Coordination compounds having redox non-innocent ligands and flow batteries containing the same

Patent metadata

Field	Value
Publication number	US-9938308-B2
Application number	US-201615093606-A
Country	US
Kind code	B2
Filing date	Apr 7, 2016
Priority date	Apr 7, 2016
Publication date	Apr 10, 2018
Grant date	Apr 10, 2018

Abstract

Electrolyte solutions for flow batteries and other electrochemical systems can contain an active material capable of transferring more than one electron per oxidation-reduction cycle. Such active materials can include coordination compounds containing a metal center and at least one redox non-innocent ligand. Accordingly, flow batteries can include a first half-cell having a first electrolyte solution therein, where the first electrolyte solution contains a coordination compound having at least one redox non-innocent ligand coordinated to a metal center. Particular redox non-innocent ligands can include those bearing a quinone functional group, such as substituted catecholates bearing a quinone functional group. Some active materials can include compositions containing a coordination compound having at least one redox non-innocent ligand coordinated to a metal center, where the at least one redox non-innocent ligand is a substituted catecholate or a salt thereof bearing a quinone functional group.

First claim

What is claimed is the following:

1. A flow battery comprising:
a first half-cell having a first electrolyte solution therein, the first electrolyte solution comprising a coordination compound having at least one redox non-innocent ligand coordinated to a metal center,
wherein the at least one redox non-innocent ligand bears a quinone functional group,
wherein the quinone functional group is part of an aromatic ring bearing a catechol group, fused to the aromatic ring bearing the catechol group, or tethered via a linker to the aromatic ring bearing the catechol group.

2. The flow battery of claim 1 , wherein the at least one redox non-innocent ligand comprises a salt of a substituted catecholate bearing the quinone functional group.

3. The flow battery of claim 1 , wherein the at least one redox non-innocent ligand is selected from the group consisting of

4. The flow battery of claim 1 , wherein the coordination compound has a formula of
D g M(L 1 )(L 2 )(L 3 );
wherein M is a transition metal; D is ammonium, tetraalkylammonium, or an alkali metal ion; g ranges between 0 and 6; and L 1 , L 2 and L 3 are ligands, at least one of L 1 , L 2 and L 3 being the at least one redox non-innocent ligand.

5. The flow battery of claim 4 , wherein the transition metal comprises titanium.

6. The flow battery of claim 1 , wherein the metal center comprises a transition metal.

7. The flow battery of claim 6 , wherein the transition metal comprises titanium.

8. The flow battery of claim 1 , further comprising:
a second half-cell having a second electrolyte solution therein, the second electrolyte solution comprising an iron hexacyanide complex.

9. A composition comprising:
a coordination compound having at least one redox non-innocent ligand coordinated to a metal center;
wherein the at least one redox non-innocent ligand comprises a substituted catecholate or a salt thereof bearing a quinone functional group;
wherein the quinone functional group is part of an aromatic ring bearing a catechol group, fused to the aromatic ring bearing the catechol group, or tethered via a linker to the aromatic ring bearing the catechol group.

10. The composition of claim 9 , wherein the metal center comprises a transition metal.

11. The composition of claim 10 , wherein the metal center comprises a transition metal.

12. The composition of claim 9 , wherein the coordination compound has a formula of
D g M(L 1 )(L 2 )(L 3 );
wherein M is a transition metal; D is ammonium, tetraalkylammonium, or an alkali metal ion; g ranges between 0 and 6; and L 1 , L 2 and L 3 are ligands, at least one of L 1 , L 2 and L 3 being the at least one redox non-innocent ligand.

13. The composition of claim 9 , wherein the at least one redox non-innocent ligand is selected from the group consisting of

14. The composition of claim 9 , further comprising:
an aqueous solution in which the coordination compound is disposed.

15. The composition of claim 14 , wherein the aqueous solution has an alkaline pH.

Assignees

• Lockheed Martin Advanced Energy Storage Llc
• Lockheed Martin Energy Llc

Inventors

• Millard Matthew

Classifications

• H01M8/20

  Indirect fuel cells, e.g. fuel cells with redox couple being irreversible (H01M8/18 takes precedence) · CPC title

• Y02E60/528

  Cross-Sectional Technologies · mapped topic

• H01M8/188 Primary

  by recharging of redox couples containing fluids; Redox flow type batteries · CPC title

• C07F7/28 Primary

  Titanium compounds · CPC title

• Y02E60/50

  Fuel cells · CPC title