups.

14. The catalyst according to claim 13 , wherein
R 1 and R 2 are each a hydrogen atom and R 3 , R 4 , R 5 and R 6 are independently selected from the group consisting of methyl, ethyl, propyl, isopropyl, butyl, tert-butyl, phenyl groups;
R 8 is phenyl; and
the internal electron donor is selected from the group consisting of 4-[benzoyl(methyl)amino]pentan-2-yl benzoate; 2,2,6,6-tetramethyl-5-(methylamino)heptan-3-ol dibenzoate; 4-[benzoyl (ethyl)amino]pentan-2-yl benzoate; and 4-(methylamino)pentan-2-yl bis (4-methoxy)benzoate).

15. The catalyst according to claim 1 , wherein
R 1 and R 2 are each a hydrogen atom and R 3 , R 4 , R 5 and R 6 are independently selected from the group consisting of C 1 -C 10 straight and branched alkyl groups;
R 7 is selected from the group consisting of methyl, ethyl, propyl, isopropyl, butyl, tert-butyl, phenyl, benzyl, substituted benzyl and halophenyl groups; and
R 8 is selected from the group consisting of C 6 -C 10 aryl groups; and C 7 -C 10

Assignees

• Saudi Basic Ind Corp

Inventors

• Taftaf Mansour
• Zuideveld Martin Alexander
• Batinas-Geurts Aurora Alexandra
• Sainani Jaiprakash Brijlal
• Patel Vimalkumar Mahendrabhai
• Zakharov Vladimir Aleksandrovich
• Bukatov Gennadii Dimitrievich
• Sergeev Sergei Andreevich
• Ghalit Nourdin

Classifications

• C07C233/69

  of an acyclic saturated carbon skeleton · CPC title

• C08F110/06 Primary

  Propene · CPC title

• C07C2101/14

  Chemistry & Metallurgy · mapped topic

• C07C233/18

  having the carbon atom of the carboxamide group bound to a hydrogen atom or to a carbon atom of an acyclic saturated carbon skeleton · CPC title

• C07C235/48

  having the nitrogen atom of at least one of the carboxamide groups bound to an acyclic carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms · CPC title