Coated photoconductors

Patent metadata

Field	Value
Publication number	US-9933715-B2
Application number	US-201615180566-A
Country	US
Kind code	B2
Filing date	Jun 13, 2016
Priority date	Oct 7, 2014
Publication date	Apr 3, 2018
Grant date	Apr 3, 2018

Abstract

The present disclosure is related to coated photoconductors. In an example, a coated photoconductor can comprise a photoconductor including a substrate having a charge generation layer and charge transport layer adhered thereto and a top coating adhered to the photoconductor.

First claim

What is claimed is:

1. A coated photoconductor, comprising:
a photoconductor including a substrate having a charge generation layer and charge transport layer adhered thereto; and
a top coating adhered to the photoconductor and comprising a cross-linkable polymer, a cross-linker, and a polymeric dopant having charge transport properties, wherein the polymeric dopant is selected from the group of polyfluorenes; polyanilines; polythiophenes; polycarbozoles; and mixtures thereof.

2. The coated photoconductor of claim 1 , wherein the top coating has a thickness of 0.1 μm to 12 μm.

3. The coated photoconductor of claim 2 , wherein the top coating has a thickness of 0.2 μm to 1 μm.

4. The coated photoconductor of claim 2 , wherein the polymeric dopant is present in the top coating at a concentration of 0.1 wt % to 10 wt %.

5. The coated photoconductor of claim 4 , wherein the polymeric dopant is present in the top coating at a concentration of 0.1 wt % to 2 wt %.

6. The coated photoconductor of claim 1 , wherein the polymeric dopant has a weight average molecular weight of less than 500,000.

7. The coated photoconductor of claim 1 , wherein the polymeric dopant comprise a polyfluorene copolymer having a weight average molecular weight of less than 50,000.

8. The coated photoconductor of claim 1 , wherein the substrate is a photo imaging plate of a liquid electrophotographic printer.

9. The coated photoconductor of claim 1 , wherein the cross-linkable polymer comprises at least one of:
polymerized monomers selected from acrylates, methacrylates, styrenes, vinyl monomers, and combinations thereof; and
a polymerized monomer selected from the group of methyl methacrylate, butyl acrylate, butyl methacrylate, hexyl acrylate, hexyl methacrylate, 2-ethylhexyl acrylate, 2-ethylhexyl methacrylate, lauryl acrylate, lauryl methacrylate, octadecyl acrylate, octadecyl methacrylate, stearyl methacrylate, acrylic acid, methacrylic acid, acrylonitrile, methacrylonitrile, styrene, methylstyrene, and combinations thereof.

10. The coated photoconductor of claim 1 , wherein the cross-linkable polymer comprises at least one of:
an acrylate copolymer;
a methacrylate copolymer;
the cross-linkable polymer selected from the group of polyisocyanates, polyols, polyesters, polyamines, and combinations thereof.

11. The coated photoconductor of claim 1 , wherein the charge generation layer comprises charge generation materials selected from the group of crystalline selenium, amorphous selenium, selenium-tellurium, selenium-tellurium-halogen, selenium-arsenic compound, amorphous silicon, phthalocyanine pigments, metal phthalocyanine, non-metal phthalocyanine, azulenium salt pigments, aquatic acid methine pigment, azo pigments having a carbazole skeleton, azo pigments having a triphenylamine skeleton, azo pigments having diphenylamine skeleton, azo pigments having dibenzothiophene skeleton, azo pigments having fluorenone skeleton, azo pigments having oxadiazole skeleton, azo pigments having bisstylbene skeleton, azo pigments having distyryl oxidiazole skeleton, azo pigments having distyrylcarbazole skeleton, perylene pigments, anthraquinone quinone pigments, polycyclic quinone pigments, quinone imine pigments, diphenylmethane pigments, triphenylmethane pigments, benzoquinone pigments, naphtoquinone pigments, cyanine pigments, azomethine pigments, indigoido pigments, bisbenzimidazole pigments, and mixtures thereof.

12. The coated photoconductor of claim 1 , wherein the charge transport layer comprises charge transport materials selected from the group of chloroanil, bromoanil, tetracyanoethylene, tetracyano quinodimethane, 2,4,7-trinitro-9-fluorenone, 2,4,5,7-tetranitro-9-fluorenone, 2,4,5,7-tetranitroxanthone, 2,4,8-trinitrothioxanthone, 2,6,8-trinitro-4H-indino[1,2-b]thiophene-4-on, 1,3,7-trinitro-dibenzothiophene-5,5-dioxide, diphenoquinones, oxazoles, oxadiazoles, imidazoles, monoarylamines, diarylamines, triarylamines, stilbenes, α-phenyl stilbenes, benzidines, diarylmethanes, triarylmethanes, 9-styrylanthracenes, pyrazolines, divinyl benzenes, hydrazones, indenes, butadienes, pyrenes, bisstylbenes, enamines, aromatic tertiary amines, and mixtures thereof.

13. The coated photoconductor of claim 1 , wherein the top coating provides an optical density of at least 0.2 after 300,000 printed images at 20% nominal coverage and provides an optical density of at least 0.8 after 300,000 impressions at 80% nominal coverage.

14. The coated photoconductor of claim 1 wherein the polyfluorenes comprise polyfluorene co-polymers, the polyanilines comprise polyaniline co-polymers, the polythiophenes comprise polythiophene co-polymers, and the polycarbozoles comprise polycarbozole co-polymers.

15. A process of manufacturing a photoconductor, comprising applying a top coating to the photoconductor, the photoconductor including a substrate having a charge generation layer and charge transport layer adhered thereto, wherein the top coating comprises a cross-linkable polymer, a cross-linker, and a polymeric dopant having charge transport properties, and wherein the polymeric dopant is dispersed throughout the top coating, and wherein the polymeric dopant is selected from the group of polyfluorenes, polyanilines, polythiophenes, polycarbozoles, and mixtures thereof.

16. The process of claim 15 wherein the polyfluorenes comprise polyfluorene co-polymers, the polyanilines comprise polyaniline co-polymers, the polythiophenes comprise polythiophene co-polymers and the polycarbozoles comprise polycarbozole co-polymers.

17. The process of claim 15 , wherein the polymeric dopant is a polyfluorene copolymer having a weight average molecular weight of less than 50,000.

Assignees

• Hewlett Packard Development Co

Inventors

• Nauka Krzysztof
• Zhou Zhang-Lin
• Ng Hou T

Classifications

• G03G5/14721

  Polyolefins; Polystyrenes; Waxes · CPC title

• G03G5/14739

  Polymers containing hereto rings in the side chain · CPC title

• G03G5/14791 Primary

  Macromolecular compounds characterised by their structure, e.g. block polymers, reticulated polymers, or by their chemical properties, e.g. by molecular weight or acidity · CPC title

• G03G5/005

  Materials for treating the recording members, e.g. for cleaning, reactivating, polishing · CPC title

• G03G5/14778

  Polycondensates comprising sulfur atoms in the main chain · CPC title